{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T00:25:01Z","timestamp":1759883101868,"version":"build-2065373602"},"reference-count":166,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2025,1,2]],"date-time":"2025-01-02T00:00:00Z","timestamp":1735776000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Network 4 Energy Sustainable Transition-NEST","award":["PE000021","CUP C93C22005230007"],"award-info":[{"award-number":["PE000021","CUP C93C22005230007"]}]},{"name":"NextGenerationEu PNRR plan","award":["PE000021","CUP C93C22005230007"],"award-info":[{"award-number":["PE000021","CUP C93C22005230007"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The main categories of transition metal\u2013mercury heterometallic compounds are briefly summarized. The attention is focused on complexes and clusters where the {Hg-Y} fragment, where Y represents a halide atom, interacts with transition metals. Most of the structurally characterized derivatives are organometallic compounds where the transition metals belong to the Groups 6, 8, 9 and 10. More than one {Hg-Y} group can be present in the same compound, interacting with the same or with different transition metals. The main synthetic strategies are discussed, and structural data of representative compounds are reported. According to the isolobality with hydrogen, {Hg-Y} can form from one to three M-{Hg-Y} bonds, but further interactions can be present, such as mercurophilic and Hg\u00b7\u00b7\u00b7halide contacts. The formal oxidation state of mercury is sometimes ambiguous and thus {Hg-Y} can be considered as a Lewis acid or base on varying the transition metal fragment. Density functional theory calculations on selected Group 6 and Group 9 model compounds are provided in order to shed light on this aspect.<\/jats:p>","DOI":"10.3390\/molecules30010145","type":"journal-article","created":{"date-parts":[[2025,1,2]],"date-time":"2025-01-02T06:05:10Z","timestamp":1735797910000},"page":"145","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Mercury Monohalides as Ligands in Transition Metal Complexes"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9450-0481","authenticated-orcid":false,"given":"Matteo","family":"Busato","sequence":"first","affiliation":[{"name":"Dipartimento di Chimica, Sapienza Universit\u00e0 di Roma, P.le Aldo Moro 5, 00185 Rome, Italy"},{"name":"Dipartimento di Scienze Molecolari e Nanosistemi, Universit\u00e0 Ca\u2019 Foscari Venezia, 30172 Mestre, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6169-3822","authenticated-orcid":false,"given":"Jes\u00fas","family":"Castro","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica, Facultade de Qu\u00edmica, Universidade de Vigo, Edificio de Ciencias Experimentais, 36310 Vigo, Galicia, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Domenico","family":"Piccolo","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Sapienza Universit\u00e0 di Roma, P.le Aldo Moro 5, 00185 Rome, Italy"},{"name":"Dipartimento di Scienze Chimiche, Universit\u00e0 di Padova, Via Marzolo 1, 35131 Padova, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4259-1027","authenticated-orcid":false,"given":"Marco","family":"Bortoluzzi","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Sapienza Universit\u00e0 di Roma, P.le Aldo Moro 5, 00185 Rome, Italy"},{"name":"CIRCC (Consorzio Universitario Reattivit\u00e0 Chimica e Catalisi), Via Celso Ulpiani 27, 70126 Bari, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,1,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1351\/pac196510010011","article-title":"Metal-metal interaction in transition metal complexes","volume":"10","author":"Lewis","year":"1965","journal-title":"Pure Appl. Chem."},{"key":"ref_2","first-page":"983","article-title":"Compounds with Bonds between Transition Metals and either Mercury, Cadmium, Zinc or Magnesium","volume":"Volume 6","author":"Wilkinson","year":"1982","journal-title":"Comprehensive Organometallic Chemistry"},{"key":"ref_3","first-page":"1","article-title":"Mercury as a Ligand","volume":"Volume 2","author":"Wilkinson","year":"1987","journal-title":"Comprehensive Coordination Chemistry"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"24","DOI":"10.1002\/anie.199300241","article-title":"Mercury, a Structural Building Block and Source of Localized Reactivity in Extended Metal-Metal Bonded Systems","volume":"32","author":"Gade","year":"1993","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_5","first-page":"323","article-title":"Cluster Complexes with Bonds Between Transition Elements and Zinc, Cadmium, and Mercury","volume":"Volume 10","author":"Abel","year":"1995","journal-title":"Comprehensive Organometallic Chemistry II"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1016\/S0020-1693(02)01453-6","article-title":"New Pt-Hg clusters with pentachlorophenyl groups","volume":"347","author":"Ara","year":"2003","journal-title":"Inorg. Chim. Acta"},{"key":"ref_7","first-page":"4091","article-title":"Synthesis and Characterization of the Dimercury(I)-Linked Compound [PPN]4[(Re7C(CO)21Hg)2]. Oxidative Cleavage of the Mercury-Mercury Bond Leading to Carbidoheptarhenate Complexes of Mercury(II), Including [PPN][Re7C(CO)21Hg(S=C(NMe2)2)]","volume":"40","author":"Wright","year":"2021","journal-title":"Inorg. Chem."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"6553","DOI":"10.1021\/ic020439n","article-title":"Pd(0) and Pt(0) Metallocryptands Encapsulating a Spinning Mercurous Dimer","volume":"41","author":"Catalano","year":"2002","journal-title":"Inorg. Chem."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"234","DOI":"10.1021\/om049251x","article-title":"Cage-Type Hexanuclear Platinum(0) Clusters with Diphosphine and Isocyanide Ligands Encapsulating Two Mercury(0) Atoms","volume":"24","author":"Tanase","year":"2005","journal-title":"Organometallics"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1547","DOI":"10.1002\/zaac.200300107","article-title":"Single Crystal Growth and Crystal Structure of Anhydrous Mercury(I) Nitrate, Hg2(NO3)2","volume":"629","author":"Weil","year":"2003","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"2946","DOI":"10.1039\/C4CC09743B","article-title":"Homolytic H2 cleavage by a mercury-bridged Ni(I) pincer complex [{(PNP)Ni}2{\u03bc-Hg}]","volume":"51","author":"Kreye","year":"2015","journal-title":"Chem. Commun."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1016\/0022-328X(91)86096-9","article-title":"Unexpected metal-metal bond formation in the M-Hg-M (M = Cr, Mo, W) structural unit. Synthesis and characterization of [\u03b75-RC5H4(CO)3M]2Hg complexes (R = H, M = W; R= CH3CO, M = Cr, Mo, W)","volume":"414","author":"Song","year":"1991","journal-title":"J. Organomet. Chem."},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Johnson, B.F.G., Kwik, W.