{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T20:00:56Z","timestamp":1791835256628,"version":"4.3.4"},"reference-count":84,"publisher":"MDPI AG","issue":"17","license":[{"start":{"date-parts":[[2024,8,28]],"date-time":"2024-08-28T00:00:00Z","timestamp":1724803200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Key Research and Development Project of Hainan Province, China","award":["ZDYF2024GXJS005"],"award-info":[{"award-number":["ZDYF2024GXJS005"]}]},{"name":"Key Research and Development Project of Hainan Province, China","award":["ZDKJ202016"],"award-info":[{"award-number":["ZDKJ202016"]}]},{"name":"Key Research and Development Project of Hainan Province, China","award":["22105053"],"award-info":[{"award-number":["22105053"]}]},{"name":"Key Research and Development Project of Hainan Province, China","award":["521QN209"],"award-info":[{"award-number":["521QN209"]}]},{"name":"Major Science and Technology Plan of Hainan Province, China","award":["ZDYF2024GXJS005"],"award-info":[{"award-number":["ZDYF2024GXJS005"]}]},{"name":"Major Science and Technology Plan of Hainan Province, China","award":["ZDKJ202016"],"award-info":[{"award-number":["ZDKJ202016"]}]},{"name":"Major Science and Technology Plan of Hainan Province, China","award":["22105053"],"award-info":[{"award-number":["22105053"]}]},{"name":"Major Science and Technology Plan of Hainan Province, China","award":["521QN209"],"award-info":[{"award-number":["521QN209"]}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["ZDYF2024GXJS005"],"award-info":[{"award-number":["ZDYF2024GXJS005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["ZDKJ202016"],"award-info":[{"award-number":["ZDKJ202016"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22105053"],"award-info":[{"award-number":["22105053"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["521QN209"],"award-info":[{"award-number":["521QN209"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Natural Science Foundation of Hainan Province, China","award":["ZDYF2024GXJS005"],"award-info":[{"award-number":["ZDYF2024GXJS005"]}]},{"name":"Natural Science Foundation of Hainan Province, China","award":["ZDKJ202016"],"award-info":[{"award-number":["ZDKJ202016"]}]},{"name":"Natural Science Foundation of Hainan Province, China","award":["22105053"],"award-info":[{"award-number":["22105053"]}]},{"name":"Natural Science Foundation of Hainan Province, China","award":["521QN209"],"award-info":[{"award-number":["521QN209"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>In view of the flue gas characteristics of cement kilns in China, the development of low-temperature denitrification catalysts with excellent anti-poisoning performance has important theoretical and practical significance. In this work, a series of MnCeOx@TiO2 and tourmaline-containing MnCeOx@TiO2-T catalysts was prepared using a chemical pre-deposition method. It was found that the MnCeOx@TiO2-T2 catalyst (containing 2% tourmaline) exhibited the best low-temperature NH3-selective catalytic reduction (NH3-SCR) performance, yielding 100% NOx conversion at 110 \u00b0C and above. When 100\u2013300 ppm SO2 and 10 vol.% H2O were introduced to the reaction, the NOx conversion of the MnCeOx@TiO2-T2 catalyst was still higher than 90% at 170 \u00b0C, indicating good anti-poisoning performance. The addition of appropriate amounts of tourmaline can not only preferably expose the active {001} facets of TiO2 but also introduce the acidic SiO2 and Al2O3 components and increase the content of Mn4+ and O\u03b1 on the surface of the catalyst, all of which contribute to the enhancement of reaction activity of NH3-SCR and anti-poisoning performance. However, excess amounts of tourmaline led to the formation of dense surface of catalysts that suppressed the exposure of catalytic active sites, giving rise to the decrease in catalytic activity and anti-poisoning capability. Through an in situ DRIFTS study, it was found that the addition of appropriate amounts of tourmaline increased the number of Br\u00f8nsted acid sites on the catalyst surface, which suppressed the adsorption of SO2 and thus inhibited the deposition of NH4HSO4 and (NH4)2HSO4 on the surface of the catalyst, thereby improving the NH3-SCR performance and anti-poisoning ability of the catalyst.