{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:27:16Z","timestamp":1760146036097,"version":"build-2065373602"},"reference-count":36,"publisher":"MDPI AG","issue":"19","license":[{"start":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T00:00:00Z","timestamp":1727654400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"EPSRC","doi-asserted-by":"publisher","award":["EPSRC EP\/L016443\/1"],"award-info":[{"award-number":["EPSRC EP\/L016443\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Ring size-dependent diastereoselective coordination of unsymmetrical diamines containing one azacyclic nitrogen and one exocyclic nitrogen to [(\u03b75-C5Me5)MCl]+ cores where M = Rh, Ir and [Ru(\u03b76-cymene)Cl]+ is reported herein. Total stereoselectivity was observed with the six- and seven-membered azacycles, whereas the five-derivative proved poorly selective. All complexes were active for transfer hydrogenation but showed no enantioselectivity with prochiral ketones.<\/jats:p>","DOI":"10.3390\/molecules29194659","type":"journal-article","created":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T11:32:05Z","timestamp":1727695925000},"page":"4659","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ringing the Changes: Effects of Heterocyclic Ring Size on Stereoselectivity in [(\u03b75-C5Me5)RhCl], [(\u03b75-C5Me5)IrCl] and [Ru(\u03b76-cymene)Cl] Complexes of Chiral 3-Amino-1-Azacycles"],"prefix":"10.3390","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3669-4804","authenticated-orcid":false,"given":"Vladimir Y.","family":"Vladimirov","sequence":"first","affiliation":[{"name":"School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Matheo","family":"Charrier-Chardin","sequence":"additional","affiliation":[{"name":"School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8658-3897","authenticated-orcid":false,"given":"Benson M.","family":"Kariuki","sequence":"additional","affiliation":[{"name":"School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1406-5940","authenticated-orcid":false,"given":"Benjamin D.","family":"Ward","sequence":"additional","affiliation":[{"name":"School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1808-1211","authenticated-orcid":false,"given":"Paul D.","family":"Newman","sequence":"additional","affiliation":[{"name":"School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,9,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3153","DOI":"10.1039\/c2cs15234g","article-title":"Chiral-at-metal complexes and their catalytic applications in organic synthesis","volume":"41","author":"Bauer","year":"2012","journal-title":"Chem. 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