-L., Lewis, J., Raithby, P.R., and Saharan, V.P. (1991). Synthesis of mercury-linked ruthenium clusters: The X-ray structure of the new cluster dianion [{Ru6C(CO)16}2Hg]2\u2212 and the cluster [{Ru5C(CO)14(\u00b5-Cl)}2Hg2Cl2]. J. Chem. Soc. Dalton Trans., 1037\u20131042.","DOI":"10.1039\/DT9910001037"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"431","DOI":"10.1016\/0022-328X(91)86469-7","article-title":"Mercury\u2014Ruthenium mixed-metal carbonyl clusters containing 2-amido-6-methylpyridine (ampy) as a \u03bc3,\u03b72-ligand. Crystal structures of [Ru6(\u03bc4-Hg)(\u03bc3-ampy)2(CO)18]\u00b72C4H8O and [Ru3(\u03bc-HgBr)(\u03bc3-ampy)(CO)9]","volume":"420","author":"Andreu","year":"1991","journal-title":"J. Organomet. Chem."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"121281","DOI":"10.1016\/j.ica.2022.121281","article-title":"Mercurophilic interactions in heterometallic Ru-Hg carbonyl clusters","volume":"545","author":"Cesari","year":"2023","journal-title":"Inorg. Chim. Acta"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"8512","DOI":"10.1039\/D1DT01269J","article-title":"Synthesis, structure and reactivity of iridium complexes containing a bis-cyclometalated tridentate C^N^C ligand","volume":"50","author":"Cheung","year":"2021","journal-title":"Dalton Trans."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1243","DOI":"10.1002\/1099-0682(200105)2001:5<1243::AID-EJIC1243>3.0.CO;2-K","article-title":"Cobalt\/Mercury Carbide Clusters Based on Trigonal-Prismatic or Octahedral Co6C Skeletons\u2014X-ray Crystal Structure of (NEt4)2[Co6C(CO)12{HgW(CO)3Cp}2]","volume":"2001","author":"Reina","year":"2001","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"999","DOI":"10.1002\/zaac.19946200608","article-title":"Heterometallische Clusterkomplexe der Typen Re2(\u03bc-PR2)(CO)8(HgY) und ReMo(\u03bc-PR2)(\u03b75-C5H5)(CO)6(HgY) (R = Ph, Cy; Y = Cl, W(\u03b75-C5H5)(CO)3)","volume":"620","author":"Haupt","year":"1994","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"15353","DOI":"10.1021\/jacs.3c03064","article-title":"Structural Characterization and Bonding Analysis of [Hg{Fe(CO)5}2]2+ [SbF6]\u22122","volume":"145","author":"Rupf","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/0022-328X(89)80091-9","article-title":"Anionic trimetallic compounds containing Fe-E-M skeletons (E = Zn, Cd, Hg; M = Fe, MO, W). Crystal structure of [NPPh3)2]2[(OC)4Fe-Hg-Fe(CO)4]","volume":"377","author":"Alvarez","year":"1989","journal-title":"J. Organomet. Chem."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3124","DOI":"10.1021\/ic00163a028","article-title":"Reduction of the Group IIB tetracarbonylferrates in Lewis bases. Synthesis, characterization, and structural features of the (Na{THF}2)+2[M\u2032(Fe(CO)4)2]2\u2212 (M\u2032 = Zn, Cd, and Hg) series","volume":"22","author":"Sosinsky","year":"1983","journal-title":"Inorg. Chem."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"2048","DOI":"10.1021\/om501125c","article-title":"Mercurophilic Interactions","volume":"34","author":"Schmidbaur","year":"2015","journal-title":"Organometallics"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"11645","DOI":"10.1039\/C7CP00542C","article-title":"Mercurophilic interactions: A theoretical study on the importance of ligands","volume":"19","author":"Cirera","year":"2017","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"597","DOI":"10.1021\/cr940396v","article-title":"Strong Closed-Shell Interactions in Inorganic Chemistry","volume":"97","year":"1997","journal-title":"Chem. Rev."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1002\/chem.201102389","article-title":"Aurophilicity versus Mercurophilicity: Impact of d10\u2013d10 Metallophilic Interactions on the Structure of Metal-Rich Supramolecular Assemblies","volume":"18","author":"Vreshch","year":"2012","journal-title":"Chem. Eur. J."},{"key":"ref_26","doi-asserted-by":"crossref","unstructured":"Gade, L.H., Johnson, B.F.G., Lewis, J., Conole, G., and McPartlin, M. (1992). Redox\u2013chemical core manipulation of [Os18Hg3C2(CO)42]2\u2212; synthesis and crystal structure of the cluster [Os18Hg2C2(CO)42]4\u2212. J. Chem. Soc. Dalton Trans., 3249\u20133254.","DOI":"10.1039\/DT9920003249"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"8698","DOI":"10.1021\/ja00023a017","article-title":"Photochemical core manipulation in high-nuclearity osmium-mercury clusters","volume":"113","author":"Gade","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"3872","DOI":"10.1002\/1521-3773(20001103)39:21<3872::AID-ANIE3872>3.0.CO;2-#","article-title":"[{Ir(\u03b75-C5Me5)CO)}6Hg8][CF3CO2]6, a Mixed-Metal Cluster with an Ir6Hg6 Twelve-Membered Ring and Additional Hg Centers and Metal-Metal Bonds","volume":"39","author":"Chiaradonna","year":"2000","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"McAuliffe, C.A. (1977). The Coordination Chemistry of Mercury. The Chemistry of Mercury. Aspects of Inorganic Chemistry, Palgrave Macmillan.","DOI":"10.1007\/978-1-349-02489-6"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1882","DOI":"10.1016\/j.ccr.2009.02.018","article-title":"Structures and properties of mercury(II) coordination polymers","volume":"253","author":"Masoomi","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"ref_31","first-page":"469","article-title":"Isomers in the chemistry of mercury coordination compounds","volume":"8","author":"Melnik","year":"2010","journal-title":"Cent. Eur. J. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"11859","DOI":"10.1039\/D0DT01541E","article-title":"Coordination chemistry of mercury(II) halide complexes: A combined experimental, theoretical and (ICSD & CSD) database study on the relationship between inorganic and organic units","volume":"49","author":"Samie","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"7408","DOI":"10.1002\/chem.201901584","article-title":"In My Element: Mercury","volume":"25","author":"Beletskaya","year":"2019","journal-title":"Chem. Eur. J."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"9099","DOI":"10.1039\/D0DT01008A","article-title":"Metallophilic interactions: Observations of the shortest metallophilic interactions between closed shell (d10\u00b7\u00b7\u00b7d10, d10\u00b7\u00b7\u00b7d8, d8\u00b7\u00b7\u00b7d8) metal ions [M\u00b7\u00b7\u00b7M\u2032 M = Hg(II) and Pd(II) and M\u2032 = Cu(I), Ag(I), Au(I), and Pd(II)]","volume":"49","author":"Raju","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"4512","DOI":"10.1039\/D1DT00641J","article-title":"Palladium(0) complexes of diferrocenylmercury diphosphines: Synthesis, X-ray structure analyses, catalytic isomerization, and C\u2013Cl bond activation","volume":"50","author":"Lalancette","year":"2021","journal-title":"Dalton Trans."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"13430","DOI":"10.1039\/C9DT02728A","article-title":"Diferrocenylmercury diphosphine diastereomers with unique geometries: Trans-chelation at Pd(II) with short Hg(II)\u00b7\u00b7\u00b7Pd(II) contacts","volume":"48","author":"Lalancette","year":"2019","journal-title":"Dalton Trans."