{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,2]],"date-time":"2026-06-02T19:31:12Z","timestamp":1780428672235,"version":"3.54.1"},"reference-count":41,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2025,4,3]],"date-time":"2025-04-03T00:00:00Z","timestamp":1743638400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFE0206500"],"award-info":[{"award-number":["2024YFE0206500"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["22033009"],"award-info":[{"award-number":["22033009"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["22072156"],"award-info":[{"award-number":["22072156"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["22073104"],"award-info":[{"award-number":["22073104"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["22121002"],"award-info":[{"award-number":["22121002"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022ZDZX031"],"award-info":[{"award-number":["2022ZDZX031"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"name":"National Science Foundation of China","award":["2024YFE0206500"],"award-info":[{"award-number":["2024YFE0206500"]}]},{"name":"National Science Foundation of China","award":["22033009"],"award-info":[{"award-number":["22033009"]}]},{"name":"National Science Foundation of China","award":["22072156"],"award-info":[{"award-number":["22072156"]}]},{"name":"National Science Foundation of China","award":["22073104"],"award-info":[{"award-number":["22073104"]}]},{"name":"National Science Foundation of China","award":["22121002"],"award-info":[{"award-number":["22121002"]}]},{"name":"National Science Foundation of China","award":["2022ZDZX031"],"award-info":[{"award-number":["2022ZDZX031"]}]},{"name":"Science and Technology Bureau of Tai\u2019an City","award":["2024YFE0206500"],"award-info":[{"award-number":["2024YFE0206500"]}]},{"name":"Science and Technology Bureau of Tai\u2019an City","award":["22033009"],"award-info":[{"award-number":["22033009"]}]},{"name":"Science and Technology Bureau of Tai\u2019an City","award":["22072156"],"award-info":[{"award-number":["22072156"]}]},{"name":"Science and Technology Bureau of Tai\u2019an City","award":["22073104"],"award-info":[{"award-number":["22073104"]}]},{"name":"Science and Technology Bureau of Tai\u2019an City","award":["22121002"],"award-info":[{"award-number":["22121002"]}]},{"name":"Science and Technology Bureau of Tai\u2019an City","award":["2022ZDZX031"],"award-info":[{"award-number":["2022ZDZX031"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>CO2 is a greenhouse gas and a nontoxic, easily available and renewable C1 feedstock. H2 is a clean and cheap reductant that can be obtained from renewable energy. Olefins are platform chemicals that can be produced from a variety of raw materials such as petroleum, coal and renewable biomass. The production of carboxylic acids by combining olefins, CO2 and H2 is a sustainable and very promising protocol. However, only a few advances in this topic have been achieved because novel catalysts need to be developed. In this work, we demonstrate that a simple iridium-based catalyst could efficiently promote the synthesis of C2+ carboxylic acids via the reaction of olefins with CO2 and H2. The reaction was effectively accelerated by a simple iridium-based catalytic system at 170 \u00b0C, which may be applied to various olefin substrates. The catalytic mechanism was studied through a series of control experiments. The findings contribute to advancing the sustainable production of valuable products by the reaction of renewable CO2 and green H2 with platform chemicals.<\/jats:p>","DOI":"10.3390\/molecules30071599","type":"journal-article","created":{"date-parts":[[2025,4,3]],"date-time":"2025-04-03T04:33:43Z","timestamp":1743654823000},"page":"1599","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Iridium-Catalyzed Hydrocarboxylation of Olefins with CO2 and H2"],"prefix":"10.3390","volume":"30","author":[{"given":"Yang","family":"Li","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0204-7262","authenticated-orcid":false,"given":"Ying","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Longbo","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanru","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Guo","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanyan","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenglong","family":"Yu","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"He","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenpeng","family":"Wang","sequence":"additional","affiliation":[{"name":"Center for Physicochemical Analysis Measurements, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juanjuan","family":"Han","sequence":"additional","affiliation":[{"name":"Center for Physicochemical Analysis Measurements, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, 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Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Buxing","family":"Han","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"},{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, 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