{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:34:24Z","timestamp":1760146464216,"version":"build-2065373602"},"reference-count":36,"publisher":"MDPI AG","issue":"21","license":[{"start":{"date-parts":[[2024,11,2]],"date-time":"2024-11-02T00:00:00Z","timestamp":1730505600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Shanxi Province Science Foundation","award":["202303021211194","20210302124333","J20231305","SKLCC202204"],"award-info":[{"award-number":["202303021211194","20210302124333","J20231305","SKLCC202204"]}]},{"name":"Shanxi Province Collegiate Education Innovation Project","award":["202303021211194","20210302124333","J20231305","SKLCC202204"],"award-info":[{"award-number":["202303021211194","20210302124333","J20231305","SKLCC202204"]}]},{"name":"Research Foundation of the Chinese State Key Laboratory of Coordination Chemistry","award":["202303021211194","20210302124333","J20231305","SKLCC202204"],"award-info":[{"award-number":["202303021211194","20210302124333","J20231305","SKLCC202204"]}]},{"name":"Taiyuan Institute of Technology Scientific Research Initial Funding","award":["202303021211194","20210302124333","J20231305","SKLCC202204"],"award-info":[{"award-number":["202303021211194","20210302124333","J20231305","SKLCC202204"]}]},{"name":"Shanxi \u201c1331\u201d Project, and a program for the (Reserved) Discipline Leaders of Taiyuan Institute of Technology","award":["202303021211194","20210302124333","J20231305","SKLCC202204"],"award-info":[{"award-number":["202303021211194","20210302124333","J20231305","SKLCC202204"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A d10-Cd cluster containing sandwich-type arsenotungstate [C3H12N2]6[Cd4Cl2(B-\u03b1-AsW9O34)2] was synthesized and its structure characterized through elemental analyses, X-ray powder diffraction (XRPD), IR spectroscopy, X-ray photoelectron spectroscopy (XPS), and single-crystal X-ray diffraction. The X-ray analysis revealed that the molecular unit of the compound consists of a captivating tetra-Cd-substituted sandwich-type polyoxoanion, accompanied by six elegantly protonated 1,2-diaminopropane as counter ions. The further novelty of the tetranuclear cadmium cluster lies in its occupied chlorine atom sites. This makes it highly susceptible to coordinate reactions with nitrogen on polycyclic aromatic hydrocarbons, thereby exhibiting different fluorescent signals that facilitate the identification and detection of these carcinogenic substances in methanol.<\/jats:p>","DOI":"10.3390\/molecules29215193","type":"journal-article","created":{"date-parts":[[2024,11,4]],"date-time":"2024-11-04T09:52:54Z","timestamp":1730713974000},"page":"5193","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A d10-Cd Cluster Containing Sandwich-Type Arsenotungstate Exhibiting Fluorescent Recognition of Carcinogenic Dye in Methanol"],"prefix":"10.3390","volume":"29","author":[{"given":"Feng","family":"Wang","sequence":"first","affiliation":[{"name":"Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7679-5741","authenticated-orcid":false,"given":"Xiang","family":"Ma","sequence":"additional","affiliation":[{"name":"Laboratory of Biochemistry and Pharmacy, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Haodong","family":"Li","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ziqi","family":"Zhao","sequence":"additional","affiliation":[{"name":"Laboratory of Biochemistry and Pharmacy, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lele","family":"Zhang","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yutong","family":"Zhao","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Haipeng","family":"Su","sequence":"additional","affiliation":[{"name":"Laboratory of Biochemistry and Pharmacy, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zeqi","family":"Wang","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Changchun","family":"Li","sequence":"additional","affiliation":[{"name":"Laboratory of Biochemistry and Pharmacy, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jiai","family":"Hua","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan 030008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,11,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Yang, Y.Q., Kong, L.R., Ding, Y., Xia, L.X., Cao, S., and Song, P. 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SAINT, Version 7.68A, Bruker AXS, Inc."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/21\/5193\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T16:27:26Z","timestamp":1760113646000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/21\/5193"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,2]]},"references-count":36,"journal-issue":{"issue":"21","published-online":{"date-parts":[[2024,11]]}},"alternative-id":["molecules29215193"],"URL":"https:\/\/doi.org\/10.3390\/molecules29215193","relation":{},"ISSN":["1420-3049"],"issn-type":[{"type":"electronic","value":"1420-3049"}],"subject":[],"published":{"date-parts":[[2024,11,2]]}}}