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In order to confer different solubility properties to the metal complexes and to stabilize Cu and Ag in their +1 oxidation state, the lipophilic triphenylphosphine (PPh3) and the hydrophilic 1,3,5-triaza-7-phosphaadamantane (PTA) were selected as co-ligands in the syntheses of the Cu(I) and Ag(I) complexes. All compounds were characterized by CHN analysis, NMR, FT-IR spectroscopy, and electrospray ionization mass spectrometry (ESI-MS); the molecular structure of the copper(II) complex [Cu(LBSPh)2] was also determined by single-crystal X-ray diffraction. Finally, the antibacterial activity of the metal complexes, the Schiff base ligands and phosphane co-ligands, were assessed by determining the minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) against Gram-negative (Escherichia coli) and Gram-positive bacteria (Staphylococcus aureus).<\/jats:p>","DOI":"10.3390\/molecules30091893","type":"journal-article","created":{"date-parts":[[2025,4,24]],"date-time":"2025-04-24T08:08:41Z","timestamp":1745482121000},"page":"1893","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["New Cu(II), Cu(I) and Ag(I) Complexes of Phenoxy-Ketimine Schiff Base Ligands: Synthesis, Structures and Antibacterial Activity"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-2522-6569","authenticated-orcid":false,"given":"Miriam","family":"Caviglia","sequence":"first","affiliation":[{"name":"School of Science and Technology, Chemistry Division, University of Camerino, Via Madonna Delle Carceri (ChIP), 62032 Camerino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-9649-4302","authenticated-orcid":false,"given":"Zhenzhen","family":"Li","sequence":"additional","affiliation":[{"name":"School of Science and Technology, Chemistry Division, University of Camerino, Via Madonna Delle Carceri (ChIP), 62032 Camerino, Italy"},{"name":"College of Material and Chemical Engineering, Institute of New Energy Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3942-1713","authenticated-orcid":false,"given":"Carlo","family":"Santini","sequence":"additional","affiliation":[{"name":"School of Science and Technology, Chemistry Division, University of Camerino, Via Madonna Delle Carceri (ChIP), 62032 Camerino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-8969-0900","authenticated-orcid":false,"given":"Jo\u2019","family":"Del Gobbo","sequence":"additional","affiliation":[{"name":"School of Science and Technology, Chemistry Division, University of Camerino, Via Madonna Delle Carceri (ChIP), 62032 Camerino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7289-0941","authenticated-orcid":false,"given":"Cristina","family":"Cimarelli","sequence":"additional","affiliation":[{"name":"School of Science and Technology, Chemistry Division, University of Camerino, Via Madonna Delle Carceri (ChIP), 62032 Camerino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1029-1820","authenticated-orcid":false,"given":"Miao","family":"Du","sequence":"additional","affiliation":[{"name":"College of Material and Chemical Engineering, Institute of New Energy Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1287-6635","authenticated-orcid":false,"given":"Alessandro","family":"Dolmella","sequence":"additional","affiliation":[{"name":"Department of Pharmaceutical and Pharmacological Sciences, University of Padova, Via Marzolo 5, 35131 Padova, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5020-1730","authenticated-orcid":false,"given":"Maura","family":"Pellei","sequence":"additional","affiliation":[{"name":"School of Science and Technology, Chemistry Division, University of Camerino, Via Madonna Delle Carceri (ChIP), 62032 Camerino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,4,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Hofer, U. (2019). The cost of antimicrobial resistance. Nat. Rev. Microbiol., 17.","DOI":"10.1038\/s41579-019-0161-1"},{"key":"ref_2","unstructured":"World Health Organization (2024, November 01). WHO Bacterial Priority Pathogens List, 2024: Bacterial Pathogens of Public Health Importance to Guide Research, Development and Strategies to Prevent and Control Antimicrobial Resistance. Available online: https:\/\/www.who.int\/publications\/i\/item\/9789240093461."