{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T23:18:36Z","timestamp":1792279116811,"version":"4.4.0"},"reference-count":52,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2024,8,6]],"date-time":"2024-08-06T00:00:00Z","timestamp":1722902400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002383","name":"King saud university","doi-asserted-by":"publisher","award":["RSP2024R61"],"award-info":[{"award-number":["RSP2024R61"]}],"id":[{"id":"10.13039\/501100002383","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>An Fe(III)-carbonato six-coordinate picket fence porphyrin complex with the formula [K(2,2,2-crypt)][FeIII(TpivPP)(CO3)]\u00b7C6H5Cl\u00b73H2O (I) has been synthesized and characterized by UV-Vis and FT-IR spectra. The structure of (carbonato)(\u03b1,\u03b1,\u03b1,\u03b1-tetrakis(o-pivalamidophenyl)porphinato)ferrate(III) was also established by XRD. The iron atom is hexa-coordinated by the four nitrogen atoms of the pyrrol rings and the two oxygen atoms of the CO32\u2212 group. Complex I, characterized as a ferric high-spin complex (S = 5\/2), presented higher Fe-Np (2.105(6) \u00c5) and Fe-PC (0.654(2) \u00c5) distances. Both X-ray molecular structure and Hirshfeld surface analysis results show that the crystal packing of I is made by C-H\u22efO and C-H\u22efCg weak intermolecular hydrogen interactions involving neighboring [FeIII(TpivPP)(CO3)]\u2212 ion complexes. Computational studies were carried out at DFT\/B3LYP-D3\/LanL2DZ to investigate the HOMO and LUMO molecular frontier orbitals and the reactivity within the studied compound. The stability of compound I was investigated by analyzing both intra- and inter-molecular interactions using the 2D and 3DHirshfeld surface (HS) analyses. Additionally, the frontier molecular orbital (FMO) calculations and the molecular electronic potential (MEP) analyses were conducted to determine the electron localizations, electrophilic, and nucleophilic regions, as well as charge transfer (ECT) within the studied system.<\/jats:p>","DOI":"10.3390\/molecules29163722","type":"journal-article","created":{"date-parts":[[2024,8,6]],"date-time":"2024-08-06T15:24:16Z","timestamp":1722957856000},"page":"3722","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Synthesis, X-ray Crystallography, Spectroscopic Characterizations, Density Functional Theory, and Hirshfeld Surface Analyses of a Novel (Carbonato) Picket Fence Iron(III) Complex"],"prefix":"10.3390","volume":"29","author":[{"given":"Mondher","family":"Dhifet","sequence":"first","affiliation":[{"name":"Laboratory of Physical Chemistry of Materials (LR01ES19), Faculty of Sciences of Monastir, University of Monastir, Avenue of the Environment, Monastir 5019, Tunisia"},{"name":"Faculty of Sciences of Gafsa, University of Gafsa, Sidi Ahmed Zarrouk, Gafsa 2112, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7913-7768","authenticated-orcid":false,"given":"Bouzid","family":"Gassoumi","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials and Interfaces (LIMA), Faculty of Science of Monastir, University of Monastir, Avenue of Environnment, Monastir 5000, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maxim A.","family":"Lutoshkin","sequence":"additional","affiliation":[{"name":"Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodokst, 50\/24, 660036 Krasnoyarsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anna S.","family":"Kazachenko","sequence":"additional","affiliation":[{"name":"Institute of Non-Ferrous Metals, Siberian Federal University, pr. Svobodny, 79, 660041 Krasnoyarsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3121-1666","authenticated-orcid":false,"given":"Aleksandr S.","family":"Kazachenko","sequence":"additional","affiliation":[{"name":"Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodokst, 50\/24, 660036 Krasnoyarsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5926-5500","authenticated-orcid":false,"given":"Omar","family":"Al-Dossary","sequence":"additional","affiliation":[{"name":"Department of Physics and Astronomy, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2350-7360","authenticated-orcid":false,"given":"Noureddine","family":"Issaoui","sequence":"additional","affiliation":[{"name":"Laboratory