<\/jats:p>","DOI":"10.3390\/molecules29174079","type":"journal-article","created":{"date-parts":[[2024,8,28]],"date-time":"2024-08-28T11:54:10Z","timestamp":1724846050000},"page":"4079","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Effect of Tourmaline Addition on the Anti-Poisoning Performance of MnCeOx@TiO2 Catalyst for Low-Temperature Selective Catalytic Reduction of NOx"],"prefix":"10.3390","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-6046-4655","authenticated-orcid":false,"given":"Zhenzhen","family":"Zhao","sequence":"first","affiliation":[{"name":"School of Advanced Agricultural Science, Weifang University, Weifang 261061, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liyin","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Power Source and Ecomaterials Science, Hebei University of Technology, Tianjin 300130, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-6976-4749","authenticated-orcid":false,"given":"Xiangqing","family":"Lin","sequence":"additional","affiliation":[{"name":"School of Advanced Agricultural Science, Weifang University, Weifang 261061, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5684-1103","authenticated-orcid":false,"given":"Gang","family":"Xue","sequence":"additional","affiliation":[{"name":"Institute of Power Source and Ecomaterials Science, Hebei University of Technology, Tianjin 300130, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Hu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, Haikou 570228, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haibin","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Chemistry, Chemical & Environmental Engineering, Weifang University, Weifang 261061, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyu","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Advanced Agricultural Science, Weifang University, Weifang 261061, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofang","family":"Su","sequence":"additional","affiliation":[{"name":"Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, Haikou 570228, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5543-6296","authenticated-orcid":false,"given":"Yanan","family":"Gao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, Haikou 570228, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,8,28]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"475","DOI":"10.1016\/j.cej.2019.02.008","article-title":"Polyetheramine improves the CO2 adsorption behavior of tetraethylenepentamine-functionalized sorbents","volume":"364","author":"Wang","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"472","DOI":"10.1016\/j.cej.2015.03.098","article-title":"Tetraethylenepentamine-modified MCM-41\/silica gel with hierarchical mesoporous structure for CO2 capture","volume":"273","author":"Wang","year":"2015","journal-title":"Chem. Eng. J."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"1336","DOI":"10.1016\/j.gee.2023.11.002","article-title":"Advanced 3D Ordered Electrodes for PEMFC Applications: From Structural Features and Fabrication Methods to the Controllable Design of Catalyst Layers","volume":"9","author":"Wang","year":"2024","journal-title":"Green Energy Environ."},{"key":"ref_4","first-page":"907","article-title":"Review of deNOx catalysts with SO2 and H2O poisoning resistance for low-temperature NH3-SCR","volume":"33","author":"Yang","year":"2014","journal-title":"Chem. Ind. Eng. Prog."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"140180","DOI":"10.1016\/j.cej.2022.140180","article-title":"Trace Co doping improves NH3-SCR performance and poisoning resistance of Ce-Mn-based catalysts","volume":"454","author":"Li","year":"2023","journal-title":"Chem. Eng. J."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"6182","DOI":"10.1021\/es3001773","article-title":"Enhancement of Activity and Sulfur Resistance of CeO2 Supported on TiO2\u2013SiO2 for the Selective Catalytic Reduction of NO by NH3","volume":"46","author":"Liu","year":"2012","journal-title":"Environ. Sci. Technol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"883","DOI":"10.1016\/j.joei.2018.08.001","article-title":"Low-temperature SCR of NO with NH3 over biomass char supported highly dispersed MnCe mixed oxides","volume":"92","author":"Yang","year":"2019","journal-title":"J. Energy Inst."