{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,21]],"date-time":"2026-01-21T18:43:15Z","timestamp":1769020995984,"version":"3.49.0"},"reference-count":60,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2025,3,24]],"date-time":"2025-03-24T00:00:00Z","timestamp":1742774400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Albemarle Corporation"},{"name":"Louisiana Board of Regents"},{"name":"LSU West Professorship"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Structural rearrangements in metal\u2013organic supramolecules constructed from the coordination of Cu(II) with m-xpt (m-xylylenebis(pyridyltriazole)) are investigated upon their interaction with 1,4-diazabicyclo[2.2.2]octane (dabco) and carbon dioxide-enriched air. The binuclear [Cu2(m-xpt)2]4+ complexes react with dabco to produce a carbonate-bridged trinuclear complex, [Cu3(m-xpt)3(\u00b5-CO3)]4+, and an oxalate-bridged binuclear complex, [Cu2(m-xpt)2(\u00b5-C2O4)]2+, where carbonate and oxalate likely originate from CO2 and dabco, respectively. The trinuclear complex reassembles the original dimer upon the removal of the carbonate ion. Similarly, polymeric [Cu(o-xpt)(PF6)]n, formed from Cu(I) and o-xpt (o-xylylenebis(pyridyltriazole)) coordination, undergoes oxidation in CO2-enriched air to yield a tetranuclear Cu(II) complex, Cu4(o-xpt)3(\u03bc4-CO3)(\u03bc2-OH)(\u03bc2-OCOCH3)4+. The reaction progress is monitored by UV-Vis spectroscopy, and the major products are characterized by single-crystal X-ray diffraction.<\/jats:p>","DOI":"10.3390\/molecules30071430","type":"journal-article","created":{"date-parts":[[2025,3,24]],"date-time":"2025-03-24T04:48:18Z","timestamp":1742791698000},"page":"1430","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Structural Rearrangement in Cyclic Cu(II) Pyridyltriazole Complexes: Oxidation of Dabco to Oxalate and CO2 Conversion to Carbonate"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7819-4851","authenticated-orcid":false,"given":"Uttam R.","family":"Pokharel","sequence":"first","affiliation":[{"name":"Department of Physical & Applied Science, University of Houston\u2014Clear Lake, Houston, TX 77058, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5544-2779","authenticated-orcid":false,"given":"Frank R.","family":"Fronczek","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9987-1663","authenticated-orcid":false,"given":"Andrew W.","family":"Maverick","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,3,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"611","DOI":"10.1039\/C4CS00094C","article-title":"Applications of metal-organic frameworks in heterogeneous supramolecular catalysis","volume":"43","author":"Liu","year":"2014","journal-title":"Chem. 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