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"3029","DOI":"10.1021\/acs.organomet.5b00334","article-title":"Study of the Nature of Closed-Shell HgII\u00b7\u00b7\u00b7MI (M = Cu, Ag, Au) Interactions","volume":"34","author":"Monge","year":"2015","journal-title":"Organometallics"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"844","DOI":"10.1021\/ic010890z","article-title":"Bis{(2-diphenylphosphino)phenyl}mercury:\u2009 A P-Donor Ligand and Precursor to Mixed Metal\u2212Mercury (d8\u2212d10) Cyclometalated Complexes Containing 2-C6H4PPh2","volume":"41","author":"Martin","year":"2002","journal-title":"Inorg. Chem."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"6552","DOI":"10.1002\/anie.201803086","article-title":"Diferrocenylmercury-Bridged Diphosphine: A Chiral, Ambiphilic, and Redox-Active Bidentate Ligand","volume":"57","author":"Lalancette","year":"2018","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1275","DOI":"10.1021\/ic403036s","article-title":"Experimental and Theoretical Comparison of the Metallophilicity between d10\u2013d10 AuI\u2013HgII and d8\u2013d10 AuIII\u2013HgII Interactions","volume":"53","author":"Monge","year":"2014","journal-title":"Inorg. Chem."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"4265","DOI":"10.1021\/om100297v","article-title":"Intermetallic Bonds in Metallophilic Mercuraazametallamacrocycles of Synthetic Design","volume":"29","author":"Patel","year":"2010","journal-title":"Organometallics"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"1715","DOI":"10.1002\/anie.200462487","article-title":"Synthesis of a Metallophilic Metallamacrocycle: A HgII\u00b7\u00b7\u00b7CuI\u00b7\u00b7\u00b7HgII\u00b7\u00b7\u00b7HgII\u00b7\u00b7\u00b7CuI \u00b7\u00b7\u00b7HgII Interaction","volume":"44","author":"Patel","year":"2005","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"6795","DOI":"10.1039\/c1cc11036e","article-title":"Amalgamating at the molecular level. A study of the strong closed-shell Au(I)\u00b7\u00b7\u00b7Hg(II) interaction","volume":"47","author":"Monge","year":"2011","journal-title":"Chem. Commun."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"6334","DOI":"10.1039\/C6DT00934D","article-title":"Synthesis of the molecular amalgam [{AuHg2(o-C6F4)3}{Hg3(o-C6F4)3}]\u2212: A rare example of a heterometallic homoleptic metallacycle","volume":"45","author":"Lasanta","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"6332","DOI":"10.1021\/ja801626c","article-title":"Hg(II)\u00b7\u00b7\u00b7Pd(II) Metallophilic Interactions","volume":"130","author":"Kim","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref_46","first-page":"578","article-title":"Mercury, Mercury Alloys, and Mercury Compounds","volume":"Volume 22","author":"Simon","year":"2012","journal-title":"Ullmann\u2019s Encyclopedia of Industrial Chemistry"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"229","DOI":"10.1016\/S0022-328X(00)83856-5","article-title":"Basicity of transiton metal carbonyl complexes: XIII. Reactions of the \u03c0-cyclopentadienyl complexes of molybdenum and tungsten with aprotic acids","volume":"199","author":"Ginzburg","year":"1980","journal-title":"J. Organomet. Chem."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/S0022-328X(00)99577-9","article-title":"\u00dcbergangsmetall-fulven-komplexe: XXVII. Basische fulven-komplexe","volume":"309","author":"Edelmann","year":"1986","journal-title":"J. Organomet. Chem."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1016\/0022-328X(84)80378-2","article-title":"Reactions of tricarbonylpyridine complexes (NN)(py)M(CO)3 (M = Mo, W.; NN = 2,2\u2032-bipyridine, 1,10-phenanthroline) with mercuric derivatives HgX2 (X = Cl, CN, SCN)","volume":"270","author":"Pardo","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Touchard, D., Lelay, C., Fillaut, J.-L., and Dixneuf, P.H. (1986). A Novel Roue to Thiocarbonyl-Metal Complexes via Electron Transfer to (\u03b72-CS2R)-Metal Cations. J. Chem. Soc. Chem. Commun., 37\u201338.","DOI":"10.1039\/C39860000037"},{"key":"ref_51","doi-asserted-by":"crossref","unstructured":"Adams, D.M., Cook, D.J., and Kemmitt, R.D.W. (1968). Reactions of mercuric halides with some substituted iron carbonyls; infrared spectra of the products and related adducts. J. Chem. Soc. A, 1067\u20131072.","DOI":"10.1039\/j19680001067"},{"key":"ref_52","doi-asserted-by":"crossref","unstructured":"Cook, D.J., Dawes, J.L., and Kemmitt, R.D.W. (1967). Some mercury halide\u2013cobalt and \u2013rhodium compounds. J. Chem. Soc. A, 1547\u20131551.","DOI":"10.1039\/J19670001547"},{"key":"ref_53","doi-asserted-by":"crossref","unstructured":"Lewis, J., and Wild, S.B. (1966). Chemistry of polynuclear compounds. Part IV. Some amine-substituted mercury halide\u2013iron carbonyl compounds. J. Chem. Soc. A, 69\u201372.","DOI":"10.1039\/J19660000069"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1016\/0022-328X(83)80135-1","article-title":"Reactions of the carbonyl complexes M(CO)3(L)3 (L = py, M = Mo, W.; L = NH3, M = Mo) and M(CO)4(2-Mepy)2 (M = Mo, W) with HgX2 (X = Cl, CN, SCN)","volume":"254","author":"Lobo","year":"1983","journal-title":"J. Organomet. Chem."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1016\/S0022-328X(00)95198-2","article-title":"Stability and bond strength in adducts of mercury(II) halides with transition metal carbonyl derivatives","volume":"102","author":"Graddon","year":"1975","journal-title":"J. Organomet. Chem."},{"key":"ref_56","doi-asserted-by":"crossref","unstructured":"Coco, S., Espinet, P., Mayor, F., and Solans, X. (1991). Insertion of mercury into iron\u2013halogen bonds. X-Ray structure of [(p-MeC6H4NC)5Fe\u2192HgI2]. J. Chem. Soc. Dalton Trans., 2503\u20132509.","DOI":"10.1039\/DT9910002503"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1016\/0022-328X(94)87276-7","article-title":"Insertion of mercury into iron-iodine bonds leading to dinuclear (Fe-Hg) mixed isonitrile-phosphine complexes","volume":"464","author":"Coco","year":"1994","journal-title":"J. Organomet. Chem."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"C49","DOI":"10.1016\/0022-328X(91)83017-X","article-title":"Unusual reductive behaviour of a trans-NiI2(RNC)2 complex at mercury and platinum electrodes","volume":"410","author":"Ehara","year":"1991","journal-title":"J. Organomet. Chem."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"1927","DOI":"10.1016\/j.jorganchem.2006.01.051","article-title":"Quantum chemistry studies on the Ru\u2013M interactions and the 31P NMR in [Ru(CO)3(Ph2Ppy)2(MCl2)] (M = Zn, Cd, Hg)","volume":"691","author":"Xu","year":"2006","journal-title":"J. Organomet. Chem."