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1016\/j.cattod.2011.03.034","article-title":"Low-temperature selective catalytic reduction of NOx with NH3 over metal oxide and zeolite catalysts\u2014A review","volume":"175","author":"Li","year":"2011","journal-title":"Catal. Today"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"347","DOI":"10.1016\/j.apcatb.2007.09.039","article-title":"Effect of transition metals addition on the catalyst of manganese\/titania for low-temperature selective catalytic reduction of nitric oxide with ammonia","volume":"79","author":"Wu","year":"2008","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"2479","DOI":"10.1002\/1521-3773(20010702)40:13<2479::AID-ANIE2479>3.0.CO;2-7","article-title":"Low-Temperature Selective Catalytic Reduction (SCR) of NO with NH3 by Using Mn, Cr, and Cu Oxides Supported on Hombikat TiO2","volume":"40","author":"Smirniotis","year":"2001","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"83594","DOI":"10.1039\/C5RA10653B","article-title":"NH3-SCR activity, hydrothermal stability and poison resistance of a zirconium phosphate\/Ce0.5Zr0.5O2 catalyst in simulated diesel exhaust","volume":"5","author":"Yu","year":"2015","journal-title":"RSC Adv."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1016\/j.apcatb.2005.08.004","article-title":"MnOx\u2013CeO2 mixed oxide catalysts for complete oxidation of formaldehyde: Effect of preparation method and calcination temperature","volume":"62","author":"Tang","year":"2006","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"848","DOI":"10.1039\/b212725c","article-title":"A superior catalyst for low-temperature NO reduction with NH3","volume":"7","author":"Qi","year":"2003","journal-title":"Chem. Commun."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/j.catcom.2006.06.025","article-title":"Low temperature selective catalytic reduction of NOx with NH3 over amorphous MnOx catalysts prepared by three methods","volume":"8","author":"Tang","year":"2007","journal-title":"Catal. Commun."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1016\/j.apcatb.2010.06.012","article-title":"Origination of N2O from NO reduction by NH3 over \u03b2-MnO2 and \u03b1-Mn2O3","volume":"99","author":"Tang","year":"2010","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"5946","DOI":"10.1021\/acs.est.9b01217","article-title":"Fe2O3-CeO2@Al2O3 Nano-arrays on Al-Mesh as SO2-tolerant monolith catalysts for NOx reduction by NH3","volume":"53","author":"Han","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"160","DOI":"10.1016\/j.apcatb.2009.12.023","article-title":"Sulfur poisoning resistant mesoporous Mn-base catalyst for low-temperature SCR of NO with NH3","volume":"95","author":"Yu","year":"2010","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"6462","DOI":"10.1021\/acs.est.9b00435","article-title":"SO2-tolerant selective catalytic reduction of NOx over meso-TiO2@Fe2O3@Al2O3 metal-based monolith catalysts","volume":"53","author":"Han","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"9821","DOI":"10.1039\/c3nr03150k","article-title":"Design of meso-TiO2@MnOx-CeOx\/CNTs with a core-shell structure as DeNOx catalysts: Promotion of activity, stability and SO2-tolerance","volume":"5","author":"Zhang","year":"2013","journal-title":"Nanoscale"},{"key":"ref_20","first-page":"11","article-title":"Preparation of tourmaline fine stone particles and introduction of related research","volume":"96","author":"Ma","year":"2020","journal-title":"China Powder Ind."},{"key":"ref_21","first-page":"24","article-title":"Research status and application of high-efficiency far-infrared radiation ceramics","volume":"26","author":"Li","year":"2005","journal-title":"Mod. Tech. Ceram."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"277","DOI":"10.1016\/S1002-0721(07)60380-9","article-title":"Preparation and characterization of rare earth composite materials radiating far infrared for activating liquefied petroleum gas","volume":"24","author":"Zhu","year":"2006","journal-title":"J. Rare Earths"},{"key":"ref_23","first-page":"331","article-title":"Research progress and prospects of tourmaline functional composite materials","volume":"21","author":"Hu","year":"2014","journal-title":"Front. Earth Sci.-Prc."