},{"key":"ref_3","unstructured":"World Health Organization (2024, November 01). WHO Publishes List of Bacteria for Which New Antibiotics Are Urgently Needed. Available online: https:\/\/www.who.int\/en\/news-room\/detail\/27-02-2017-who-publishes-list-of-bacteria-for-which-new-antibiotics-are-urgently-needed."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"202","DOI":"10.1038\/s41570-023-00463-4","article-title":"Metals to combat antimicrobial resistance","volume":"7","author":"Frei","year":"2023","journal-title":"Nat. Rev. Chem."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"115413","DOI":"10.1016\/j.ejmech.2023.115413","article-title":"Antibiotics with novel mode of action as new weapons to fight antimicrobial resistance","volume":"256","author":"Ruggieri","year":"2023","journal-title":"Eur. J. Med. Chem."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"726","DOI":"10.1038\/s41570-021-00313-1","article-title":"Towards the sustainable discovery and development of new antibiotics","volume":"5","author":"Miethke","year":"2021","journal-title":"Nat. Rev. Chem."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"10346","DOI":"10.1039\/D0CS00945H","article-title":"Recent developments of metal-based compounds against fungal pathogens","volume":"50","author":"Lin","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"E398","DOI":"10.1016\/S2542-5196(18)30186-4","article-title":"Anthropological and socioeconomic factors contributing to global antimicrobial resistance: A univariate and multivariable analysis","volume":"2","author":"Collignon","year":"2018","journal-title":"Lancet Planetary Health"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"5106","DOI":"10.1039\/c3cc41143e","article-title":"Exploration of the medical periodic table: Towards new targets","volume":"49","author":"Barry","year":"2013","journal-title":"Chem. Commun."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"4540","DOI":"10.1021\/cr400460s","article-title":"Metallodrugs in Medicinal Inorganic Chemistry","volume":"114","author":"Mjos","year":"2014","journal-title":"Chem. Rev."},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Cvijan, B.B., Jacic, J.K., and Bajcetic, M. (2023). The Impact of Copper Ions on the Activity of Antibiotic Drugs. Molecules, 28.","DOI":"10.3390\/molecules28135133"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"2627","DOI":"10.1039\/C9SC06460E","article-title":"Metal complexes as a promising source for new antibiotics","volume":"11","author":"Frei","year":"2020","journal-title":"Chem. Sci."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"108710","DOI":"10.1016\/j.inoche.2021.108710","article-title":"Coordination metal complexes with Schiff bases: Useful pharmacophores with comprehensive biological applications","volume":"130","author":"Ghanghas","year":"2021","journal-title":"Inorg. Chem. Commun."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"129402","DOI":"10.1016\/j.molstruc.2020.129402","article-title":"Cobalt and ruthenium complexes with pyrimidine based Schiff base: Synthesis, characterization, anticancer activities and electrochemotherapy efficiency","volume":"1226","author":"Alkis","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"100195","DOI":"10.1016\/j.mtchem.2019.100195","article-title":"Metal complexes driven from Schiff bases and semicarbazones for biomedical and allied applications: A review","volume":"14","author":"More","year":"2019","journal-title":"Mater. Today Chem."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"5834","DOI":"10.1039\/C8NJ00357B","article-title":"Interactions of Schiff base compounds and their coordination complexes with the drug cisplatin","volume":"42","author":"Magyari","year":"2018","journal-title":"New J. Chem."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"810","DOI":"10.1002\/aoc.3506","article-title":"Synthesis and antioxidant activities of Schiff bases and their complexes: A review","volume":"30","author":"Kaseem","year":"2016","journal-title":"Appl. Organomet. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/j.jorganchem.2016.08.023","article-title":"Organometallic complexes of Schiff bases: Recent progress in oxidation catalysis","volume":"822","author":"Ko","year":"2016","journal-title":"J. Organomet. Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1597","DOI":"10.1021\/cr400559g","article-title":"Molecular Assembly of Schiff Base Interactions: Construction and Application","volume":"115","author":"Jia","year":"2015","journal-title":"Chem. Rev."