{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T08:42:39Z","timestamp":1780044159020,"version":"3.53.1"},"reference-count":67,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2024,11,25]],"date-time":"2024-11-25T00:00:00Z","timestamp":1732492800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001665","name":"ANR ChOZe","doi-asserted-by":"publisher","award":["ANR-13-BS07-0017"],"award-info":[{"award-number":["ANR-13-BS07-0017"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"ANR ChOZe","doi-asserted-by":"publisher","award":["202008440326"],"award-info":[{"award-number":["202008440326"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"name":"CNRS","award":["ANR-13-BS07-0017"],"award-info":[{"award-number":["ANR-13-BS07-0017"]}]},{"name":"CNRS","award":["202008440326"],"award-info":[{"award-number":["202008440326"]}]},{"name":"Minist\u00e8re de l\u2019Enseignement Sup\u00e9rieur et de la Recherche","award":["ANR-13-BS07-0017"],"award-info":[{"award-number":["ANR-13-BS07-0017"]}]},{"name":"Minist\u00e8re de l\u2019Enseignement Sup\u00e9rieur et de la Recherche","award":["202008440326"],"award-info":[{"award-number":["202008440326"]}]},{"name":"China Scholarship Council","award":["ANR-13-BS07-0017"],"award-info":[{"award-number":["ANR-13-BS07-0017"]}]},{"name":"China Scholarship Council","award":["202008440326"],"award-info":[{"award-number":["202008440326"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Due to the importance of biaryls as natural products, drugs, agrochemicals, dyes, or organic electronic materials, a green alternative biaryl synthesis has been developed based on easy-to-prepare and cheap copper(I)-exchanged zeolite catalysts. CuI-USY proved to efficiently catalyze the direct homocoupling of either phenols or aryl boronic acids under simple and practical conditions. The CuI-USY-catalyzed oxidative homocoupling of phenols could conveniently be performed under air either in warm methanol or water with good to high yields. In methanol, a small amount of Cs2CO3 was required, while none was necessary in water. The homocoupling of aryl boronic acids was best performed also in warm methanol, without an additive. These mild conditions showed good functional-group tolerance, leading to a variety of substituted (hetero)biaryls (28 examples). The heterogeneous CuI-USY catalyst could readily be recovered and reused. Interestingly, the homocoupling of vinyl boronic acids was successfully coupled to a Diels\u2013Alder reaction, even in a one-pot process, allowing access to highly functionalized cyclohexenes.<\/jats:p>","DOI":"10.3390\/molecules29235552","type":"journal-article","created":{"date-parts":[[2024,11,25]],"date-time":"2024-11-25T08:38:24Z","timestamp":1732523904000},"page":"5552","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["CuI-Zeolite Catalysis for Biaryl Synthesis via Homocoupling Reactions of Phenols or Aryl Boronic Acids"],"prefix":"10.3390","volume":"29","author":[{"given":"Xiaohui","family":"Di","sequence":"first","affiliation":[{"name":"Catalyse Organom\u00e9tallique, Synth\u00e8se Organique et Sant\u00e9 (COSyS), Institut de Chimie (UMR-CNRS 7177), Universit\u00e9 de Strasbourg, 67000 Strasbourg, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tony","family":"Garnier","sequence":"additional","affiliation":[{"name":"Catalyse Organom\u00e9tallique, Synth\u00e8se Organique et Sant\u00e9 (COSyS), Institut de Chimie (UMR-CNRS 7177), Universit\u00e9 de Strasbourg, 67000 Strasbourg, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arnaud","family":"Clerc","sequence":"additional","affiliation":[{"name":"Catalyse Organom\u00e9tallique, Synth\u00e8se Organique et Sant\u00e9 (COSyS), Institut de Chimie (UMR-CNRS 7177), Universit\u00e9 de Strasbourg, 67000 Strasbourg, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eliott","family":"Jung","sequence":"additional","affiliation":[{"name":"Catalyse Organom\u00e9tallique, Synth\u00e8se Organique et Sant\u00e9 (COSyS), Institut de Chimie (UMR-CNRS 7177), Universit\u00e9 de Strasbourg, 67000 Strasbourg, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5427-5040","authenticated-orcid":false,"given":"Christian","family":"Lherbet","sequence":"additional","affiliation":[{"name":"LSPCMIB, UMR CNRS UPS 5068, Universit\u00e9 Toulouse 3 Paul Sabatier, 118 Route de Narbonne, 31062 Toulouse cedex 9, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Val\u00e9rie","family":"B\u00e9n\u00e9teau","sequence":"additional","affiliation":[{"name":"Catalyse Organom\u00e9tallique, Synth\u00e8se Organique et Sant\u00e9 (COSyS), Institut de Chimie (UMR-CNRS 7177), Universit\u00e9 de Strasbourg, 67000 Strasbourg, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3924-530X","authenticated-orcid":false,"given":"Patrick","family":"Pale","sequence":"additional","affiliation":[{"name":"Catalyse Organom\u00e9tallique, Synth\u00e8se Organique et Sant\u00e9 (COSyS), Institut de Chimie (UMR-CNRS 7177), Universit\u00e9 de Strasbourg, 67000 Strasbourg, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5842-5288","authenticated-orcid":false,"given":"Stefan","family":"Chassaing","sequence":"additional","affiliation":[{"name":"Catalyse Organom\u00e9tallique, Synth\u00e8se Organique et Sant\u00e9 (COSyS), Institut de Chimie (UMR-CNRS 7177), Universit\u00e9 de Strasbourg, 67000 Strasbourg, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,11,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1633","DOI":"10.1002\/cber.18840170219","article-title":"Ueber die Ersetzung der Amidgruppe durch Chlor in den aromatischen Substanzen","volume":"17","author":"Sandmeyer","year":"1884","journal-title":"Ber. 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