{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T04:58:27Z","timestamp":1789707507241,"version":"4.0.1"},"reference-count":61,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T00:00:00Z","timestamp":1738108800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100005393","name":"Slovenian Research and Innovation Agency (ARIS)","doi-asserted-by":"publisher","award":["P1-0179"],"award-info":[{"award-number":["P1-0179"]}],"id":[{"id":"10.13039\/100005393","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A series of differently substituted \u03b2-enaminones 2a,b, 4a\u2013i, 8a\u2013d, and 9\u201313, their BF2-\u03b2-ketoiminate complexes 5a\u2013d, and BF2-\u03b2-diketonate complexes 6a\u2013d were prepared as model substrates for photochemical transformations. The attempted photochemical transformations of enaminones 2, 4, 8 and BF2-\u03b2-ketoiminate complexes 5 failed. On the other hand, irradiation of mixtures of BF2-\u03b2-diketonate complexes 6a\u2013d and cycloalkanes with UV-A light (365 nm) gave the corresponding De Mayo reaction products 7a\u2013f in 9\u201330% yields. The photochemical ring-expansion of acetyl tetralone-derived BF2-complex 6d gave novel diannulated cyclooctane derivatives 7e and 7f, which would be difficult to obtain using conventional cyclization methods.<\/jats:p>","DOI":"10.3390\/molecules30030601","type":"journal-article","created":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T03:26:10Z","timestamp":1738121170000},"page":"601","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Preparation and Transformations of Acetophenone-Derived Enamino Ketones, BF2-\u03b2-Ketoiminates, and BF2-\u03b2-Diketonates"],"prefix":"10.3390","volume":"30","author":[{"given":"Helena","family":"Brodnik","sequence":"first","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luka","family":"Ciber","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5186-9879","authenticated-orcid":false,"given":"Uro\u0161","family":"Gro\u0161elj","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3331-4885","authenticated-orcid":false,"given":"Nejc","family":"Petek","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8709-9853","authenticated-orcid":false,"given":"Bogdan","family":"\u0160tefane","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3339-3595","authenticated-orcid":false,"given":"Jurij","family":"Svete","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,1,29]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"277","DOI":"10.1039\/cs9770600277","article-title":"Enaminones","volume":"6","author":"Greenhill","year":"1977","journal-title":"Chem. Soc. Rev."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"2433","DOI":"10.1021\/cr020093y","article-title":"Synthesis of Heterocycles from Alkyl 3-(Dimethylamino)propenoates and Related Enaminones","volume":"104","author":"Stanovnik","year":"2004","journal-title":"Chem. Rev."},{"key":"ref_3","first-page":"187","article-title":"The structure and tautomerism of azo coupled \u03b2-Enaminones","volume":"86","year":"2010","journal-title":"Dyes Pigment."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"16437","DOI":"10.1039\/C5CC05891K","article-title":"Cyclic enaminones. Part I: Stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods","volume":"51","author":"Chattopadhyay","year":"2015","journal-title":"Chem. Commun."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"16450","DOI":"10.1039\/C5CC05892A","article-title":"Cyclic enaminones. Part II: Applications as versatile intermediates in alkaloid synthesis","volume":"51","author":"Chattopadhyay","year":"2015","journal-title":"Chem. Commun."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"587","DOI":"10.1055\/s-0040-1707328","article-title":"Recent Advances in Organic Synthesis Based on N,N-Dimethyl Enaminones","volume":"53","author":"Huang","year":"2021","journal-title":"Synthesis"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"131984","DOI":"10.1016\/j.tet.2021.131984","article-title":"Enaminones as building blocks in drug development: Recent advances in their chemistry, synthesis, and biological properties","volume":"83","author":"Amaye","year":"2021","journal-title":"Tetrahedron"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1508","DOI":"10.1002\/adsc.202200144","article-title":"Recent Advances in Reactions Using Enaminone in Water or Aqueous Medium","volume":"364","author":"Wang","year":"2022","journal-title":"Adv. Synth. Catal."},{"key":"ref_9","unstructured":"Rappaport, Z. (1994). Photochemistry of enamines and enaminones. Enamines, Yohn Wiley & Sons. Chapter 11."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"108977","DOI":"10.1016\/j.cclet.2023.108977","article-title":"Recent advances in visible light-mediated chemical transformations of enaminones","volume":"35","author":"Han","year":"2024","journal-title":"Chin. Chem. Lett."