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"12264","DOI":"10.3390\/molecules181012264","article-title":"Schiff Bases: A Short Survey on an Evergreen Chemistry Tool","volume":"18","author":"Qin","year":"2013","journal-title":"Molecules"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"1420","DOI":"10.1016\/j.ccr.2007.09.005","article-title":"Catalytic activities of Schiff base transition metal complexes","volume":"252","author":"Gupta","year":"2008","journal-title":"Coord. Chem. Rev."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1847","DOI":"10.1002\/macp.200500290","article-title":"Propylene Polymerization Behavior of Fluorinated Bis(phenoxy-imine) Ti Complexes with an MgCl2-Based Compound (MgCl2-Supported Ti-Based Catalysts)","volume":"206","author":"Nakayama","year":"2005","journal-title":"Macromol. Chem. Phys."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"1717","DOI":"10.1016\/j.cct.2003.09.003","article-title":"The challenge of cyclic and acyclic Schiff bases and related derivatives","volume":"248","author":"Vigato","year":"2004","journal-title":"Coord. Chem. Rev."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"410","DOI":"10.1039\/B307853C","article-title":"Metal-Salen Schiff base complexes in catalysis: Practical aspects","volume":"33","author":"Cozzi","year":"2004","journal-title":"Chem. Soc. Rev."},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Akitsu, T. (2024). Novelties in Schiff Bases, IntechOpen.","DOI":"10.5772\/intechopen.114475"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"841","DOI":"10.1080\/13543776.2023.2297729","article-title":"Part-II: An update of Schiff bases synthesis and applications in medicinal chemistry-a patent review (2016\u20132023)","volume":"33","author":"Younus","year":"2023","journal-title":"Expert Opin. Ther. Patents"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"e202104290","DOI":"10.1002\/slct.202104290","article-title":"Recent Progress in Metal-Incorporated Acyclic Schiff-Base Derivatives: Biological Aspects","volume":"7","author":"Nath","year":"2022","journal-title":"ChemistrySelect"},{"key":"ref_28","doi-asserted-by":"crossref","unstructured":"Soroceanu, A., and Bargan, A. (2022). Advanced and Biomedical Applications of Schiff-Base Ligands and Their Metal Complexes: A Review. Crystals, 12.","DOI":"10.3390\/cryst12101436"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"30186","DOI":"10.1039\/D0RA05720G","article-title":"A review on biological activities of Schiff base, hydrazone, and oxime derivatives of curcumin","volume":"10","author":"Omidi","year":"2020","journal-title":"RSC Adv."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"e5687","DOI":"10.1002\/aoc.5687","article-title":"Recent advances in anticancer ruthenium Schiff base complexes","volume":"34","author":"Parveen","year":"2020","journal-title":"Appl. Organomet. Chem."},{"key":"ref_31","doi-asserted-by":"crossref","unstructured":"Khan, A.M., Abid, O.U.R., and Mir, S. (2020). Assessment of biological activities of chitosan Schiff base tagged with medicinal plants. Biopolymers, 111.","DOI":"10.1002\/bip.23338"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1080\/13543776.2017.1252752","article-title":"Schiff bases in medicinal chemistry: A patent review (2010\u20132015)","volume":"27","author":"Hameed","year":"2017","journal-title":"Expert Opin. Ther. Patents"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"829","DOI":"10.1002\/bio.3259","article-title":"New phthalimide-appended Schiff bases: Studies of DNA binding, molecular docking and antioxidant activities","volume":"32","author":"Nayab","year":"2017","journal-title":"Luminescence"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"124","DOI":"10.2174\/138527209787193774","article-title":"Biological Properties of Schiff Bases and Azo Derivatives of Phenols","volume":"13","author":"Przybylski","year":"2009","journal-title":"Curr. Org. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"216327","DOI":"10.1016\/j.ccr.2024.216327","article-title":"Recent advances of Schiff base metal complexes as potential anticancer agents","volume":"525","author":"Lv","year":"2025","journal-title":"Coord. Chem. Rev."