},{"key":"ref_60","doi-asserted-by":"crossref","unstructured":"Nowell, I.N., and Russell, D.R. (1967). The crystal structure of the dicarbonylcyclopentadienylcobalt\u2013mercuric chloride complex. Chem. Commun., 817.","DOI":"10.1039\/C19670000817"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"1918","DOI":"10.1021\/om00140a034","article-title":"Direct synthesis of low-valent acyl isocyanide metal complexes. Preparation, structure and properties of (\u03b75-C5H5)Co(CNCOR)2 complexes formed via reaction of (\u03b75-C5H5)Co(CO)2 with acyl isocyanides","volume":"5","author":"Carter","year":"1986","journal-title":"Organometallics"},{"key":"ref_62","first-page":"1919","article-title":"Stabilization of a metal-carbene intermediate by formation of a metal-mercury(II) bond. Synthesis and x-ray structure of [cyclic] Cl2HgFe(:C+SC(CO2Me):C(CO2Me)S)(CO)2(PMe2Ph)2","volume":"12","author":"Dixneuf","year":"1984","journal-title":"Organometallics"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"1772","DOI":"10.1021\/om00140a003","article-title":"Formation of donor-acceptor Fe(0)\u2192Hg(II) bond for the stabilization of carbene-iron(0) complexes: Synthesis, characterization, and reactivity toward sulfur donor molecules and x-ray structure of Cl2HgFe(CO)2(PMe2Ph)2(CS2C2(CO2Me)2)","volume":"5","author":"Khasnis","year":"1986","journal-title":"Organometallics"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"4185","DOI":"10.1021\/ic00243a026","article-title":"Synthesis and characterization of a platinum-mercury \u201cA-frame\u201d cluster","volume":"25","author":"Sharp","year":"1986","journal-title":"Inorg. Chem."},{"key":"ref_65","doi-asserted-by":"crossref","unstructured":"Faraone, F., Lo Schiavo, S., Bruno, G., and Bombieri, G. (1984). Mercury(II) chloride bridging two rhodium atoms. Preparation and X-ray crystal structure of [Rh2(\u03b7-C5H5)2(\u00b5-CO)(\u00b5-Ph2PCH2PPh2)(\u00b5-HgCl2)]. J. Chem. Soc. Chem. Commun., 6\u20137.","DOI":"10.1039\/C39840000006"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"1337","DOI":"10.1016\/j.inoche.2008.08.017","article-title":"Synthesis, X-ray structures, and photoluminescence of heterometal trinuclear Hg(II)\u2013Pt(I) and tetranuclear Hg(II)\u2013Pd(I) complexes","volume":"11","author":"Luo","year":"2008","journal-title":"Inorg. Chem. Commun."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1016\/S0020-1693(99)00216-9","article-title":"Formation of donor\u2013acceptor Fe(0)\u2013Hg(II) bond in separation and stabilization of optically active iron(0) phosphine complexes. Absolute configuration of (+)-(R)-(CO)4Fe(\u03bc-EtPhPpy)HgCl2","volume":"293","author":"Kuang","year":"1999","journal-title":"Inorg. Chim. Acta"},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0022-328X(96)06118-9","article-title":"Coordination chemistry of organometallic polydentate ligands. Studies on the syntheses and properties of Fe-M binuclear complexes prepared from organometallic tridentate ligand trans-Fe(CO)3(Ph2Ppy)2 (Ph2Ppy = 2-(diphenylphosphino)pyridine)","volume":"516","author":"Zhang","year":"1996","journal-title":"J. Organomet. Chem."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1016\/S0022-328X(96)06372-3","article-title":"The new organometallic polydentate ligand trans-bis(2-(diphenylphosphino) pyrimidine) tricarbonyliron(0) and its mono-, di- and tridentate coordination modes towards mercury(II) halide\/pseudohalide","volume":"536\u2013537","author":"Li","year":"1997","journal-title":"J. Organomet. Chem."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/S0022-328X(00)00248-5","article-title":"Synthesis and structural characterization of hetero-binuclear complexes containing a Fe0\u2192Mn+ bond bridged by a non-rigid P,N-phosphine ligand","volume":"605","author":"Song","year":"2000","journal-title":"J. Organomet. Chem."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1039\/b108287f","article-title":"Hetero-binuclear complexes containing a Ru0\u2006\u2192\u2006Mn+ bond bridged by P,N-phosphine ligands: Convenient synthesis of tridentate organometallic trans-Ru(CO)3(L)2 \u2006(L\u2006=\u2006phosphine bearing an N-donor substituent) ligands","volume":"26","author":"Song","year":"2002","journal-title":"New. J. Chem."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"1066","DOI":"10.1021\/om00068a013","article-title":"Crystal structure and molecular geometry of a square-pyramidal platinum(II) complex [{2,6-(Me2NCH2)2C6H3}Pt(\u03bc-{(p-tol)NC(H)N(i-Pr)})HgBrCl] containing a PtII-to-HgII donor bond","volume":"1","author":"Vrieze","year":"1982","journal-title":"Organometallics"},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"2730","DOI":"10.1021\/ic00039a014","article-title":"Reactivity of complexes with weak metal-metal bonds. Reactions of Lewis acids with AuIr(CO)Cl(\u03bc-Ph2PCH2PPh2)2](PF6)","volume":"31","author":"Balch","year":"1992","journal-title":"Inorg. Chem."},{"key":"ref_74","doi-asserted-by":"crossref","unstructured":"Cabeza, J.A., Fern\u00e1ndez-Colinas, J.M., Garc\u00eda-Granda, S., Riera, V., and Van der Maelen, J.F. (1991). Selective insertion of mercury(II) halides into the ruthenium\u2013mercury bonds of trinuclear Ru2Hg clusters. J. Chem. Soc. Chem. Commun., 168\u2013170.","DOI":"10.1039\/C39910000168"},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"1233","DOI":"10.1021\/ic00033a020","article-title":"Addition of mercury(II) electrophiles to [Ru2(C10H8N2)(CO)4(PiPr3)2] and selective insertion versus addition in the reactions of mercury(II) electrophiles with trinuclear diruthenium mercury clusters. X-ray structures of [Ru2Hg(O2CCF3)2(C10H8N2)(CO)4(PiPr3)2] and [Ru2Hg2Cl4(C10H8N2)(CO)4(PiPr3)2]\u00b7CH2Cl2 (C10H10N2 = 1,8-diaminonaphthalene)","volume":"31","author":"Cabeza","year":"1992","journal-title":"Inorg. Chem."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"6166","DOI":"10.1021\/ic970584e","article-title":"Reactivity of [M(C\u2227P)(S2C-R)] (M = Pd, Pt; C\u2227P = CH2-C6H4-P(o-tolyl)2-\u03baC,P.; R = NMe2, OEt) toward HgX2 (X = Br, I). X-ray Crystal Structures of [Pt{CH2-C6H4P(o-tolyl)2-\u03baC,P}(S2CNMe2)HgI(\u03bc-I)]2 and [PdBr(S2COEt){\u03bc-P(o-tolyl)2-C6H4-CH2-}HgBr]\u00b70.5HgBr2\u00b7C2H4Cl2","volume":"36","author":"Falvello","year":"1997","journal-title":"Inorg. Chem."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"3376","DOI":"10.1246\/bcsj.64.3376","article-title":"Four- and Five-Coordinated Nickel(II) Isocyanide Complexes and Donor\u2013Acceptor Complexes Containing Nickel and Mercury","volume":"64","author":"Yamamoto","year":"1991","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"10325","DOI":"10.1021\/ic501376v","article-title":"Gold(I) and Related Heterometallic Derivatives of Dimolybdenum Complexes with Asymmetric Phosphinidene Bridges","volume":"53","author":"Alvarez","year":"2014","journal-title":"Inorg. Chem."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"3417","DOI":"10.1016\/0277-5387(96)00059-9","article-title":"Coordination chemistry of organometallic polydentate ligands. Syntheses of Fe-M complexes using Fe(CO)4(Ph2Ppy-P)[Ph2Ppy = 2-(diphenylphosphino)pyridine] and trans-Fe(PhPMepy)2(CO)3 [PhPMepy = 2-(phenylmethylphosphino)pyridine] as a neutral bi- or tridentate ligand","volume":"15","author":"Kuang","year":"1996","journal-title":"Polyhedron"},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"6830","DOI":"10.1039\/D2SC01200F","article-title":"Arsolyl-supported intermetallic dative bonding","volume":"13","author":"Kirk","year":"2022","journal-title":"Chem. Sci."