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1002\/adsc.202300647","article-title":"Harnessing the Power of the De Mayo Reaction: Unveiling a Photochemical and Photocatalytic Masked [2+2] Methodology for Organic Synthesis","volume":"366","author":"Salaverri","year":"2024","journal-title":"Adv. Synth. Catal."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"101860","DOI":"10.1016\/j.rechem.2024.101860","article-title":"The chemical organic reactions of \u03b2-diketones to prepare different \u03b2-diketone derivatives, their properties and its applications: A review","volume":"12","author":"Keshe","year":"2024","journal-title":"Results Chem."},{"key":"ref_13","unstructured":"Meyer, K., and O\u2019hare, D. (2022). 11.07\u2014Boron Complexes in Organic Synthesis. Comprehensive Organometallic Chemistry IV, Elsevier. [4th ed.]."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"3423","DOI":"10.1002\/ejoc.201500318","article-title":"Synthesis, Post-Modification and Fluorescence Properties of Boron Diketonate Complexes","volume":"2015","author":"Guieu","year":"2015","journal-title":"Eur. J. Org. Chem."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"101937","DOI":"10.1039\/C6RA23719C","article-title":"Borondifluoride \u03b2-diketonate complex as fluorescent organic nanoparticles: Aggregation-induced emission for cellular imaging","volume":"6","author":"Zhang","year":"2016","journal-title":"RSC Adv."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"5219","DOI":"10.1002\/chem.201504903","article-title":"Boron Difluoride Curcuminoid Fluorophores with Enhanced Two-Photon Excited Fluorescence Emission and Versatile Living-Cell Imaging Properties","volume":"22","author":"Kamada","year":"2016","journal-title":"Chem. Eur. J."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"162","DOI":"10.1016\/j.dyepig.2014.07.001","article-title":"Dicyanoboron diketonate dyes: Synthesis, photophysical properties and bioimaging","volume":"112","author":"Zhou","year":"2015","journal-title":"Dye. Pigment."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"e223","DOI":"10.1038\/am.2015.118","article-title":"Recent progress of optical functional nanomaterials based on organoboron complexes with \u03b2-diketonate, ketoiminate and diiminate","volume":"7","author":"Tanaka","year":"2015","journal-title":"NPG Asia Mater."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"110848","DOI":"10.1016\/j.dyepig.2022.110848","article-title":"N,O-bidentate BF2-enaminone complexes: Synthesis, electronic structure, photophysical properties, and biological behaviour","volume":"208","author":"Motverov","year":"2022","journal-title":"Dye. Pigment."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"2268","DOI":"10.1021\/ma500082e","article-title":"Conjugated Polymers Based on Tautomeric Units: Regulation of Main-Chain Conjugation and Expression of Aggregation Induced Emission Property via Boron-Complexation","volume":"47","author":"Yoshii","year":"2014","journal-title":"Macromolecules"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3339","DOI":"10.1021\/acs.macromol.9b02633","article-title":"N,N-Dimethyl-Substituted Boron Ketoiminates for Multicolor Fluorescent Initiators and Polymers","volume":"53","author":"Yang","year":"2020","journal-title":"Macromolecules"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"2279","DOI":"10.1021\/am405209w","article-title":"General Design Strategy for Aromatic Ketone-Based Single-Component Dual-Emissive Materials","volume":"6","author":"Zhang","year":"2014","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"3200","DOI":"10.1002\/ejic.200800243","article-title":"\u03b2-Diketonate, \u03b2-Ketoiminate, and \u03b2-Diiminate Complexes of Difluoroboron","volume":"2008","author":"Macedo","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"198","DOI":"10.1016\/j.dyepig.2018.05.001","article-title":"Diversity-oriented four-component synthesis of solid state luminescent difluoro oxazaborinines","volume":"157","author":"Dohe","year":"2018","journal-title":"Dyes Pigments"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"386","DOI":"10.1021\/acscombsci.7b00027","article-title":"Combinatorial Synthesis of Acacen-Type Ligands and Their Coordination Compounds","volume":"19","author":"Svete","year":"2017","journal-title":"ACS Comb. Sci."