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"137023","DOI":"10.1016\/j.electacta.2020.137023","article-title":"Improving the electrocatalytic performance of Pd for formic acid electrooxidation by introducing tourmaline","volume":"360","author":"Luo","year":"2020","journal-title":"Electrochim. Acta"},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Helian, Y., Cui, S., and Ma, X. (2020). The effect of tourmaline on SCR denitrification activity of MnOx\/TiO2 at low temperature. Catalysts, 10.","DOI":"10.3390\/catal10091020"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"04017053","DOI":"10.1061\/(ASCE)EE.1943-7870.0001246","article-title":"Influence of tourmaline on the anaerobic ammonium oxidation process in sequencing batch reactors","volume":"143","author":"Tan","year":"2017","journal-title":"J. Environ. Eng."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"128242","DOI":"10.1016\/j.cej.2020.128242","article-title":"Active sites adjustable phosphorus promoted CeO2\/TiO2 catalysts for selective catalytic reduction of NOx by NH3","volume":"409","author":"Zeng","year":"2021","journal-title":"Chem. Eng. J."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"160","DOI":"10.1016\/j.apcata.2015.01.013","article-title":"Influence of tungsten on the activity of a Mn\/Ce\/W\/Ti catalyst for the selective catalytic reduction of NO with NH3 at low temperatures","volume":"497","author":"Kwon","year":"2015","journal-title":"Appl. Catal. A-Gen."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"113767","DOI":"10.1016\/j.mcat.2023.113767","article-title":"Mn MOF-derivatives synthesized based upon a mechanochemistry method for low-temperature NH3- SCR: From amorphous precursor to amorphous catalyst","volume":"554","author":"Li","year":"2024","journal-title":"Mol. Catal."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/j.apcatb.2011.01.001","article-title":"Catalytic oxidation of toluene over binary mixtures of copper, manganese and cerium oxides supported on \u03b3-Al2O3","volume":"103","author":"Saqer","year":"2011","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"10834","DOI":"10.1039\/c3ra47076h","article-title":"Catalytic behavior of supported Ru nanoparticles on the (101) and (001) facets of anatase TiO2","volume":"4","author":"Wang","year":"2014","journal-title":"RSC Adv."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1016\/j.cej.2019.03.054","article-title":"Effect of preferential exposure of anatase TiO2 {001} facets on the performance of Mn-Ce\/TiO2 catalysts for low-temperature selective catalytic reduction of NOx with NH3","volume":"369","author":"Li","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1016\/j.cattod.2019.08.018","article-title":"Environmentally-friendly tourmaline modified CeMnFeOx catalysts for low-temperature selective catalytic reduction of NOx with NH3","volume":"355","author":"Zhao","year":"2020","journal-title":"Catal. Today"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"279","DOI":"10.1016\/j.jes.2020.01.011","article-title":"Effect of SiO2 addition on NH4HSO4 decomposition and SO2 poisoning over V2O5-MoO3\/TiO2-CeO2 catalyst","volume":"91","author":"Zheng","year":"2020","journal-title":"J. Environ. Sci."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"350","DOI":"10.1016\/j.jhazmat.2014.05.071","article-title":"Promotion effects of SiO2 or\/and Al2O3 doped CeO2\/TiO2 catalysts for selective catalytic reduction of NO by NH3","volume":"278","author":"Zhao","year":"2014","journal-title":"J. Hazard. Mater."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1419","DOI":"10.1126\/science.aao2109","article-title":"Activation of surface lattice oxygen in single-atom Pt\/CeO2 for low-temperature CO oxidation","volume":"358","author":"Nie","year":"2017","journal-title":"Science"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"4268","DOI":"10.1021\/acscatal.9b04654","article-title":"Single-Facet Dominant Anatase TiO2 (101) and (001) Model Catalysts to Elucidate the Active Sites for Alkanol Dehydration","volume":"10","author":"Lin","year":"2020","journal-title":"ACS Catal."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"10850","DOI":"10.1039\/C9NJ02102G","article-title":"Effect of ceria loading on Zr-pillared clay catalysts for selective catalytic reduction of NO with NH3","volume":"43","author":"Cheng","year":"2019","journal-title":"New J. Chem."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1016\/j.jcat.2010.08.016","article-title":"Cr-MnOx mixed-oxide catalysts for selective catalytic reduction of NOx with NH3 at low temperature","volume":"276","author":"Chen","year":"2010","journal-title":"J. Catal."