},{"key":"ref_81","doi-asserted-by":"crossref","unstructured":"Ciplys, A.M., Geue, R.J., and Snow, M.R. (1976). Crystal structure of the dimeric 1:2 addition complex of tricarbonylmesitylenemolybdenum with mercury(II) chloride. J. Chem. Soc. Dalton Trans., 35\u201337.","DOI":"10.1039\/dt9760000035"},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"3091","DOI":"10.1021\/om000223y","article-title":"Reactivity of [M(C\u2227P)(acac-O,O\u2032)] [M = Pt, Pd; C\u2227P = CH2-C6H4-P(o-tolyl)2-\u03baC,P; acac = 2,4-pentanedionato] toward HgX2 (X = Br, I, CH3COO, CF3COO). New Polynuclear Complexes Containing Pt\u2212Hg Bonds. Molecular Structures of [{Pt(C\u2227P)(acac-O,O\u2032)-HgBr(\u03bc-Br)}2(\u03bc-HgBr2)], an Unprecedented Square-Planar Bromomercurate Complex, and [{Pt(C\u2227P)(\u03bc-O2CCH3)2Hg(\u03bc3-acac2\u2212-\u03baC3,O)Hg(O2CCH3-\u03baO)}\u00b7CHCl3]2, the First Complex Containing Asymmetric Dimercurated Acetylacetone","volume":"19","author":"Ara","year":"2000","journal-title":"Organometallics"},{"key":"ref_83","doi-asserted-by":"crossref","unstructured":"Nowell, I.W., and Russell, D.R. (1972). Structures of mercury(II) halide adducts with transition-metal Lewis bases. Part II. Crystal structure of the 1:3 complex between dicarbonyl-\u03c0-cyclopentadienylcobalt and mercury(II) chloride. J. Chem. Soc. Dalton Trans., 2396\u20132399.","DOI":"10.1039\/DT9720002396"},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"221","DOI":"10.1016\/0022-328X(92)80232-M","article-title":"Characterization of 1:1 heterobimetallic complexes of (\u03b75-C5Me5)Ir(CO)2 with zinc, cadmium and mercury(II) chloride and the X-ray structure determination of the 1:2 mercury complex","volume":"439","author":"Einstein","year":"1992","journal-title":"J. Organomet. Chem."},{"key":"ref_85","doi-asserted-by":"crossref","unstructured":"Mays, M.J., and Robb, J.D. (1968). Exchange reactions involving transition-metal\u2013mercury bonds. J. Chem. Soc. A, 329\u2013332.","DOI":"10.1039\/J19680000329"},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/0022-2860(85)80149-6","article-title":"IR spectra of organophosphine substituted derivatives of (halomercury)tetracarbonylcobalt","volume":"127","year":"1985","journal-title":"J. Mol. Struct."},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/S0277-5387(00)83561-5","article-title":"Reactivity of the Mo-Sn bond. Reactions of [MoSnPh3(CO)3(\u03b7-C5H5)] with HgX2 (X = Cl, OCOCF3)","volume":"10","author":"Cano","year":"1991","journal-title":"Polyhedron"},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/S0022-328X(00)93374-6","article-title":"Reactivity of Metal-Metal Bonds: I. Cleavage of molybdenum-tin and tungsten-tin bonds and synthesis of novel organomercury derivatives","volume":"40","author":"Roberts","year":"1972","journal-title":"J. Organomet. Chem."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/S0022-328X(00)81746-5","article-title":"Reactivity of metal-metal bonds: II. Exchange reactions of trimethyltin derivatives of manganese and iron","volume":"47","author":"Roberts","year":"1973","journal-title":"J. Organomet. Chem."},{"key":"ref_90","doi-asserted-by":"crossref","unstructured":"Chipperfield, J.R., Hayter, A.C., and Webster, D.E. (1977). Reactivity of main-group\u2013transition-metal bonds. Part 7. Kinetics of the reaction of mercury(II) halides with compounds containing tin\u2013chromium, \u2013molybdenum, \u2013tungsten, \u2013manganese, \u2013rhenium, and \u2013iron bonds. J. Chem. Soc. Dalton Trans., 485\u2013490.","DOI":"10.1039\/DT9770000485"},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/0022-328X(87)87127-9","article-title":"The reactions of [Fe2(\u03b7-C5H5)2(CO)4\u2212n(CNMe)n] (n = 0\u20134) complexes with halogens and mercury(II) salts","volume":"323","author":"Kumar","year":"1987","journal-title":"J. Organomet. Chem."},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"1669","DOI":"10.1016\/S0277-5387(00)80095-9","article-title":"Reactivity of carbonyl complexes containing Mo-Hg bonds; reaction of tin(II) halides with [Mo(CO)3(NN)(HgX)(X)] (NN = bpy, phen, dmp); crystal structure of [Mo(CO)3(dmp)(HgCl)(Cl)]","volume":"13","author":"Cano","year":"1994","journal-title":"Polyhedron"},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"32","DOI":"10.1016\/j.jorganchem.2019.03.022","article-title":"Stereochemistry of oxidative addition reactions of cycloneophyl complexes of Platinum(II): A methylene insertion reaction from dichloromethane","volume":"890","author":"Fard","year":"2019","journal-title":"J. Organomet. Chem."},{"key":"ref_94","doi-asserted-by":"crossref","first-page":"2261","DOI":"10.1021\/om501023r","article-title":"The Platinum Center is a Stronger Nucleophile than the Free Nitrogen Donors in a Dimethylplatinum Complex with a Dipyridylpyridazine Ligand","volume":"34","author":"McCready","year":"2015","journal-title":"Organometallics"},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"1728","DOI":"10.1021\/ic001145+","article-title":"Mechanism of Oxidative Addition of Mercury(II) Compounds to Platinum(II)","volume":"40","author":"Janzen","year":"2001","journal-title":"Inorg. Chem."},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"1614","DOI":"10.1016\/j.ica.2004.11.007","article-title":"Oxidative addition of mercury(II) halides and carboxylates to platinum(II): Formation of Pt\u2013Hg covalent and donor\u2013acceptor bonds","volume":"358","author":"Janzen","year":"2005","journal-title":"Inorg. Chim. Acta"},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"2095","DOI":"10.1021\/ic00135a077","article-title":"Chemistry of transition-metal phosphine and phosphite complexes. 2. Preparation and properties of XHgCo[P(OC6H5)3]3L","volume":"21","author":"Anderson","year":"1982","journal-title":"Inorg. Chem."},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"221","DOI":"10.1016\/S0022-328X(00)92382-9","article-title":"Studies on main group metal-transition-metal bonded compounds.6. The structure of \u03b75-C5H5(CO)3MoHgCl","volume":"161","author":"Albright","year":"1978","journal-title":"J. Organomet. Chem."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"2197","DOI":"10.1021\/ic50221a051","article-title":"Structural Studies on Some (\u03b75-C5H5)M(CO)3X Molecules: (\u03b75-C5H5)W(CO)3Cl, (\u03b75-C5H5)Mo(CO)3Cl, and (\u03b75-C5H5)Mo(CO)3HgCl","volume":"20","author":"Bueno","year":"1981","journal-title":"Inorg. Chem."},{"key":"ref_100","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1016\/0022-328X(85)80223-0","article-title":"Synthesis of heteronuclear carbonyl complexes (\u03b75-C5H4CH3)(CO)3MoHgX (X = Cl, Br, I, SCN). Crystal structure of (\u03b75-C5H4CH3)(CO)3MoHgCl","volume":"292","author":"Cano","year":"1985","journal-title":"J. Organomet. Chem."},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"251","DOI":"10.1016\/0020-1693(94)04172-R","article-title":"Effects of substitutions on cyclopentadienyl rings in complexes with molybdenum-mercury bonds. 