},{"key":"ref_26","doi-asserted-by":"crossref","unstructured":"Ciber, L., Po\u017egan, F., Brodnik, H., \u0160tefane, B., Svete, J., and Gro\u0161elj, U. (2022). Synthesis and Catalytic Activity of Organocatalysts Based on Enaminone and Benzenediamine Hydrogen Bond Donors. Catalysts, 12.","DOI":"10.3390\/catal12101132"},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Kotnik, T., Menart, S., Adam, \u017d., Bitenc, J., Ciber, L., Gro\u0161elj, U., Petek, N., \u0160tefane, B., Svete, J., and Genorio, B. (2024). Synthesis and Redox Activity of Polyenaminones for Sustainable Energy Storage Applications. Polymers, 16.","DOI":"10.3390\/polym16192700"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"2900","DOI":"10.1021\/ol100620j","article-title":"Selective Addition of Organolithium Reagents to BF2-Chelates of \u03b2-Ketoesters","volume":"12","year":"2010","journal-title":"Org. Lett."},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"Itoh, K., Okazaki, K., Sera, A., and Chow, Y.L. (1992). The photoaddition of enaminoketonatoboron difluorides with trans-stilbene. Chem. Commun., 1608\u20131609.","DOI":"10.1039\/c39920001608"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"963","DOI":"10.1021\/jo00240a006","article-title":"The 1-aza-Cope rearrangement. 1","volume":"53","author":"Wu","year":"1988","journal-title":"J. Org. Chem."},{"key":"ref_31","first-page":"5988","article-title":"The 1-aza-Cope rearrangement. 2","volume":"53","author":"Wu","year":"1988","journal-title":"J. Org. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"747","DOI":"10.1002\/0471264180.or075.04","article-title":"The Aza-Cope\/Mannich Reaction","volume":"75","author":"Overman","year":"2011","journal-title":"Organic Reactions"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"1573","DOI":"10.1002\/cber.19300630641","article-title":"\u00dcber die Einwirkung von Ammoniak und Aminen auf einige aliphatische und aromatische Oxymethylen-ketone","volume":"63","author":"Benary","year":"1930","journal-title":"Chem. Ber."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"879","DOI":"10.1002\/jhet.5570450337","article-title":"Reaction of \u03b2-dimethylaminovinyl ketones with hydroxylamine: A simple and useful method for synthesis of 3- and 5-substituted isoxazoles","volume":"45","author":"Rosa","year":"2008","journal-title":"J. Heterocycl. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"8291","DOI":"10.1016\/j.tet.2010.08.039","article-title":"Synthesis and photochromism of a series of new 2-unsubstituted 3-(2-benzylbenzoyl)quinolin-4(1H)-ones","volume":"66","author":"Larina","year":"2010","journal-title":"Tetrahedron"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"15020","DOI":"10.1039\/D0CC06834A","article-title":"An efficient method for the synthesis of 2-pyridones via C\u2013H bond functionalization","volume":"56","author":"Zhou","year":"2020","journal-title":"Chem. Commun."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"3039","DOI":"10.1002\/adsc.201100305","article-title":"Ruthenium-Catalyzed Asymmetric Hydrogenation of \u03b2-Keto- enamines: An Efficient Approach to Chiral \u03b3-Amino Alcohols","volume":"353","author":"Geng","year":"2011","journal-title":"Adv. Synth. Catal."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1002\/zfch.19860260312","article-title":"Vinamid-Mesogene\u2013[4-n-Alkoxy-phenyl]-[\u03b2-(4-n-alkoxy-phenyl)amino-vinyl]-ketone","volume":"26","author":"Hoffmann","year":"1986","journal-title":"Z. Chem."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"2815","DOI":"10.1002\/ejoc.200700064","article-title":"Ruthenium Complexes of Electronically Coupled Cyclopentadienone Ligands\u2014Catalysts for Transformations of Propargyl Alcohols","volume":"2007","author":"Haak","year":"2007","journal-title":"Eur. J. Org. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"10501","DOI":"10.1002\/slct.202002612","article-title":"Multi-Component Approach for Synthesis of Quinolinyl-1,4-dihydropyridines, Evaluation of Cytotoxicity against MCF7 and Molecular Docking Studies","volume":"5","author":"Suresh","year":"2020","journal-title":"ChemistrySelect"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"4189","DOI":"10.1002\/ejoc.201000607","article-title":"Acid-Catalyzed Cascade Reactions of Enaminones with Aldehydes: C\u2013H Functionalization To Afford 1,4-Dihydropyridines","volume":"2010","author":"Yang","year":"2010","journal-title":"Eur. J. Org. Chem."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"6753","DOI":"10.1039\/C9OB01137D","article-title":"Fe-Catalyzed enaminone synthesis from ketones and amines","volume":"17","author":"Wu","year":"2019","journal-title":"Org. Biomol. Chem."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"2880","DOI":"10.1016\/j.tetlet.2016.05.064","article-title":"Copper-catalyzed intramolecular oxidative amination of enaminone C\u2013H bond for the synthesis of imidazo [1,2-a]pyridines","volume":"57","author":"Wan","year":"2016","journal-title":"Tetrahedron Lett."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1256","DOI":"10.1021\/acs.orglett.8b00222","article-title":"Highly Site-Selective Metal-Free C\u2013H Acyloxylation of Stable Enamines","volume":"20","author":"Wang","year":"2018","journal-title":"Org. Lett."