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jes.2020.07.027","article-title":"Improvement of the activity and SO2 tolerance of Sb-modified Mn\/PG catalysts for NH3-SCR at a low temperature","volume":"101","author":"Zhang","year":"2021","journal-title":"J. Environ. Sci."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"125790","DOI":"10.1016\/j.colsurfa.2020.125790","article-title":"Mn-Fe-Ce multiple oxides with Al2O3 coating supported onto honeycomb cordierite monoliths for NO catalytic oxidation","volume":"611","author":"Tang","year":"2021","journal-title":"Colloid Surf. A"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"110562","DOI":"10.1016\/j.mcat.2019.110562","article-title":"New insight into the synergistic promotion effect of phosphorus and molybdenum on the ceria-titanium catalysts for superior SCR performance","volume":"478","author":"Zhang","year":"2019","journal-title":"Mol. Catal."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"147999","DOI":"10.1016\/j.apsusc.2020.147999","article-title":"The property tuning of NH3-SCR over iron-tungsten catalyst: Role of calcination temperature on surface defect and acidity","volume":"538","author":"Zhang","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"119133","DOI":"10.1016\/j.fuel.2020.119133","article-title":"Environmental-friendly production of FeNbTi catalyst with significant enhancement in SCR activity and SO2 resistance for NOx removal","volume":"285","author":"Hou","year":"2021","journal-title":"Fuel"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.apcata.2017.07.024","article-title":"Nb-modified Mn\/Ce\/Ti catalyst for the selective catalytic reduction of NO with NH3 at low temperature","volume":"545","author":"Zhao","year":"2017","journal-title":"Appl. Catal. A-Gen."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"15161","DOI":"10.1039\/C9NJ03461G","article-title":"MnOx-CeO2@TiO2 core-shell composites for low temperature SCR of NOx","volume":"43","author":"Ma","year":"2019","journal-title":"New J. Chem."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"3470","DOI":"10.1039\/C4CC09719J","article-title":"Improved low temperature NH3-SCR performance of FeMnTiOx mixed oxide with CTAB-assisted synthesis","volume":"51","author":"Wu","year":"2015","journal-title":"Chem. Commun."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"7803","DOI":"10.1021\/acs.jpcc.6b12772","article-title":"Improvement of Nb doping on SO2 resistance of VOx\/CeO2 catalyst for the selective catalytic reduction of NOx with NH3","volume":"121","author":"Lian","year":"2017","journal-title":"J. Phys. Chem. C"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"122597","DOI":"10.1016\/j.cej.2019.122597","article-title":"Effect of SO2 on the low-temperature denitrification performance of Ho-modified Mn\/Ti catalyst","volume":"400","author":"Zhang","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"123011","DOI":"10.1016\/j.jhazmat.2020.123011","article-title":"A MnOx@Eu-CeOx nanorod catalyst with multiple protective effects: Strong SO2-tolerance for low temperature DeNOx processes","volume":"399","author":"Yu","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"122947","DOI":"10.1016\/j.jhazmat.2020.122947","article-title":"Boosting the alkali\/heavy metal poisoning resistance for no removal by using iron-titanium pillared montmorillonite catalysts","volume":"399","author":"Xu","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"ref_52","doi-asserted-by":"crossref","unstructured":"Gan, L., Li, K., Niu, H., Peng, Y., Chen, J., Huang, Y., and Li, J. (2021). Simultaneous removal of NOx and chlorobenzene on V2O5\/TiO2 granular catalyst: Kinetic study and performance prediction. Front. Environ. Sci. Eng., 15.","DOI":"10.1007\/s11783-020-1363-5"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"582","DOI":"10.1016\/j.apcatb.2013.09.016","article-title":"The role of cerium in the improved SO2 tolerance for NO reduction with NH3 over Mn-Ce\/TiO2 catalyst at low temperature","volume":"148","author":"Jin","year":"2014","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"371","DOI":"10.1016\/j.apcatb.2014.03.030","article-title":"SO2 poisoning impact on the NH3-SCR reaction over a commercial Cu-SAPO-34 SCR