{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T20:27:55Z","timestamp":1778876875427,"version":"3.51.4"},"reference-count":56,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2025,1,17]],"date-time":"2025-01-17T00:00:00Z","timestamp":1737072000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"French National Centre for Scientific Research","award":["International Research Project"],"award-info":[{"award-number":["International Research Project"]}]},{"name":"French National Centre for Scientific Research","award":["JPNP06046"],"award-info":[{"award-number":["JPNP06046"]}]},{"name":"New Energy and Industrial Technology Development Organization","award":["International Research Project"],"award-info":[{"award-number":["International Research Project"]}]},{"name":"New Energy and Industrial Technology Development Organization","award":["JPNP06046"],"award-info":[{"award-number":["JPNP06046"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A first syn-type tricyclic 8-8-8 (three fused-8-membered ring) laddersiloxane functionalized with four azido groups was successfully synthesized through efficient and highly selective hydrosilylation and nucleophilic substitution, achieving an excellent overall yield. The starting material, a tetravinyl-substituted 8-8-8 laddersiloxane, was prepared via a straightforward and scalable method. The obtained azido-functionalized ladder compound, fully characterized, constitutes a versatile building block for hybrid materials. Reacting this compound with 2-ethynylpyridine via click chemistry yielded a multidentate ligand containing four 2-triazole-pyridyl moieties. This N,N-bidentate ligand was subsequently employed in copper-catalyzed alcohol oxidative dehydrogenation reactions, demonstrating its potential in catalysis.<\/jats:p>","DOI":"10.3390\/molecules30020373","type":"journal-article","created":{"date-parts":[[2025,1,17]],"date-time":"2025-01-17T11:24:56Z","timestamp":1737113096000},"page":"373","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis of an Azido-Substituted 8-Membered Ring Laddersiloxane and Its Application in Catalysis"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3610-6355","authenticated-orcid":false,"given":"Yujia","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu 376-8515, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Niyaz","family":"Yagafarov","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu 376-8515, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Koki","family":"Shimamura","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu 376-8515, Japan"},{"name":"ICGM, Univ Montpellier, CNRS, ENSCM (Institut Charles Gerhardt Montpellier, Universit\u00e9 de Montpellier, Centre National de la Recherche Scientifique, \u00c9cole Nationale Sup\u00e9rieure de Chimie de Montpellier), 1919 Route de Mende, CEDEX 05, 34293 Montpellier, France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5732-758X","authenticated-orcid":false,"given":"Nobuhiro","family":"Takeda","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu 376-8515, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2158-1644","authenticated-orcid":false,"given":"Masafumi","family":"Unno","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu 376-8515, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Armelle","family":"Ouali","sequence":"additional","affiliation":[{"name":"ICGM, Univ Montpellier, CNRS, ENSCM (Institut Charles Gerhardt Montpellier, Universit\u00e9 de Montpellier, Centre National de la Recherche Scientifique, \u00c9cole Nationale Sup\u00e9rieure de Chimie de Montpellier), 1919 Route de Mende, CEDEX 05, 34293 Montpellier, France"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,1,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1409","DOI":"10.1021\/cr00037a012","article-title":"Silsesquioxanes","volume":"95","author":"Baney","year":"1995","journal-title":"Chem. 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