95Mo and 199Hg NMR studies","volume":"228","author":"Cano","year":"1995","journal-title":"Inorg. Chim. Acta"},{"key":"ref_102","doi-asserted-by":"crossref","unstructured":"Auvray, N., Baul, T.S.B., Braunstein, P., Croizat, P., Englert, U., Herberich, G.E., and Welter, R. (2006). Organometallic building blocks with amino-substituted cyclopentadienyl and boratabenzene ligands for the synthesis of heterometallic complexes and clusters. Dalton Trans., 2950\u20132958.","DOI":"10.1039\/b602106a"},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"1685","DOI":"10.1071\/CH9771685","article-title":"Crystal structures of Bis[tricarbonyl(\u03b7-cyclopentadienyl)molybdato(0)]mercury(II) and trans-Dicarbonyl(dimethylphenylarsine)[iodomercurio(0)](\u03b7-methylcylopentadienyl) molybdenum(II)","volume":"30","author":"Mickiewicz","year":"1977","journal-title":"Aust. J. Chem."},{"key":"ref_104","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1016\/0020-1693(94)04124-5","article-title":"Synthesis and structural analysis of trans-Cp(CO)2(PPh3)WHgCl","volume":"227","author":"Mullica","year":"1994","journal-title":"Inorg. Chim. Acta"},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"2667","DOI":"10.1071\/CH9742667","article-title":"Crystal structure of (2,2\u2032-Bipyridyl)tricarbonylchloro(chloromercurio)molybdenum-(II)","volume":"27","author":"Brotherton","year":"1974","journal-title":"Aust. J. Chem."},{"key":"ref_106","doi-asserted-by":"crossref","unstructured":"Kergoat, R., Kubicki, M.M., Guerchais, J.E., Norman, N.C., and Orpen, A.G. (1982). Bis(cyclopentadienyls) with transition metal\u2013mercury bonds. Part 4. Formation of niobium\u2013mercury bonds and X-ray crystal structure of [Nb(\u03b7-C5H5)2{HgS2CN(C2H5)2}3]. J. Chem. Soc. Dalton Trans., 633\u2013638.","DOI":"10.1002\/chin.198225251"},{"key":"ref_107","doi-asserted-by":"crossref","first-page":"583","DOI":"10.1007\/BF00965385","article-title":"Study of the reactions of halogen and mercury halogen derivatives of metal carbonyls with samarium and ytterbium","volume":"37","author":"Suleimanov","year":"1988","journal-title":"Russ. Chem. Bull."},{"key":"ref_108","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1002\/cber.19891220204","article-title":"\u00dcbergangsmetall-Silyl-Komplexe, 27. Silylsubstituierte Hetero-Mehrkern-Komplexe durch Umsetzung der anionischen Silyl-Komplexe [MeCpMn(CO)2SiR3]\u2212 und [Fe(CO)3(PPh3)SiR3]\u2212 mit Zink-, Cadmium- und Quecksilber-Dihalogeniden","volume":"122","author":"Kunz","year":"1989","journal-title":"Chem. Ber."},{"key":"ref_109","doi-asserted-by":"crossref","unstructured":"Braunstein, P., Englert, U., Herberich, G.E., Neusch\u00fctz, M., and Schmidt, M.U. (1999). Heterometallic complexes with borole ligands. J. Chem. Soc. Dalton Trans., 2807\u20132812.","DOI":"10.1039\/a903846i"},{"key":"ref_110","doi-asserted-by":"crossref","first-page":"847","DOI":"10.1007\/BF00947851","article-title":"Synthesis and some properties of tetra[\u03b75-cyclopentadienyldi-carbonylrheniummercury]","volume":"33","author":"Kolobova","year":"1984","journal-title":"Russ. Chem. Bull."},{"key":"ref_111","doi-asserted-by":"crossref","first-page":"3813","DOI":"10.1021\/ja00088a018","article-title":"Syntheses and Molecular and Electronic Structures of Tris(arylimido)technetium(VI) and -(V) Complexes Derived from Successive One-Electron Reductions of Tris(arylimido)iodotechnetium(VII)","volume":"116","author":"Burrell","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref_112","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/0022-328X(92)83083-T","article-title":"\u00dcbergangsmetall-silyl-komplexe: XLII. Einflu\u03b2 des phosphan-liganden auf bildung, struktur und stabilit\u00e4t der hetero-zweikernkomplexe (CO)3(R\u20323P)(R3Si)Fe\u2014MLn (M = Cu, Ag, Au, Hg)","volume":"427","author":"Reinhard","year":"1992","journal-title":"J. Organomet. Chem."},{"key":"ref_113","doi-asserted-by":"crossref","first-page":"1095","DOI":"10.1002\/(SICI)1521-3749(199807)624:7<1095::AID-ZAAC1095>3.0.CO;2-H","article-title":"Neue phosphido- und phosphinidenverbr\u00fcckte Quecksilbercluster: Die Kristallstrukturen der Mehrkernkomplexe [Hg3{Fe(CO)4}2X2] (X = Cl, Br) (1, 2), [Hg10{Fe(CO)4}4(PtBu)4Cl4] (3), [Hg14{Fe(CO)4}5(PtBu)8Cl2] (4), [SiMe3OPiPr3][Hg12{Fe(CO)4}7(PtBu)4(PtBuSiMe3)Br2] (5), [Hg5{Fe(CO)4}3(PtBu2)2Br2] (6), [Hg8{Fe(CO)4}4(P2Ph2)2(PnPr3)Cl4] (7), [Hg8{Fe(CO)4}4(P2Ph2)2(PPh2Et)Cl4] (8) und [Hg10{Fe(CO)4}6(P2Ph2)2(PnPr3)Br4] (9)","volume":"624","author":"Eisenmann","year":"1998","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_114","doi-asserted-by":"crossref","first-page":"2097","DOI":"10.1002\/cber.19280610907","article-title":"\u00dcber die Einwirkung von Quecksilbersalzen auf Eisenpentacarbonyl","volume":"61","author":"Hock","year":"1928","journal-title":"Chem. Ber."},{"key":"ref_115","doi-asserted-by":"crossref","first-page":"503","DOI":"10.1016\/S0022-328X(00)85372-3","article-title":"The crystal and molecular structure of (BrHg)2Fe(CO)4","volume":"7","author":"Baird","year":"1967","journal-title":"J. Organomet. Chem."},{"key":"ref_116","doi-asserted-by":"crossref","unstructured":"Casey, M., and Manning, A.R. (1970). The preparation, reactions, and infrared spectra of some derivatives of bis(tricarbonylnitrosyliron)mercury. J. Chem. Soc. A, 2258\u20132261.","DOI":"10.1039\/j19700002258"},{"key":"ref_117","doi-asserted-by":"crossref","first-page":"C61","DOI":"10.1016\/S0022-328X(00)85828-3","article-title":"Regiospecificity in the reaction of [Fe2(\u03b7-C5H5)2(CO)4\u2212n(CNMe)n] (n = 0\u20132) with mercury(II) halides","volume":"216","author":"Kumar","year":"1981","journal-title":"J. Organomet. Chem."},{"key":"ref_118","doi-asserted-by":"crossref","first-page":"1471","DOI":"10.1016\/S0277-5387(00)80322-8","article-title":"The insertion of the [M(CO)3(NN)] fragments (M = Mo, W.; NN = 2,2\u2032-bipyridine; 1,10-phenanthroline; ethylenediamine) into the Hg-X (X = Cl, Br, I, N3, SCN) bonds of the [\u03b75-C5H5Fe(CO)2(HgX)] complexes. Heterotrimetallic compounds with Fe-Hg-M-X bondings","volume":"8","author":"Granifo","year":"1989","journal-title":"Polyhedron"},{"key":"ref_119","doi-asserted-by":"crossref","unstructured":"Bentley, G.A., Laing, K.R., Roper, W.R., and Waters, J.M. (1970). Preparation and crystal structure of dichloro(chloromercury)(nitrosyl)bis(triphenylphosphine)osmium(II). J. Chem. Soc. D, 998.","DOI":"10.1039\/c29700000998"},{"key":"ref_120","doi-asserted-by":"crossref","first-page":"543","DOI":"10.1016\/S0277-5387(00)81023-2","article-title":"Crystal structures of [Co{P(OPh)3}4(HgX)], X = Cl, Br; Non-linearity of Co-Hg-X arising from intramolecular phosphorus-mercury interactions","volume":"6","author":"Goodgame","year":"1987","journal-title":"Polyhedron"},{"key":"ref_121","doi-asserted-by":"crossref","unstructured":"Bonati, F., Cenini, S., and Ugo, R. (1967). Interaction of tin(II) halides with compounds having mercury\u2013metal bonds. J. Chem. Soc. A, 932\u2013935.","DOI":"10.1039\/J19670000932"},{"key":"ref_122","doi-asserted-by":"crossref","unstructured":"Brotherton, P.D., Raston, C.L., White, A.H., and Wild, S.B. (1976). Crystal structures of mercury(II) chloride and bromide addition complexes of carbonylchlorobis(triphenylphosphine)iridium(I). J. Chem. Soc. Dalton Trans., 1799\u20131802.","DOI":"10.1039\/dt9760001799"},{"key":"ref_123","doi-asserted-by":"crossref","unstructured":"Dewhurst, R.D., Hill, A.F., and Willis, A.C. (2009). Iridium tricarbido complexes via transmetallation with tricarbidomercurials. Dalton Trans., 3384\u20133387.","DOI":"10.1039\/b900205g"},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"6063","DOI":"10.1021\/om2008524","article-title":"Intramolecular Metal\u2013Metal Bond Rearrangement in a Pt2PdHg Heterometallic Cluster Forming a HgI\u2013PdI Covalent Bond","volume":"30","author":"Hosokawa","year":"2011","journal-title":"Organometallics"},{"key":"ref_125","doi-asserted-by":"crossref","first-page":"2399","DOI":"10.1002\/1099-0682(200109)2001:9<2399::AID-EJIC2399>3.0.CO;2-O","article-title":"Chemistry at the Sterically Shielded Mercury Centre of the [(\u03b74-pp3)PtHg] Fragment","volume":"2001","author":"Schuh","year":"2001","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_126","doi-asserted-by":"crossref","unstructured":"Chan, W.