},{"key":"ref_36","doi-asserted-by":"crossref","unstructured":"Kadhum, A.M., Mallah, S.H., Waheeb, A.S., Salman, A.W., Zafar, A., Ahmad, N.S., Siraj, S., and Iqbal, M.A. (2024). Advancement in Schiff base complexes for treatment of colon cancer. Rev. Inorg. Chem., 1\u201321.","DOI":"10.1515\/revic-2024-0068"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"101350","DOI":"10.1016\/j.rechem.2024.101350","article-title":"Recent advances in biological and medicinal profile of Schiff bases and their metal complexes: An updated version (2018\u20132023)","volume":"7","author":"Thakur","year":"2024","journal-title":"Results Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"2330","DOI":"10.2174\/0929867330666230224092830","article-title":"Recent Advances on the Antimicrobial Activities of Schiff Bases and their Metal Complexes: An Updated Overview","volume":"31","author":"Jorge","year":"2024","journal-title":"Curr. Med. Chem."},{"key":"ref_39","doi-asserted-by":"crossref","unstructured":"Ceramella, J., Iacopetta, D., Catalano, A., Cirillo, F., Lappano, R., and Sinicropi, M.S. (2022). A Review on the Antimicrobial Activity of Schiff Bases: Data Collection and Recent Studies. Antibiotics, 11.","DOI":"10.3390\/antibiotics11020191"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"418","DOI":"10.3390\/chemistry2020026","article-title":"Recent Studies on the Antimicrobial Activity of Transition Metal Complexes of Groups 6\u201312","volume":"2","author":"Sovari","year":"2020","journal-title":"Chemistry"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"409","DOI":"10.1039\/C7MD00526A","article-title":"Heterocyclic Schiff base transition metal complexes in antimicrobial and anticancer chemotherapy","volume":"9","author":"Malik","year":"2018","journal-title":"MedChemComm"},{"key":"ref_42","doi-asserted-by":"crossref","unstructured":"Hassan, M.A., Omer, A.M., Abbas, E., Baset, W.M.A., and Tamer, T.M. (2018). Preparation, physicochemical characterization and antimicrobial activities of novel two phenolic chitosan Schiff base derivatives. Sci. Rep., 8.","DOI":"10.1038\/s41598-018-29650-w"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"2269","DOI":"10.1021\/bc5004907","article-title":"Conjugation of a New Series of Dithiocarbazate Schiff Base Copper(II) Complexes with Vectors Selected to Enhance Antibacterial Activity","volume":"25","author":"Low","year":"2014","journal-title":"Bioconjug. Chem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jare.2010.05.004","article-title":"Schiff bases: A short review of their antimicrobial activities","volume":"2","author":"Modolo","year":"2011","journal-title":"J. Adv. Res."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"2639","DOI":"10.1016\/j.ejmech.2008.02.013","article-title":"Synthesis, spectral characterization, in vitro antibacterial, antifungal and cytotoxic activities of Co(II), Ni(II) and Cu(II) complexes with 1,2,4-triazole Schiff bases","volume":"43","author":"Bagihalli","year":"2008","journal-title":"Eur. J. Med. Chem."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"110449","DOI":"10.1016\/j.inoche.2023.110449","article-title":"Pharmacological aspects of Schiff base metal complexes: A critical review","volume":"150","author":"Ashraf","year":"2023","journal-title":"Inorg. Chem. Commun."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"883","DOI":"10.1007\/s12039-016-1091-3","article-title":"Salicylaldimine Copper(II) complex catalyst: Pioneer for ring opening Polymerization of Lactide","volume":"128","author":"Routaray","year":"2016","journal-title":"J. Chem. Sci."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"4033","DOI":"10.1016\/j.poly.2007.04.039","article-title":"Ni(II) and Cu(II) complexes of phenoxy-ketimine ligands: Synthesis, structures and their utility in bulk ring-opening polymerization (ROP) of L-lactide","volume":"26","author":"John","year":"2007","journal-title":"Polyhedron"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"112710","DOI":"10.1016\/j.dyepig.2025.112710","article-title":"Recent advances in Schiff base coinage metal complexes as anticancer agents: A comprehensive review (2021\u20132025)","volume":"237","author":"Felemban","year":"2025","journal-title":"Dyes Pigment."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1080\/00958972.2025.2477589","article-title":"Molecular docking study and in vitro evaluation of apoptotic effect of biogenic-amine-based N, O-Cu(II) complexes as potent antitumor agents","volume":"78","author":"Babic","year":"2025","journal-title":"J. Coord. Chem."