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"3632","DOI":"10.1021\/ja00428a041","article-title":"Nucleophilic substitution reactions of trans-3-methoxy-4\u2019-substituted acrylophenones","volume":"98","author":"Chu","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"ref_46","doi-asserted-by":"crossref","unstructured":"Roberts, E., and Turner, E.E. (1927). CCXXXIX.\u2014The factors controlling the formation of some derivatives of quinoline, and a new aspect of the problem of substitution in the quinoline series. J. Chem. Soc., 1832\u20131857.","DOI":"10.1039\/JR9270001832"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"8529","DOI":"10.1039\/C6OB01401A","article-title":"Efficient synthesis of pyrrolo [1,2-a]quinoxalines catalyzed by a Br\u00f8nsted acid through cleavage of C\u2013C bonds","volume":"14","author":"Xie","year":"2016","journal-title":"Org. Biomol. Chem."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"1456","DOI":"10.1080\/00397910801914343","article-title":"Simple and Efficient One-Pot, Three-Component, Solvent-Free Synthesis of \u03b2-Enaminones via Sonogashira Coupling\u2013Michael Addition Sequences","volume":"38","author":"Palimkar","year":"2008","journal-title":"Synth. Commun."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"9354","DOI":"10.1016\/j.tet.2007.07.004","article-title":"Synthesis and photoluminescence properties of BF2 complexes with 1,3-diketone ligands","volume":"63","author":"Ono","year":"2007","journal-title":"Tetrahedron"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"2245","DOI":"10.1055\/s-0039-1690881","article-title":"BX3-Mediated Intermolecular Formation of Functionalized 3-Halo-1H-indenes via Cascade Halo-Nazarov-Type Cyclization","volume":"52","author":"Kumari","year":"2020","journal-title":"Synthesis"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"4920","DOI":"10.1021\/ol102083v","article-title":"Synthesis and Characterization of Polycarbonyl Compounds via their BF2-Adducts","volume":"12","author":"Kersten","year":"2010","journal-title":"Org. Lett."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"1723","DOI":"10.1055\/a-1833-8927","article-title":"Unprecedented Rearrangement of \u03b2-Difluoroboryloxy Ethers: A Route to C-2 Alkyl-chromenones","volume":"33","author":"Saho","year":"2022","journal-title":"Synlett"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"9448","DOI":"10.1021\/ja020223k","article-title":"Diastereoselective Cycloreductions and Cycloadditions Catalyzed by Co(dpm)2-Silane (dpm = 2,2,6,6-tetramethylheptane-3,5-dionate): Mechanism and Partitioning of Hydrometallative versus Anion Radical Pathways","volume":"124","author":"Wang","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"5112","DOI":"10.1021\/ja0040971","article-title":"Diastereoselective Cobalt-Catalyzed Aldol and Michael Cycloreductions","volume":"123","author":"Baik","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref_55","unstructured":"(2011). CrysAlis PRO, Agilent Technologies UK Ltd."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","article-title":"OLEX2: A complete structure solution, refinement and analysis program","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cristallogr."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A short history of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr. A"},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","article-title":"SHELXT\u2014Integrated space-group and crystal-structure determination","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. Sect. Found. Adv."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal structure refinement with SHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. Sect. C Struct. Chem."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"453","DOI":"10.1107\/S002188980600731X","article-title":"Mercury: Visualization and analysis of crystal structures","volume":"39","author":"Macrae","year":"2006","journal-title":"J. Appl. Crystallogr."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1107\/S0021889802022112","article-title":"Single-crystal structure validation with the program PLATON","volume":"36","author":"Spek","year":"2003","journal-title":"J. Appl. Crystallogr."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/3\/601\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T10:38:07Z","timestamp":1759919887000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/3\/601"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,29]]},"references-count":61,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2025,2]]}},"alternative-id":["molecules30030601"],"URL":"https:\/\/doi.org\/10.3390\/molecules30030601","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,29]]}}}