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The modified MOF was achieved through a post-synthetic modification process involving the partial replacement of titanium with zirconium or cerium within the MOF\u2019s structure. The objective behind this alteration is to create a synergistic effect between the MOF, serving as a support matrix, and the embedded copper nanoparticles, thereby enhancing the performance of the catalyst. The obtained catalysts were characterized and evaluated in the hydrogenation of CO2 to methanol under different experimental conditions, reaching CO2 conversions of up to 5%, with a selectivity towards methanol that reached values of up to 60%. According to the obtained results, the catalyst composed of Ti, Zr and Cu stood out for having the highest CO2 conversion and selectivity towards methanol, in addition to practically inhibiting the production of methane. These results demonstrate that the interaction of the framework with the Cu nanoparticles, and thus its catalytic properties, can be changed by modifying the properties of the MOF.<\/jats:p>","DOI":"10.3390\/molecules30071458","type":"journal-article","created":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T12:18:52Z","timestamp":1742905132000},"page":"1458","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Tailoring Catalysts for CO2 Hydrogenation: Synthesis and Characterization of NH2\u2013MIL\u2013125 Frameworks"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4096-8764","authenticated-orcid":false,"given":"Leidy","family":"Figueroa-Quintero","sequence":"first","affiliation":[{"name":"Inorganic Chemistry Department, Laboratory of Advanced Materials, University Materials Institute of Alicante, University of Alicante, 03080 Alicante, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tom\u00e1s","family":"Cordero-Lanzac","sequence":"additional","affiliation":[{"name":"SMN Centre for Materials Science and Nanotechnology, Department of Chemistry, University of Oslo, Sem Saelands Vei 26, 0371 Oslo, Norway"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6357-0383","authenticated-orcid":false,"given":"Enrique V.","family":"Ramos-Fernandez","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry Department, Laboratory of Advanced Materials, University Materials Institute of Alicante, University of Alicante, 03080 Alicante, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Unni","family":"Olsbye","sequence":"additional","affiliation":[{"name":"SMN Centre for Materials Science and Nanotechnology, Department of Chemistry, University of Oslo, Sem Saelands Vei 26, 0371 Oslo, Norway"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Javier","family":"Narciso","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry Department, Laboratory of Advanced Materials, University Materials Institute of Alicante, University of Alicante, 03080 Alicante, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,3,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2557","DOI":"10.1016\/j.cherd.2014.03.005","article-title":"Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies","volume":"92","author":"Jadhav","year":"2014","journal-title":"Chem. 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