},{"key":"ref_51","doi-asserted-by":"crossref","unstructured":"Kumar, V., and Kataria, R. (2024). Phenanthroline and Schiff Base associated Cu(II)-coordinated compounds containing N, O as donor atoms for potent anticancer activity. J. Inorg. Biochem., 251.","DOI":"10.1016\/j.jinorgbio.2023.112440"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"815","DOI":"10.1021\/cr400135x","article-title":"Advances in Copper Complexes as Anticancer Agents","volume":"114","author":"Santini","year":"2014","journal-title":"Chem. Rev."},{"key":"ref_53","doi-asserted-by":"crossref","unstructured":"Panova, E.V., Voronina, J.K., and Safin, D.A. (2023). Copper(II) Chelates of Schiff Bases Enriched with Aliphatic Fragments: Synthesis, Crystal Structure, In Silico Studies of ADMET Properties and a Potency against a Series of SARS-CoV-2 Proteins. Pharmaceuticals, 16.","DOI":"10.3390\/ph16020286"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"12540","DOI":"10.1039\/D2NJ02170F","article-title":"Copper(II) salen-based complexes as potential anticancer agents","volume":"46","author":"Mohan","year":"2022","journal-title":"New J. Chem."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"13704","DOI":"10.1021\/acsomega.1c00906","article-title":"Design of New Schiff-Base Copper(II) Complexes: Synthesis, Crystal Structures, DFT Study, and Binding Potency toward Cytochrome P450 3A4","volume":"6","author":"Yusuf","year":"2021","journal-title":"ACS Omega"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"120004","DOI":"10.1016\/j.ica.2020.120004","article-title":"Novel copper(II) and zinc(II) complexes of halogenated bidentate N,O-donor Schiff base ligands: Synthesis, characterization, crystal structures, DNA binding, molecular docking, DFT and TD-DFT computational studies","volume":"514","author":"Kargar","year":"2021","journal-title":"Inorg. Chim. Acta"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"41737","DOI":"10.1039\/C9RA07298E","article-title":"The synthesis of a Cu(II) Schiff base complex using a bidentate N2O2 donor ligand: Crystal structure, photophysical properties, and antibacterial activities","volume":"9","author":"Guo","year":"2019","journal-title":"RSC Adv."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"9073","DOI":"10.1039\/C6DT00461J","article-title":"Mixed-ligand copper(II) Schiff base complexes: The role of the co-ligand in DNA binding, DNA cleavage, protein binding and cytotoxicity","volume":"45","author":"Lian","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"1803","DOI":"10.1016\/j.saa.2011.05.062","article-title":"Synthesis, spectral characterization, solution equilibria, in vitro antibacterial and cytotoxic activities of Cu(II), Ni(II), Mn(II), Co(II) and Zn(II) complexes with Schiff base derived from 5-bromosalicylaldehyde and 2-aminomethylthiophene","volume":"79","author":"Eldebss","year":"2011","journal-title":"Spectrochim. Acta Part A"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1016\/j.jinorgbio.2006.10.004","article-title":"DNA-binding and cleavage studies of novel binuclear copper(II) complex with 1,1\u2032-dimethyl-2,2\u2032-biimidazole ligand","volume":"101","author":"Li","year":"2007","journal-title":"J. Inorg. Biochem."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"1888","DOI":"10.1016\/j.jinorgbio.2006.07.014","article-title":"Synthesis, structure and biological activity of cobalt(II) and copper(II) complexes of valine-derived Schiff bases","volume":"100","author":"Lv","year":"2006","journal-title":"J. Inorg. Biochem."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/S0010-8545(99)00165-4","article-title":"Complexes of macrocycles with pendant arms as models for biological molecules","volume":"196","author":"Costamagna","year":"2000","journal-title":"Coord. Chem. Rev."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"117071","DOI":"10.1016\/j.poly.2024.117071","article-title":"Synthesis, structural studies and antimicrobial activity of copper(II) complexes derived from 2,4-difluoro-6-(((2-(pyrrolidin-1-yl)ethyl)imino) methyl)phenol","volume":"259","author":"Lei","year":"2024","journal-title":"Polyhedron"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"115549","DOI":"10.1016\/j.ejmech.2023.115549","article-title":"Versatile applications of transition metal incorporating quinoline Schiff base metal complexes: An overview","volume":"258","author":"Sonawane","year":"2023","journal-title":"Eur. J. Med. Chem."