of Quantum and Statistical Physics LR18ES18, Faculty of Sciences of Monastir, Avenue of the Environment, Monastir 5079, Tunisia"},{"name":"Higher Institute of Computer Sciences and Mathematics of Monastir, University of Monastir, Monastir 5000, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7565-8240","authenticated-orcid":false,"given":"Habib","family":"Nasri","sequence":"additional","affiliation":[{"name":"Laboratory of Physical Chemistry of Materials (LR01ES19), Faculty of Sciences of Monastir, University of Monastir, Avenue of the Environment, Monastir 5019, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,8,6]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"8281","DOI":"10.1021\/ja00806a013","article-title":"Hoard, Stereochemistry of low-spin cobalt porphyrins. I. Structure and bonding in a nitrosylcobalt porphyrin and their bearing on one rational model for the oxygenated","volume":"95","author":"Scheidt","year":"1973","journal-title":"J. Am. Chem. Soc."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"8607","DOI":"10.1021\/ja00779a068","article-title":"Dynamics of axial ligation in metalloporphyrins. I. Imidazole exchange in low-spin ferric porphyrins","volume":"94","author":"Walker","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"7868","DOI":"10.1021\/ja00804a054","article-title":"Reversible oxygen adduct formation in ferrous complexes derived from a picket fence porphyrin. Model for oxymyoglobin","volume":"95","author":"Collman","year":"1973","journal-title":"J. Am. Chem. Soc."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"6237","DOI":"10.1021\/ja00255a003","article-title":"Gated electron transfer: When are observed rates controlled by conformational interconversion?","volume":"109","author":"Hoffman","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"8324","DOI":"10.1021\/ic800944q","article-title":"Modulation of Metal Displacements in a Saddle Distorted Macrocycle: Synthesis, Structure, and Properties of High-Spin Fe(III) Porphyrins and Implications for the Hemoproteins","volume":"47","author":"Patra","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"589","DOI":"10.1021\/cr020634j","article-title":"Models of the bis-histidine-ligated electron-transferring cytochromes. Comparative geometric and electronic structure of low-spin ferro-and ferrihemes","volume":"104","author":"Walker","year":"2004","journal-title":"Chem. Rev."},{"key":"ref_7","doi-asserted-by":"crossref","unstructured":"Montiel-Montoya, R., Bill, E., Gonser, U., Lauer, S., Trautwein, A.X., Schappacher, M., Ricard, L., and Weiss, R. (1983). M\u00f6ssbauer Studies of Synthetic Analogues for the Active Site in Cytochromes P450. The Coordination Chemistry of Metalloenzymes: The Role of Metals in Reactions Involving Water, Dioxygen and Related Species. Proceedings of the NATO Advanced Study Institute held at San Miniato, Pisa, Italy, 28 May\u20138 June 1982, Springer.","DOI":"10.1007\/978-94-009-7049-6_30"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1007\/BF00549096","article-title":"Bonded-atom fragments for describing molecular charge densities","volume":"44","author":"Hirshfeld","year":"1977","journal-title":"Theor. Chim. Acta"},{"key":"ref_9","first-page":"1006","article-title":"CrystalExplorer: A program for Hirshfeld surface analysis, visualization and qu antitative analysis of molecular crystals","volume":"54","author":"Wolff","year":"2013","journal-title":"J. Appl. Cryst."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1039\/B818330A","article-title":"Hirshfeld surface analysis","volume":"11","author":"Spackman","year":"2009","journal-title":"Cryst. Eng. Commun."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"378","DOI":"10.1039\/B203191B","article-title":"Fingerprinting intermolecular interactions in molecular crystals","volume":"4","author":"Spackman","year":"2002","journal-title":"Cryst. Eng. Commun."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1427","DOI":"10.1021\/ja00839a026","article-title":"Robinsonlc, Picket fence porphyrins. Synthetic models for oxygen binding hemoproteins","volume":"97","author":"Collman","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"ref_13","unstructured":"Bruker, A. (2014). Instrument Service v4. 