-H., Zhang, Z.-Z., Mak, T.C.W., and Che, C.-M. (1998). Co-ordination chemistry of the organometallic tridentate ligand trans-[Ru(2-Ph2PC5H4N-P)2(CO)3] and crystal structures of metal complex derivatives. J. Chem. Soc. Dalton Trans., 803\u2013810.","DOI":"10.1039\/a706958h"},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"722","DOI":"10.1002\/cjoc.20000180512","article-title":"Coordination chemistry of organometallic polydentate ligand Reactive chemistry of the tridentate ligand trans-Fe(Ph2PQu-P)2(CO)3 [Ph2PQu=2-diphenyl-phosphino-4-methylquinoline] and molecular structure of [Fe(CO)3(\u03bc-Ph2PQu)2HgI]+[HgI3]\u2212","volume":"18","author":"Xu","year":"2000","journal-title":"Chin. J. Chem."},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1016\/S0020-1693(98)00272-2","article-title":"Reaction of M(CO)Cl(L)2 with mercury(II) chloride (M = Ir, Rh; L = Ph2Ppy, P(fur)3) (Ph2Ppy = 2-(diphenylphospino)pyridine, P(fur)3 = tri-(2-furyl)phosphine)","volume":"284","author":"Kuang","year":"1999","journal-title":"Inorg. Chim. Acta"},{"key":"ref_129","doi-asserted-by":"crossref","first-page":"338","DOI":"10.1021\/om970145n","article-title":"IrPd, IrHg, IrCu, and IrTl Binuclear Complexes Bridged by the Short-Bite Ligand 2-(Diphenylphosphino)pyridine. Catalytic Effect in the Hydroformylation of Styrene Due to the Monodentate P-Bonded 2-(Diphenylphosphino)pyridine Ligands of trans-[Ir(CO)(Ph2PPy)2Cl]","volume":"17","author":"Scopelliti","year":"1998","journal-title":"Organometallics"},{"key":"ref_130","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1016\/S0022-328X(97)00672-4","article-title":"Metal\u2013metal bond cleavage in the trinuclear clusters M3(CO)12\u2212n(Ph2Ppy)n (M = Ru, n = 3; Os, n = 1; Ph2Ppy = 2-(diphenylphosphino)pyridine) by Lewis acids","volume":"559","author":"Kuang","year":"1998","journal-title":"J. Organomet. Chem."},{"key":"ref_131","doi-asserted-by":"crossref","unstructured":"Baker, R.W., and Pauling, P. (1970). The crystal structure of bis(chloropyridylmercury)tetracarbonyliron, Fe(CO)4[HgCl(C5H5N)]2. J. Chem. Soc. D., 573\u2013574.","DOI":"10.1039\/c29700000573"},{"key":"ref_132","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1016\/S0022-328X(00)93434-X","article-title":"Metal-metal bonded compounds V. Compounds with Ir(Rh)-Hg bonds containing a bridging and a chelating triazenido group, which interconvert intramolecularly","volume":"187","author":"Kokkes","year":"1980","journal-title":"J. Organomet. Chem."},{"key":"ref_133","doi-asserted-by":"crossref","first-page":"2442","DOI":"10.1039\/c1nj20279k","article-title":"Reactions of the \u03bc3-sulfido triiron cluster [SFe3(CO)9]2\u2212 with functionalized organic halides and mercury salts: Selective reactivity, electrochemistry, and theoretical calculations","volume":"35","author":"Miu","year":"2011","journal-title":"New. J. Chem."},{"key":"ref_134","doi-asserted-by":"crossref","first-page":"456","DOI":"10.1021\/om960767t","article-title":"Reactivity of [SeFe3(CO)9]2\u2212 with Electrophiles:\u2009 Formation of [SeFe2Ru3(CO)14]2\u2212, [SeFe3(CO)9(\u03bc-HgI)]\u2212, Fe2(CO)6(\u03bc-SeCHPhSe), and Se2Fe2(CO)6(\u03bc-CH2)2","volume":"16","author":"Shieh","year":"1997","journal-title":"Organometallics"},{"key":"ref_135","doi-asserted-by":"crossref","first-page":"2159","DOI":"10.1016\/S0277-5387(00)81796-9","article-title":"The reactivity of [Os3(CO)10(C2Ph2)] towards phenyl mercury halides","volume":"7","author":"Rosales","year":"1988","journal-title":"Polyhedron"},{"key":"ref_136","doi-asserted-by":"crossref","first-page":"3626","DOI":"10.1021\/ja00530a055","article-title":"Synthesis, structure, and reactivity of mercurial derivatives of an organoruthenium cluster","volume":"102","author":"Fahmy","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"ref_137","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.jorganchem.2014.08.009","article-title":"Bridging phenyl ligands. Unsaturated mercury-triosmium carbonyl cluster complexes containing bridging phenyl ligands","volume":"784","author":"Adams","year":"2015","journal-title":"J. Organomet. Chem."},{"key":"ref_138","doi-asserted-by":"crossref","first-page":"c43","DOI":"10.1016\/0022-328X(84)80251-X","article-title":"Reduction products of dinuclear [Rh2Cl2(CO)2 {\u03bc-(PhO)2PN(Et)P(OPh)2}2]. Crystal structure of [Rh2HgCl(\u03bc-H)(CO)2{\u03bc-(PhO)2PN(Et)P(OPh)2}2]","volume":"268","author":"Field","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"ref_139","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/j.jorganchem.2015.01.008","article-title":"New rhenium carbonyl cluster complexes containing bridging hydrocarbyl and bridging mercury groups","volume":"784","author":"Adams","year":"2015","journal-title":"J. Organomet. Chem."},{"key":"ref_140","doi-asserted-by":"crossref","unstructured":"Tiripicchio, A., Lahoz, F.J., Oro, L.A., and Pinillos, M.T. (1984). Preparation and X-ray structure of a rhodium(III)\u2013rhodium(I) pyrazolate complex with a mercury atom asymmetrically bridging the metal atoms. J. Chem. Soc. Chem. Commun., 936\u2013937.","DOI":"10.1039\/C39840000936"},{"key":"ref_141","doi-asserted-by":"crossref","first-page":"9548","DOI":"10.1021\/acs.inorgchem.9b00978","article-title":"Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond","volume":"58","author":"Yamaguchi","year":"2019","journal-title":"Inorg. Chem."},{"key":"ref_142","doi-asserted-by":"crossref","first-page":"2239","DOI":"10.1021\/om00053a029","article-title":"Chemistry of iridium carbonyl cluster complexes. Synthesis and characterization of mixed-metal carbonyl clusters via capping reactions with HgCl2 and Au(PPh3)Cl. Crystal structures of [N(PPh3)2][Ir6(\u03bc3-CO)3(CO)12(\u03bc3-HgCl)]\u00b70.5C6H12 and [NMe3(CH2Ph)][Ir6(\u03bc3-CO)3(CO)12[\u03bc3-Au(PPh3)]\u00b7C4H8O","volume":"10","author":"Demartin","year":"1991","journal-title":"Organometallics"},{"key":"ref_143","doi-asserted-by":"crossref","first-page":"186","DOI":"10.1021\/om00001a029","article-title":"Au-Ir and Hg-Ir Mixed-Metal Carbonyl Clusters. Synthesis, Characterization, and Solid State Structure of [Ir6(CO)15(AuPPh3)2] and [Ir6(CO)14(HgCl)2]2\u2212","volume":"14","author":"Ceriotti","year":"1995","journal-title":"Organometallics"},{"key":"ref_144","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1016\/S0020-1693(97)05685-5","article-title":"The bicluster oxidative addition as a route to bicapped hexaplatinum clusters","volume":"265","author":"Hao","year":"1997","journal-title":"Inorg. Chim. Acta"},{"key":"ref_145","doi-asserted-by":"crossref","first-page":"2223","DOI":"10.1021\/ic00037a042","article-title":"A new class of planar (platinum-mercury) mixed metal clusters containing a [Pt3(CO)3(PR3)3] moiety capped by two HgX units","volume":"31","author":"Albinati","year":"1992","journal-title":"Inorg. Chem."