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"136346","DOI":"10.1016\/j.molstruc.2023.136346","article-title":"Recent advances in synthesis of heterocyclic Schiff base transition metal complexes and their antimicrobial activities especially antibacterial and antifungal","volume":"1294","author":"Kumar","year":"2023","journal-title":"J. Mol. Struct."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"e6760","DOI":"10.1002\/aoc.6760","article-title":"Synthesis, characterization, in vitro antimicrobial and cytotoxic studies of Co(II), Ni(II), Cu(II), and Zn(II) complexes obtained from Schiff base ligands of 1, 2, 3, 4-tetrahydro-naphthalen-1-ylamine","volume":"36","author":"Devi","year":"2022","journal-title":"Appl. Organomet. Chem."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"24087","DOI":"10.1039\/C9RA03586A","article-title":"Tetranuclear Cu(II)-chiral complexes: Synthesis, characterization and biological activity","volume":"9","author":"Peewasan","year":"2019","journal-title":"RSC Adv."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"15151","DOI":"10.1039\/C9RA02600B","article-title":"New transition metal complexes with a pendent indole ring: Insights into the antifungal activity and mode of action","volume":"9","author":"Dar","year":"2019","journal-title":"RSC Adv."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"129908","DOI":"10.1016\/j.molstruc.2021.129908","article-title":"Synthesis, crystal structure, theoretical calculation, spectroscopic and antibacterial activity studies of copper(II) complexes bearing bidentate Schiff base ligands derived from 4-aminoantipyrine: Influence of substitutions on antibacterial activity","volume":"1230","author":"Kargar","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"1534","DOI":"10.1080\/00958972.2021.1900831","article-title":"Some new Cu(II) complexes containing O,N-donor Schiff base ligands derived from 4-aminoantipyrine: Synthesis, characterization, crystal structure and substitution effect on antimicrobial activity","volume":"74","author":"Kargar","year":"2021","journal-title":"J. Coord. Chem."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"1060","DOI":"10.1002\/jccs.201800027","article-title":"Synthesis, characterization, biological activity, and corrosion inhibition in acid medium of unsymmetrical tetradentate N2O2 Schiff base complexes","volume":"65","author":"Alturiqi","year":"2018","journal-title":"J. Chin. Chem. Soc."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1016\/j.molstruc.2025.142051","article-title":"Anion-directed synthesis of copper(I\/II) complexes with a Schiff base derived from 2-(diphenylphosphino)benzaldehyde and aminoguanidine","volume":"1336","author":"Regojevic","year":"2025","journal-title":"J. Mol. Struct."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"4837","DOI":"10.1016\/j.ica.2009.06.033","article-title":"Two different 1D-chains in the structures of the copper(I) coordination polymers based on bidentate Schiff-base building units and thiocyanate anions as bridging ligands","volume":"362","author":"Khalaji","year":"2009","journal-title":"Inorg. Chim. Acta"},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"1637","DOI":"10.1016\/j.ica.2008.07.002","article-title":"New (NS)2 Schiff base with a flexible spacer: Synthesis and structural characterization of its first coordination polymer [Cu2(l-I)2(l-(thio)2dapte)]n (1)","volume":"362","author":"Morshedi","year":"2009","journal-title":"Inorg. Chim. Acta"},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"e202400080","DOI":"10.1002\/ejic.202400080","article-title":"Substituted Pyrrole-based Schiff Bases: Effect on the Luminescence of Neutral Heteroleptic Cu(I) Complexes","volume":"27","author":"Ferraro","year":"2024","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"7172","DOI":"10.1021\/ic2007588","article-title":"Synthesis and Characterization of Neutral Luminescent Diphosphine Pyrrole- and Indole-Aldimine Copper(I) Complexes","volume":"50","author":"Crestani","year":"2011","journal-title":"Inorg. Chem."