2.7, APEX2, SADABS, SAINT-Plus & XPREP, Bruker AXS Inc."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"306","DOI":"10.1107\/S1600576715001132","article-title":"Crystal structure determination and refinement via SIR2014","volume":"48","author":"Burla","year":"2005","journal-title":"J. Appl. Cryst."},{"key":"ref_15","first-page":"3","article-title":"SHELXT\u2013Integrated space-group and crystal-structure determination","volume":"71","author":"Sheldrick","year":"2014","journal-title":"Acta Cryst."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1107\/S0021889894010642","article-title":"SORTX\u2014A program for on-screen stick-model editing and autosorting of SHELX files for use on a PC","volume":"28","author":"Mcardle","year":"1995","journal-title":"J. Appl. Cryst."},{"key":"ref_17","first-page":"148","article-title":"Structure validation in chemical crystallography","volume":"65","author":"Spek","year":"2009","journal-title":"Acta. Cryst."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"565","DOI":"10.1107\/S0021889897003117","article-title":"ORTEP-3 for Windows-a version of ORTEP-III with a Graphical User Interface (GUI)","volume":"30","author":"Farrugia","year":"1997","journal-title":"J. Appl. Cryst."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1107\/S0021889807067908","article-title":"Mercury CSD 2.0\u2013new features for the visualization and investigation of crystal structures","volume":"41","author":"Macrae","year":"2008","journal-title":"J. Appl. Crystallogr."},{"key":"ref_20","first-page":"9","article-title":"PLATON SQUEEZE: A tool for the calculation of the disordered solvent contribution to the calculated structure factors","volume":"71","author":"Spek","year":"2015","journal-title":"Acta Crystallogr."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"S1","DOI":"10.1039\/p298700000s1","article-title":"Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds","volume":"2","author":"Allen","year":"1987","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"2776","DOI":"10.1016\/j.ica.2008.12.020","article-title":"Preparation, UV\u2013Vis, IR and 1H NMR spectra, and molecular structure of the complex ion (\u03b72-carbonato)(\u03b1,\u03b1,\u03b1,\u03b1-tetrakis (o-pivalamidophenyl) porphinato) ferrate (III)","volume":"362","author":"Dhifet","year":"2009","journal-title":"Inorg.Chim. Acta"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"3904","DOI":"10.1021\/ic50225a061","article-title":"Preparation, solution properties, and structure of iron (III) porphyrin oxyanion complexes. Crystal and molecular stereochemistry of a novel bidentate nitrato complex","volume":"23","author":"Phillippi","year":"1981","journal-title":"Inorg. Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"440","DOI":"10.1021\/ic00302a014","article-title":"Five-and six-coordinate high-spin iron (III) porphyrin complexes with teflate (OTeF5\u2212) ligands","volume":"28","author":"Kellett","year":"1989","journal-title":"Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"3459","DOI":"10.1021\/ic00042a023","article-title":"Reactions of bis (nitro)[.alpha.,.alpha.,.alpha.,.alpha.-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(III) with 2,3,5,6-tetrafluorothiophenol and 2,3,5,6-tetrafluorothiophenolate. EPR and Moessbauer spectra and molecular structures","volume":"31","author":"Nasri","year":"1992","journal-title":"Inorg. Chem."},{"key":"ref_26","first-page":"507","article-title":"Synthesis and Structure of a Dimercapto\u2014Iron(III) Porphyrin Derivative: [Fe(SC6HF4)2TPP][Na c 18C6], C6H6","volume":"57","author":"Doppelt","year":"1984","journal-title":"Croat. Chem. Acta"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/BFb0036789","article-title":"Recent advances in the stereochemistry of metallotetrapyrroles","volume":"64","author":"Scheidt","year":"1987","journal-title":"Struct. Bond."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"034108","DOI":"10.1063\/1.2148954","article-title":"Semi empirical hybrid density functional with perturbative second order correlation","volume":"124","author":"Grimme","year":"2006","journal-title":"J. Chem. Phys."