catalyst","volume":"156\u2013157","author":"Zhang","year":"2014","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1016\/j.apcatb.2016.10.010","article-title":"Efficient NH3-SCR removal of NOx with highly ordered mesoporous WO3(x)-CeO2 at low temperatures","volume":"203","author":"Zhan","year":"2017","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"17727","DOI":"10.1021\/acssuschemeng.0c05862","article-title":"Rationally tailored redox properties of a mesoporous Mn-Fe spinel nanostructure for boosting low-temperature selective catalytic reduction of NOx with NH3","volume":"8","author":"Wei","year":"2020","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"120056","DOI":"10.1016\/j.fuel.2020.120056","article-title":"The decomposition of Mn-substituted siderite during coaling enhanced the transformation of NO before catalyst bed: Effect of Mn substitution","volume":"290","author":"Shu","year":"2021","journal-title":"Fuel"},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"630","DOI":"10.1021\/la970993n","article-title":"A vibrational and spectroscopic study of WO3\/TiO2-Al2O3 catalyst precursors","volume":"14","author":"Ramirez","year":"1998","journal-title":"Langmuir"},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"104399","DOI":"10.1016\/j.jece.2020.104399","article-title":"Effect of hierarchical element doping on the low-temperature activity of manganese-based catalysts for NH3-SCR","volume":"8","author":"Tang","year":"2020","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1016\/j.cej.2017.02.042","article-title":"Promotional mechanisms of activity and SO2 tolerance of Co- or Ni-doped MnOx-CeO2 catalysts for SCR of NOx with NH3 at low temperature","volume":"317","author":"Gao","year":"2017","journal-title":"Chem. Eng. J."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"369","DOI":"10.1016\/j.apcatb.2011.01.044","article-title":"Influence of sulfation on iron titanate catalyst for the selective catalytic reduction of NOx with NH3","volume":"10","author":"Liu","year":"2011","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"1037","DOI":"10.1016\/j.apsusc.2017.11.180","article-title":"In situ DRIFTS investigation of NH3-SCR reaction over CeO2\/zirconium phosphate catalyst","volume":"435","author":"Zhang","year":"2018","journal-title":"Appl. Surf. Sci."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.apcatb.2011.08.027","article-title":"Low temperature selective catalytic reduction of NO with NH3 over Mn-Fe spinel: Performance, mechanism and kinetic study","volume":"110","author":"Yang","year":"2011","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"125258","DOI":"10.1016\/j.jhazmat.2021.125258","article-title":"Insight into the reaction mechanism over PMoA for low temperature NH3-SCR: A combined In-situ DRIFTs and DFT transition state calculations","volume":"412","author":"Jia","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"125756","DOI":"10.1016\/j.jclepro.2020.125756","article-title":"Mineral-derived catalysts optimized for selective catalytic reduction of NOx with NH3","volume":"289","author":"Xing","year":"2021","journal-title":"J. Clean. Prod."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"9590","DOI":"10.1021\/es102692b","article-title":"DRIFT study on Cerium-Tungsten\/Titiania catalyst for selective catalytic reduction of NOx with NH3","volume":"44","author":"Chen","year":"2010","journal-title":"Environ. Sci. Technol."},{"key":"ref_67","unstructured":"Ren, W. (2010). Research on Denitration Mechanism and Preparation of Ferrous Sulfate SCR Catalyst. [Ph.D. Thesis, Tsinghua University]."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1016\/j.apcata.2007.05.024","article-title":"Manganese oxide catalysts for NOx reduction with NH3 at low temperatures","volume":"327","author":"Kang","year":"2007","journal-title":"Appl. Catal. A Gen."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1007\/s10562-005-9194-3","article-title":"Novel MnOx Catalysts for NO Reduction at Low Temperature with Ammonia","volume":"106","author":"Kang","year":"2006","journal-title":"Catal. Lett."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/0926-3373(93)E0034-9","article-title":"Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia","volume":"3","author":"Kapteijn","year":"1994","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"4491","DOI":"10.1021\/ie010218+","article-title":"Selective Catalytic Reduction of Nitrogen Oxides with NH3 over Natural Manganese Ore at Low Temperature, Ind","volume":"40","author":"Park","year":"2001","journal-title":"Eng. Chem. Res."