{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T12:06:54Z","timestamp":1792843614310,"version":"4.5.0"},"reference-count":90,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2024,8,7]],"date-time":"2024-08-07T00:00:00Z","timestamp":1722988800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22208033"],"award-info":[{"award-number":["22208033"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22206077"],"award-info":[{"award-number":["22206077"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22KJB530005"],"award-info":[{"award-number":["22KJB530005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["CJ20230039"],"award-info":[{"award-number":["CJ20230039"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["YN21044"],"award-info":[{"award-number":["YN21044"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Natural Science Foundation of the Jiangsu Higher Education Institutions of China","award":["22208033"],"award-info":[{"award-number":["22208033"]}]},{"name":"Natural Science Foundation of the Jiangsu Higher Education Institutions of China","award":["22206077"],"award-info":[{"award-number":["22206077"]}]},{"name":"Natural Science Foundation of the Jiangsu Higher Education Institutions of China","award":["22KJB530005"],"award-info":[{"award-number":["22KJB530005"]}]},{"name":"Natural Science Foundation of the Jiangsu Higher Education Institutions of China","award":["CJ20230039"],"award-info":[{"award-number":["CJ20230039"]}]},{"name":"Natural Science Foundation of the Jiangsu Higher Education Institutions of China","award":["YN21044"],"award-info":[{"award-number":["YN21044"]}]},{"name":"Changzhou Science and Technology Projec","award":["22208033"],"award-info":[{"award-number":["22208033"]}]},{"name":"Changzhou Science and Technology Projec","award":["22206077"],"award-info":[{"award-number":["22206077"]}]},{"name":"Changzhou Science and Technology Projec","award":["22KJB530005"],"award-info":[{"award-number":["22KJB530005"]}]},{"name":"Changzhou Science and Technology Projec","award":["CJ20230039"],"award-info":[{"award-number":["CJ20230039"]}]},{"name":"Changzhou Science and Technology Projec","award":["YN21044"],"award-info":[{"award-number":["YN21044"]}]},{"name":"Changzhou Institute of Technology Start-up Capital","award":["22208033"],"award-info":[{"award-number":["22208033"]}]},{"name":"Changzhou Institute of Technology Start-up Capital","award":["22206077"],"award-info":[{"award-number":["22206077"]}]},{"name":"Changzhou Institute of Technology Start-up Capital","award":["22KJB530005"],"award-info":[{"award-number":["22KJB530005"]}]},{"name":"Changzhou Institute of Technology Start-up Capital","award":["CJ20230039"],"award-info":[{"award-number":["CJ20230039"]}]},{"name":"Changzhou Institute of Technology Start-up Capital","award":["YN21044"],"award-info":[{"award-number":["YN21044"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>In recent years, nanozymes have attracted particular interest and attention as catalysts because of their high catalytic efficiency and stability compared with natural enzymes, whereas how to use simple methods to further improve the catalytic activity of nanozymes is still challenging. In this work, we report a trimetallic metal\u2013organic framework (MOF) based on Fe, Co and Ni, which was prepared by replacing partial original Fe nodes of the Fe-MOF with Co and Ni nodes. The obtained FeCoNi-MOF shows both oxidase-like activity and peroxidase-like activity. FeCoNi-MOF can not only oxidize the chromogenic substrate 3,3,5,5-tetramethylbenzidine (TMB) to its blue oxidation product oxTMB directly, but also catalyze the activation of H2O2 to oxidize the TMB. Compared with corresponding monometallic\/bimetallic MOFs, the FeCoNi-MOF with equimolar metals hereby prepared exhibited higher peroxidase-like activity, faster colorimetric reaction speed (1.26\u20132.57 folds), shorter reaction time (20 min) and stronger affinity with TMB (2.50\u20135.89 folds) and H2O2 (1.73\u20133.94 folds), owing to the splendid synergistic electron transfer effect between Fe, Co and Ni. Considering its outstanding advantages, a promising FeCoNi-MOF-based sensing platform has been designated for the colorimetric detection of the biomarker H2O2 and environmental pollutant TP, and lower limits of detection (LODs) (1.75 \u03bcM for H2O2 and 0.045 \u03bcM for TP) and wider linear ranges (6\u2013800 \u03bcM for H2O2 and 0.5\u201380 \u03bcM for TP) were obtained. In addition, the newly constructed colorimetric platform for TP has been applied successfully for the determination of TP in real water samples with average recoveries ranging from 94.6% to 112.1%. Finally, the colorimetric sensing platform based on FeCoNi-MOF is converted to a cost-effective paper strip sensor, which renders the detection of TP more rapid and convenient.<\/jats:p>","DOI":"10.3390\/molecules29163739","type":"journal-article","created":{"date-parts":[[2024,8,7]],"date-time":"2024-08-07T11:33:52Z","timestamp":1723030432000},"page":"3739","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Trimetallic FeCoNi Metal\u2013Organic Framework with Enhanced Peroxidase-like Activity for the Construction of a Colorimetric Sensor for Rapid Detection of Thiophenol in Water Samples"],"prefix":"10.3390","volume":"29","author":[{"given":"Zehui","family":"Deng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China"},{"name":"Shandong Institute of Metrology, Jinan 250014, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqing","family":"Cao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Materials, Changzhou Institute of Technology, 666 Liaohe Road (S), Changzhou 213022, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Materials, Changzhou Institute of Technology, 666 Liaohe Road (S), Changzhou 213022, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhao","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Materials, Changzhou Institute of Technology, 666 Liaohe Road (S), Changzhou 213022, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3194-0164","authenticated-orcid":false,"given":"Jianwei","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Materials, Changzhou Institute of Technology, 666 Liaohe Road (S), Changzhou 213022, China"},{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhu Road (S), Nanjing 211816, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,8,7]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"659","DOI":"10.1016\/0891-5849(89)90147-0","article-title":"Toxicity of thiols and disulphides: Involvement of free-radical species","volume":"7","author":"Munday","year":"1989","journal-title":"Free Radic. 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