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","article-title":"Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density","volume":"37","author":"Lee","year":"1988","journal-title":"Phys. Rev. B"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"270","DOI":"10.1063\/1.448799","article-title":"Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg","volume":"82","author":"Hay","year":"1985","journal-title":"J. Chem. Phys."},{"key":"ref_31","unstructured":"(2024, June 10). G09|Gaussian.com. Available online: https:\/\/gaussian.com\/glossary\/g09\/."},{"key":"ref_32","unstructured":"Roy, D.D., Todd, A.K., and John, M.M. (2009). Gauss View, 5.0. 8, Gaussian Inc."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"2354","DOI":"10.1002\/jcc.26012","article-title":"DFT calculations on molecular structures, HOMO\u2013LUMO study, reactivity descriptors and spectral analyses of newly synthesized diorganotin(IV) 2-chloridophenylacetohydroxamate complexes","volume":"40","author":"Choudhary","year":"2019","journal-title":"J. Comput. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"124315","DOI":"10.1016\/j.molliq.2024.124315","article-title":"Solvation model, Vibrational analysis, Electronic level, Non-Covalent interactions and Molecular docking investigations of 6-Chloro-2-(4-Aminophenyl)-1H-Benzimidazole","volume":"398","author":"Fasiuddin","year":"2024","journal-title":"J. Mol. Liq."},{"key":"ref_35","doi-asserted-by":"crossref","unstructured":"Guill\u00e9n-L\u00f3pez, A., Cabrera, O.G.R., de la Cruz Arreola, S., Celaya, C.A., Sevilla-Camacho, P.Y., and Mu\u00f1iz, J. (2024). Exploring the potential of porphyrin-based materials for organic solar cells supported on carbon: A quantum chemistry approach. J. Photochem. Photobiol. A Chem., 449.","DOI":"10.1016\/j.jphotochem.2023.115401"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"121552","DOI":"10.1016\/j.molliq.2023.121552","article-title":"Intermolecular interactions in ethanol solution of OABA: Raman, FTIR, DFT, M062X, MEP, NBO, FMO, AIM, NCI, RDG analysis","volume":"377","author":"Jumabaev","year":"2023","journal-title":"J. Mol. Liq."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"487","DOI":"10.1080\/22297928.2023.2283451","article-title":"Biological and computational studies of novel scaffolds of gallic acid: Insight from density functional theory and molecular docking studies","volume":"13","author":"Hijazi","year":"2023","journal-title":"Anal. Chem. Lett."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"100438","DOI":"10.1016\/j.chphi.2023.100438","article-title":"Exploration of semi-carbazone derivatives as promising agents against cholera: Insights from spectroscopic analysis, reactivity studies (ELF, HOMO-LUMO, NBO), solvation effects, and molecular docking investigations","volume":"8","author":"Owen","year":"2024","journal-title":"Chem. Phys. Impact"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"35307","DOI":"10.1021\/acsomega.3c04957","article-title":"Polymorphs of Substituted p-Toluenesulfonanilide: Synthesis, Single-Crystal Analysis, Hirshfeld Surface Exploration, and Theoretical Investigation","volume":"8","author":"Riaz","year":"2023","journal-title":"ACS Omega"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"7077","DOI":"10.1002\/aoc.7077","article-title":"Sulfonamide derived Schiff base Mn (II), Co (II), and Ni (II) complexes: Crystal structures, density functional theory and Hirshfeld surface analysis","volume":"37","author":"Siddiqui","year":"2023","journal-title":"Appl. Organomet. Chem."},{"key":"ref_41","doi-asserted-by":"crossref","unstructured":"Fatima, A., Kumar, A., Saral, A.K.A., Muthu, S., Afzal, M., Haq, N., Nazar, I., Siddiqui, N., and Javed, S. (2023). Study of L-tryptophan (a neurotransmitter precursor): Spectral, Hirshfeld surface, molecular docking and dynamics simulations. Z. Phys. Chem.","DOI":"10.1515\/zpch-2023-0441"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"575","DOI":"10.1107\/S205225251700848X","article-title":"CrystalExplorer model energies and energy frameworks: Extension to metal coordination compounds, organic salts, solvates and open-shell systems","volume":"4","author":"Mackenzie","year":"2017","journal-title":"IUCrJ"},{"key":"ref_43","doi-asserted-by":"crossref","unstructured":"McKinnon, J.J., Jayatilaka, D., and