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"236","DOI":"10.1016\/j.cattod.2005.10.032","article-title":"Cu\u2013Mn mixed oxides for low temperature NO reduction with NH3","volume":"111","author":"Kang","year":"2006","journal-title":"Catal. Today"},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/j.apcatb.2004.01.023","article-title":"MnOx-CeO2 mixed oxides prepared by co-precipitation for selective catalytic reduction of NO with NH3 at low temperatures","volume":"51","author":"Qi","year":"2004","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"434","DOI":"10.1016\/S0021-9517(03)00081-2","article-title":"Performance and kinetics study for low-temperature SCR of NO with NH3 over MnOx\u2013CeO2 catalyst","volume":"217","author":"Qi","year":"2003","journal-title":"J. Catal."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1039\/b111382h","article-title":"Low temperature selective catalytic reduction (SCR) of NO with NH3 over Fe\u2013Mn based catalysts","volume":"5","author":"Long","year":"2002","journal-title":"Chem. Commun."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"194","DOI":"10.1016\/j.apcatb.2009.09.029","article-title":"Effect of manganese substitution on the structure and activity of iron titanate catalyst for the selective catalytic reduction of NO with NH3","volume":"93","author":"Liu","year":"2009","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"70","DOI":"10.1016\/j.cattod.2010.02.043","article-title":"Selective catalytic reduction of NO with NH3 over manganese substituted iron titanate catalyst: Reaction mechanism and H2O\/SO2 inhibition mechanism study","volume":"153","author":"Liu","year":"2010","journal-title":"Catal. Today"},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"531","DOI":"10.1016\/S1872-2067(08)60049-2","article-title":"MnOx-SnO2 Catalysts Synthesized by a Redox Coprecipitation Method for Selective Catalytic Reduction of NO by NH3","volume":"29","author":"Tang","year":"2008","journal-title":"Chin. J. Catal."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"297","DOI":"10.1016\/0926-3373(92)80055-5","article-title":"Alumina supported manganese oxides for the low-temperature selective catalytic reduction of nitric oxide with ammonia","volume":"1","author":"Singoredjo","year":"1992","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"6436","DOI":"10.1021\/ie060484t","article-title":"Manganese Oxide Catalysts Supported on TiO2, Al2O3, and SiO2:\u2009 A Comparison for Low-Temperature SCR of NO with NH3","volume":"45","author":"Smirniotis","year":"2006","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"1896","DOI":"10.1016\/j.catcom.2007.03.007","article-title":"Effects of precursors on the surface Mn species and the activities for NO reduction over MnOx\/TiO2 catalysts","volume":"8","author":"Li","year":"2007","journal-title":"Catal. Commun."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"2217","DOI":"10.1016\/j.catcom.2008.05.001","article-title":"Ceria modified MnOx\/TiO2 as a superior catalyst for NO reduction with NH3 at low-temperature","volume":"9","author":"Wu","year":"2008","journal-title":"Catal. Commun."},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1016\/j.apcatb.2008.10.014","article-title":"Screening of doped MnOx\u2013CeO2 catalysts for low-temperature NO-SCR","volume":"88","author":"Casapu","year":"2009","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"406","DOI":"10.1016\/j.cattod.2007.06.013","article-title":"Low-temperature SCR of NO with NH3 over AC\/C supported manganese-based monolithic catalysts","volume":"126","author":"Tang","year":"2007","journal-title":"Catal. Today"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/17\/4079\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T15:44:27Z","timestamp":1760111067000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/17\/4079"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,8,28]]},"references-count":84,"journal-issue":{"issue":"17","published-online":{"date-parts":[[2024,9]]}},"alternative-id":["molecules29174079"],"URL":"https:\/\/doi.org\/10.3390\/molecules29174079","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,8,28]]}}}