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"116002","DOI":"10.1016\/j.poly.2022.116002","article-title":"Schiff base-type Cu(I) complexes containing naphthylpyridyl-methanimine ligands featuring higher light-absorption capability: Synthesis, structures, and photophysical properties","volume":"224","author":"Lv","year":"2022","journal-title":"Polyhedron"},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"131638","DOI":"10.1016\/j.molstruc.2021.131638","article-title":"Schiff base-type copper(I) complexes exhibiting high molar extinction coefficients: Synthesis, characterization and DFT studies","volume":"1249","author":"Lv","year":"2022","journal-title":"J. Mol. Struct."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"132180","DOI":"10.1016\/j.molstruc.2021.132180","article-title":"Orange-red emissive Cu(I) complexes bearing Schiff base ligands: Synthesis, structures, and photophysical properties","volume":"1252","author":"Lv","year":"2022","journal-title":"J. Mol. Struct."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1016\/S0305-4179(99)00116-3","article-title":"A historical review of the use of silver in the treatment of burns. II. Renewed interest for silver","volume":"26","author":"Klasen","year":"2000","journal-title":"Burns"},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"2735","DOI":"10.1007\/s12274-020-3279-6","article-title":"Schiff-base silver nanocomplexes formation on natural biopolymer coated mesoporous silica contributed to the improved curative effect on infectious microbes","volume":"14","author":"Cai","year":"2021","journal-title":"Nano Res."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"3840","DOI":"10.1080\/00958972.2014.974582","article-title":"Review: Antibacterial behavior of carboxylate silver(I) complexes","volume":"67","author":"Paez","year":"2014","journal-title":"J. Coord. Chem."},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/S0162-0134(97)00006-8","article-title":"Ag(I)-N bond-containing compound showing wide spectra in effective antimicrobial activities: Polymeric silver(I) imidazolate","volume":"68","author":"Nomiya","year":"1997","journal-title":"J. Inorg. Biochem."},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1515\/revic-2021-0034","article-title":"Schiff bases and their metal complexes with biologically compatible metal ions; biological importance, recent trends and future hopes","volume":"42","author":"Khan","year":"2022","journal-title":"Rev. Inorg. Chem."},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.molstruc.2017.01.061","article-title":"Silver(I)-pyridinyl Schiff base complexes: Synthesis, characterisation and antimicrobial studies","volume":"1135","author":"Njogu","year":"2017","journal-title":"J. Mol. Struct."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"121760","DOI":"10.1016\/j.ica.2023.121760","article-title":"DNA\/BSA binding studies and in vitro anticancer and antibacterial studies of isoelectronic Cu(I)- and Ag(I)-pyridinyl Schiff base complexes incorporating triphenylphosphine as co-ligands","volume":"558","author":"Adeleke","year":"2023","journal-title":"Inorg. Chim. Acta"},{"key":"ref_87","doi-asserted-by":"crossref","unstructured":"Raczuk, E., Dmochowska, B., Samaszko-Fiertek, J., and Madaj, J. (2022). Different Schiff Bases-Structure, Importance and Classification. Molecules, 27.","DOI":"10.3390\/molecules27030787"},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"2974","DOI":"10.1039\/C5DT03897A","article-title":"Lanthanide salen-type complexes exhibiting single ion magnet and photoluminescent properties","volume":"45","author":"Ren","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"8436","DOI":"10.1021\/acs.inorgchem.5b01128","article-title":"Coordination Structure Conversion of Hydrazone-Palladium(II) Complexes in the Solid State and in Solution","volume":"54","author":"Kitamura","year":"2015","journal-title":"Inorg. Chem."},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"61232","DOI":"10.1039\/C4RA11716F","article-title":"Synthesis, characterization and biological evaluation of cationic hydrazone copper complexes with diverse diimine co-ligands","volume":"4","author":"Chew","year":"2014","journal-title":"RSC Adv."},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"12440","DOI":"10.1021\/ic401362s","article-title":"Synthesis, Characterization, and Anticancer Activity of a Series of Ketone-N4-Substituted Thiosemicarbazones and Their Ruthenium(II) Arene Complexes","volume":"52","author":"Su","year":"2013","journal-title":"Inorg. Chem."