Spackman, M.A. (2007). Towards quantitative analysis of intermolecular interactions with Hirshfeld surfaces. Chem. Commun., 3814\u20133816.","DOI":"10.1039\/b704980c"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"817","DOI":"10.1016\/j.poly.2016.06.045","article-title":"Synthesis, spectroscopic characterizations, cyclic voltammetry investigation and molecular structure of the di-\u03bc-cyanato-N-bis(\u03bc-1,4,7,10,13,16-hexaoxacyclooctadecane)bis(5,10,15,20-tetraphenylporphyrinato) dimagnesiumdipotassium complex","volume":"117","author":"Ezzayani","year":"2016","journal-title":"Polyhedron"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"7011","DOI":"10.1016\/j.tet.2017.10.029","article-title":"Synthesis, crystal structure and spectroscopic characterizations of porphyrin-based Mg (II) complexes\u2013Potential application as antibacterial agent","volume":"73","author":"Amiri","year":"2017","journal-title":"Tetrahedron"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"477","DOI":"10.1016\/j.jssc.2017.11.018","article-title":"Two novel magnesium (II) meso-tetraphenylporphyrin-based coordination complexes: Syntheses, combined experimental and theoretical structures elucidation, spectroscopy, photophysical properties and antibacterial activity","volume":"258","author":"Amiri","year":"2018","journal-title":"J. Solid State Chem."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"130299","DOI":"10.1016\/j.molstruc.2021.130299","article-title":"New DMAP meso-arylporphyrin Magnesium(II) complex. Spectroscopic, Cyclic voltammetry and X-ray molecular structure characterization. DFT, DOS and MEP calculations and Antioxidant and Antifungal activities","volume":"1236","author":"Fradi","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"1845","DOI":"10.1021\/ic00036a023","article-title":"Weiss, Structural, Moessbauer, and EPR investigations on two oxidation states of a five-coordinate, high-spin synthetic heme. Quantitative interpretation of zero-field parameters and large quadrupole splitting","volume":"31","author":"Bominaar","year":"1992","journal-title":"Inorg. Chem."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"3607","DOI":"10.1016\/S0277-5387(98)00156-9","article-title":"Synthesis, spectroscopic and structural characterization of the pentacoordinate high-spin Fe (III) isothiocyanate \u201cpicket fence\u201d porphyrin complex","volume":"17","author":"Nasri","year":"1998","journal-title":"Polyhedron"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"575","DOI":"10.1142\/S108842460500068X","article-title":"Preparation and spectroscopic properties of the (cyanato-N) and (oxalato) iron(III) \u201cpicket fence\u201d porphyrins: Structure of the (cyanato-N)(\u03b1,\u03b1,\u03b1,\u03b1-tetrakis(o-pivalamidophenyl)porphinato)iron(III) complex","volume":"9","author":"Belkhiria","year":"2005","journal-title":"J. Porphyr. Phthalocyanines"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1021\/ic00327a009","article-title":"Use of protected binding sites for nitrite binding in iron(III) porphyrinates. Crystal structure of the bis(nitro)(.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(o-pivalamidophenyl)porphinato)iron(III) anion","volume":"28","author":"Nasri","year":"1990","journal-title":"Inorg. Chem."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"1483","DOI":"10.1021\/ic00007a012","article-title":"Reactions of bis(nitro)(.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(o-pivalamidophenyl)porphinato)ferrate(III) with pyridine and imidazole. EPR and Moessbauer spectra and molecular structures of the mixed-ligand species","volume":"30","author":"Nasri","year":"1991","journal-title":"Inorg. Chem."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/16\/3722\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T15:30:56Z","timestamp":1760110256000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/16\/3722"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,8,6]]},"references-count":52,"journal-issue":{"issue":"16","published-online":{"date-parts":[[2024,8]]}},"alternative-id":["molecules29163722"],"URL":"https:\/\/doi.org\/10.3390\/molecules29163722","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,8,6]]}}}