{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T17:17:27Z","timestamp":1790356647047,"version":"4.1.0"},"reference-count":127,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2025,3,14]],"date-time":"2025-03-14T00:00:00Z","timestamp":1741910400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Recovery and Resilience Plan (NRRP)","award":["1561"],"award-info":[{"award-number":["1561"]}]},{"name":"National Recovery and Resilience Plan (NRRP)","award":["PE0000021"],"award-info":[{"award-number":["PE0000021"]}]},{"name":"National Recovery and Resilience Plan (NRRP)","award":["CUP C93C22005230007"],"award-info":[{"award-number":["CUP C93C22005230007"]}]},{"name":"European Union\u2014NextGenerationEU","award":["1561"],"award-info":[{"award-number":["1561"]}]},{"name":"European Union\u2014NextGenerationEU","award":["PE0000021"],"award-info":[{"award-number":["PE0000021"]}]},{"name":"European Union\u2014NextGenerationEU","award":["CUP C93C22005230007"],"award-info":[{"award-number":["CUP C93C22005230007"]}]},{"name":"Ministero dell\u2019Universit\u00e0 e della Ricerca (MUR)","award":["1561"],"award-info":[{"award-number":["1561"]}]},{"name":"Ministero dell\u2019Universit\u00e0 e della Ricerca (MUR)","award":["PE0000021"],"award-info":[{"award-number":["PE0000021"]}]},{"name":"Ministero dell\u2019Universit\u00e0 e della Ricerca (MUR)","award":["CUP C93C22005230007"],"award-info":[{"award-number":["CUP C93C22005230007"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The reaction between the iminophosphorane ligand N-phenyl-1,1,1-triphenylphosphanimine (NPh=PPh3) and anhydrous manganese(II) halides allowed the isolation of complexes with the general formula [MnX2(NPh=PPh3)2] (X = Cl, Br, I). The compounds showed luminescence in the green region attributed to the 4T1(4G)\u21926A1(6S) transition of the metal centre in the tetrahedral field, which was superimposed in the cases of X = Cl and X = Br on weak ligand-centred fluorescence. The emission and excitation spectra were compared with those of the free ligand and of the related zinc(II) bromo-complex. DFT calculations on the free ligand and on the manganese(II) bromo-complex helped to rationalise the experimental data. The protonation of NPh=PPh3 led to the formation of the iminium cation [NHPh=PPh3]+, which was used as a building block for the synthesis of organic\u2013inorganic hybrids with the general formula [NHPh=PPh3]2[MnX4] (X = Cl, Br, I). The crystal structure of [NHPh=PPh3]2[MnBr4] was determined by means of X-ray diffraction. Green photoluminescence associated with the metal-centred transition was also observed for the organic\u2013inorganic hybrids, with higher quantum yields with respect to the neutral [MnX2(NPh=PPh3)2] complexes. In the case of X = I, luminescence from the cation was superimposed on that from the tetraiodomanganate anion upon excitation of the compound with near\u2013UV light.<\/jats:p>","DOI":"10.3390\/molecules30061319","type":"journal-article","created":{"date-parts":[[2025,3,14]],"date-time":"2025-03-14T13:07:51Z","timestamp":1741957671000},"page":"1319","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Luminescent Manganese(II) Iminophosphorane Derivatives"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-2115-5817","authenticated-orcid":false,"given":"Domenico","family":"Piccolo","sequence":"first","affiliation":[{"name":"Dipartimento di Scienze Chimiche, Universit\u00e0 di Padova, Via Marzolo 1, 35131 Padova, Italy"},{"name":"Dipartimento di Scienze Molecolari e Nanosistemi, Universit\u00e0 Ca\u2019 Foscari Venezia, 30172 Mestre, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6169-3822","authenticated-orcid":false,"given":"Jes\u00fas","family":"Castro","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica, Facultade de Qu\u00edmica, Universidade de Vigo, Edificio de Ciencias Experimentais, 36310 Vigo, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6396-6035","authenticated-orcid":false,"given":"Daniele","family":"Rosa-Gastaldo","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Chimiche, Universit\u00e0 di Padova, Via Marzolo 1, 35131 Padova, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4259-1027","authenticated-orcid":false,"given":"Marco","family":"Bortoluzzi","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Molecolari e Nanosistemi, Universit\u00e0 Ca\u2019 Foscari Venezia, 30172 Mestre, Italy"},{"name":"CIRCC (Consorzio Universitario Reattivit\u00e0 Chimica e Catalisi), Via Celso Ulpiani 27, 70126 Bari, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,3,14]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"213331","DOI":"10.1016\/j.ccr.2020.213331","article-title":"Luminescent manganese(II) complexes: Synthesis, properties and optoelectronic applications","volume":"416","author":"Qin","year":"2020","journal-title":"Coord. 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