{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T02:06:45Z","timestamp":1783390005840,"version":"3.54.6"},"reference-count":53,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2024,11,24]],"date-time":"2024-11-24T00:00:00Z","timestamp":1732406400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Agricultural Scientific and Technological Innovation Project of the Shandong Academy of Agricultural Sciences","award":["CXGC2023D01"],"award-info":[{"award-number":["CXGC2023D01"]}]},{"name":"Agricultural Scientific and Technological Innovation Project of the Shandong Academy of Agricultural Sciences","award":["CXGC2023F04"],"award-info":[{"award-number":["CXGC2023F04"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Peroxymonosulfate (PMS)-based advanced oxidation processes have shown potential for the removal of organic contaminants; however, the preparation of catalysts with high degradation efficiencies and rapid reaction rates remains a challenge. In this study, we have successfully synthesized CoFe bimetallic modified corn cob-derived biochar (CoFe\/BC) for the activation of PMS, achieving the rapid and efficient degradation of bisphenol F (BPF). The synthesized CoFe\/BC catalyst demonstrated excellent catalytic performance, achieving over 99% removal within 3 min and exhibiting a removal rate of 90.0% after five cycles. This could be attributed to the cyclic transformation of Co and Fe, which sustained rapid PMS activation for BPF degradation, and Co0\/Fe0 played a significant role in the cyclic transformation. Furthermore, the electron paramagnetic resonance tests confirmed that \u2022SO4\u2212 and \u2022OH were the primary reactive oxygen species, while \u2022O2\u2212 played a minor role in BPF degradation. This study highlights the high degradation efficiency, rapid reaction rate, excellent magnetic separation properties, and exceptional reusability of CoFe\/BC catalysts for BPF removal, providing valuable insights for practical wastewater treatment.<\/jats:p>","DOI":"10.3390\/molecules29235545","type":"journal-article","created":{"date-parts":[[2024,11,25]],"date-time":"2024-11-25T08:38:24Z","timestamp":1732523904000},"page":"5545","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Rapid Degradation of Bisphenol F Using Magnetically Separable Bimetallic Biochar Composite Activated by Peroxymonosulfate"],"prefix":"10.3390","volume":"29","author":[{"given":"Hui","family":"Liang","sequence":"first","affiliation":[{"name":"Institute of Plant Protection, Shandong Academy of Agricultural Sciences, Jinan 250100, China"},{"name":"Shandong Key Laboratory for Green Prevention and Control of Agricultural Pests, Jinan 250100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruijuan","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Plant Protection, Shandong Academy of Agricultural Sciences, Jinan 250100, China"},{"name":"Shandong Key Laboratory for Green Prevention and Control of Agricultural Pests, Jinan 250100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tongjin","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Plant Protection, Shandong Academy of Agricultural Sciences, Jinan 250100, China"},{"name":"Shandong Key Laboratory for Green Prevention and Control of Agricultural Pests, Jinan 250100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rumei","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Plant Protection, Shandong Academy of Agricultural Sciences, Jinan 250100, China"},{"name":"Shandong Key Laboratory for Green Prevention and Control of Agricultural Pests, Jinan 250100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuxiao","family":"Zhu","sequence":"additional","affiliation":[{"name":"Institute of Plant Protection, Shandong Academy of Agricultural Sciences, Jinan 250100, China"},{"name":"Shandong Key Laboratory for Green Prevention and Control of Agricultural Pests, Jinan 250100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Fang","sequence":"additional","affiliation":[{"name":"Institute of Plant Protection, Shandong Academy of Agricultural Sciences, Jinan 250100, China"},{"name":"Shandong Key Laboratory for Green Prevention and Control of Agricultural Pests, Jinan 250100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,11,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"146905","DOI":"10.1016\/j.scitotenv.2021.146905","article-title":"Biomonitoring of occupational exposure to bisphenol A, bisphenol S and bisphenol F: A systematic review","volume":"783","author":"Bousoumah","year":"2021","journal-title":"Sci. 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