},{"key":"ref_146","doi-asserted-by":"crossref","unstructured":"Gade, L.H., Johnson, B.F.G., Lewis, J., McPartlin, M., and Powell, H.R. (1992). Systematic build-up of high-nuclearity osmium\u2013mercury clusters. J. Chem. Soc. Dalton Trans., 921\u2013931.","DOI":"10.1039\/DT9920000921"},{"key":"ref_147","doi-asserted-by":"crossref","first-page":"1825","DOI":"10.1007\/BF00952385","article-title":"Reactions of platinum(0) and palladium(0) complexes with mercury(II) compounds: New methods for the synthesis of organic platinum and palladium derivatives","volume":"31","author":"Bashilov","year":"1982","journal-title":"Russ. Chem. Bull."},{"key":"ref_148","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1016\/S0277-5387(00)83946-7","article-title":"Synthesis and structure of the new heteronuclear palladium-mercury cluster","volume":"2","author":"Mednikov","year":"1983","journal-title":"Polyhedron"},{"key":"ref_149","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1007\/BF02495367","article-title":"Synthesis of platinum-mercury clusters and the molecular structure of Pt4(HgBr)2(\u03bc-CO)4(PPh3)4","volume":"46","author":"Eremenko","year":"1997","journal-title":"Russ. Chem. Bull."},{"key":"ref_150","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/0022-328X(94)05055-G","article-title":"Synthesis and X-ray crystal structure of the heterometallic platinum-mercury cluster [{Pt4(\u03bc-CO)4(PMe2Ph)4}{\u03bc3-HgI}2]","volume":"486","author":"Dahmen","year":"1995","journal-title":"J. Organomet. Chem."},{"key":"ref_151","doi-asserted-by":"crossref","first-page":"2664","DOI":"10.1021\/om960116x","article-title":"Cluster Synthesis. 46. New Mixed-Metal Complexes of the Layer-Segregated Cluster Pt3Ru6(CO)21(\u03bc3-H)(\u03bc-H)3","volume":"15","author":"Adams","year":"1996","journal-title":"Organometallics"},{"key":"ref_152","doi-asserted-by":"crossref","first-page":"4283","DOI":"10.1021\/om300278k","article-title":"Cyclic Trinuclear Rh2M Complexes (M = Rh, Pt, Pd, Ni) Supported by meso-1,3-Bis[(diphenylphosphinomethyl)phenylphosphino]propane","volume":"31","author":"Nakajima","year":"2012","journal-title":"Organometallics"},{"key":"ref_153","first-page":"421","article-title":"Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(\u03bc-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands","volume":"593\u2013594","author":"Casas","year":"2000","journal-title":"J. Organomet. Chem."},{"key":"ref_154","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1016\/j.ccr.2017.04.009","article-title":"Topological analysis of the metal-metal bond: A tutorial review","volume":"345","author":"Lepetit","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"ref_155","doi-asserted-by":"crossref","unstructured":"Bridgeman, A.J., Cavigliasso, G., Ireland, L.R., and Rothery, J. (2001). The Mayer bond order as a tool in inorganic chemistry. J. Chem. Soc. Dalton Trans., 2095\u20132108.","DOI":"10.1039\/b102094n"},{"key":"ref_156","doi-asserted-by":"crossref","first-page":"064103","DOI":"10.1063\/5.0040021","article-title":"r2SCAN-3c: A \u201cSwiss army knife\u201d composite electronic-structure method","volume":"154","author":"Grimme","year":"2021","journal-title":"J. Chem. Phys."},{"key":"ref_157","doi-asserted-by":"crossref","first-page":"8208","DOI":"10.1021\/acs.jpclett.0c02405","article-title":"Accurate and Numerically Efficient r2SCAN Meta-Generalized Gradient Approximation","volume":"11","author":"Furness","year":"2020","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_158","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","article-title":"Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_159","doi-asserted-by":"crossref","first-page":"1057","DOI":"10.1039\/b515623h","article-title":"Accurate Coulomb-fitting basis sets for H to Rn","volume":"8","author":"Weigend","year":"2006","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_160","doi-asserted-by":"crossref","first-page":"154101","DOI":"10.1063\/1.3700154","article-title":"A geometrical correction for the inter- and intra-molecular basis set superposition error in Hartree-Fock and density functional theory calculations for large systems","volume":"136","author":"Kruse","year":"2012","journal-title":"J. Chem. Phys."},{"key":"ref_161","doi-asserted-by":"crossref","first-page":"154122","DOI":"10.1063\/1.5090222","article-title":"Generally applicable atomic-charge dependent London dispersion correction","volume":"150","author":"Caldeweyher","year":"2019","journal-title":"J. Chem. Phys."},{"key":"ref_162","doi-asserted-by":"crossref","first-page":"669","DOI":"10.1002\/jcc.10189","article-title":"Energies, structures, and electronic properties of molecules in solution with the C-PCM solvation model","volume":"24","author":"Cossi","year":"2003","journal-title":"J. Comput. Chem."},{"key":"ref_163","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1002\/wcms.81","article-title":"The ORCA program system","volume":"2","author":"Neese","year":"2012","journal-title":"WIREs Comput. Mol. Sci."},{"key":"ref_164","doi-asserted-by":"crossref","first-page":"e1606","DOI":"10.1002\/wcms.1606","article-title":"Software update: The ORCA program system\u2014Version 5.0","volume":"12","author":"Neese","year":"2022","journal-title":"WIREs Comput. Mol. Sci."},{"key":"ref_165","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1002\/jcc.22885","article-title":"Multiwfn: A multifunctional wavefunction analyser","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."},{"key":"ref_166","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1002\/(SICI)1521-3749(200001)626:1<290::AID-ZAAC290>3.0.CO;2-G","article-title":"Synthese und Kristallstructuren neuer phosphorverbr\u00fcckter bimetallischer Cluster der Elemente Quecksilber und Eisen","volume":"626","author":"Hezel","year":"2000","journal-title":"Z. Anorg. Allg. Chem."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/1\/145\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,7]],"date-time":"2025-10-07T15:23:22Z","timestamp":1759850602000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/1\/145"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,2]]},"references-count":166,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2025,1]]}},"alternative-id":["molecules30010145"],"URL":"https:\/\/doi.org\/10.3390\/molecules30010145","relation":{},"ISSN":["1420-3049"],"issn-type":[{"type":"electronic","value":"1420-3049"}],"subject":[],"published":{"date-parts":[[2025,1,2]]}}}