},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"622","DOI":"10.1039\/C1CS15170C","article-title":"Recent advances with \u03c0-conjugated salen systems","volume":"41","author":"Whiteoak","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"4423","DOI":"10.1039\/c2dt11938b","article-title":"Copper(I) and nickel(II) complexes with 1:1 vs. 1:2 coordination of ferrocenyl hydrazone ligands: Do the geometry and composition of complexes affect DNA binding\/cleavage, protein binding, antioxidant and cytotoxic activities?","volume":"41","author":"Krishnamoorthy","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_94","doi-asserted-by":"crossref","first-page":"4054","DOI":"10.1080\/00958972.2012.731595","article-title":"Synthesis and characterization of NaY zeolite-encapsulated Mn-hydrazone Schiff base: An efficient and reusable catalyst for oxidation of olefins","volume":"65","author":"Bagherzadeh","year":"2012","journal-title":"J. Coord. Chem."},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"5791","DOI":"10.1021\/om300334z","article-title":"Exploring the Versatility of Cycloplatinated Thiosemicarbazones as Antitumor and Antiparasitic Agents","volume":"31","author":"Chellan","year":"2012","journal-title":"Organometallics"},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"9323","DOI":"10.1039\/c2dt12231f","article-title":"One pot synthesis of structurally different mono and dimeric Ni(II) thiosemicarbazone complexes and N-arylation on a coordinated ligand: A comparative biological study","volume":"41","author":"Prabhakaran","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1016\/j.molstruc.2011.05.029","article-title":"Tautomeric Schiff bases: Iono-, solvato-, thermo- and photochromism","volume":"998","author":"Minkin","year":"2011","journal-title":"J. Mol. Struct."},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/j.molstruc.2004.06.030","article-title":"Characterisation of the PT-form of o-hydroxy acylarornatic Schiff bases by NMR spectroscopy and DFT calculations","volume":"707","author":"Hansen","year":"2004","journal-title":"J. Mol. Struct."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"963","DOI":"10.1002\/chem.200390118","article-title":"Neutral and ionic hydrogen bonding in Schiff bases","volume":"9","author":"Dominiak","year":"2003","journal-title":"Chem. Eur. J."},{"key":"ref_100","doi-asserted-by":"crossref","first-page":"2131","DOI":"10.1021\/jp035009c","article-title":"Proton transfer equilibria in Schiff bases with steric repulsion","volume":"108","author":"Filarowski","year":"2004","journal-title":"J. Phys. Chem. A"},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/S0022-2860(98)00660-7","article-title":"Strengthening of the intramolecular O\u22efH\u22efN hydrogen bonds in Schiff bases as a result of steric repulsion","volume":"484","author":"Filarowski","year":"1999","journal-title":"J. Mol. Struct."},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"4140","DOI":"10.1021\/acs.orglett.2c01349","article-title":"Access to ortho-Hydroxyphenyl Ketimines via Imine Anion-Mediated Smiles Rearrangement","volume":"24","author":"Jinno","year":"2022","journal-title":"Org. Lett."},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"5350","DOI":"10.1002\/anie.201800435","article-title":"2-Hydroxybenzophenone as a Chemical Auxiliary for the Activation of Ketiminoesters for Highly Enantioselective Addition to Nitroalkenes under Bifunctional Catalysis","volume":"57","author":"Esteban","year":"2018","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_104","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/j.ica.2015.11.023","article-title":"Synthesis, structure and catalytic activity of bis(phenoxyiminato)iron(III) complexes in coupling reaction of CO2 and epoxides","volume":"442","author":"Genjang","year":"2016","journal-title":"Inorg. Chim. Acta"},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/j.molcata.2009.07.009","article-title":"Efficient coupling of CO2 and epoxides with bis(phenoxyiminato) cobalt(III)\/Lewis base catalysts","volume":"312","author":"Sibaouih","year":"2009","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_106","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1016\/j.molcata.2006.04.012","article-title":"Catalyst poisoning in catalyzed imine hydrogenation: A novel zwitterionic Rh(I)\/o-hydroxy-substituted imine complex","volume":"257","author":"Marcazzan","year":"2006","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_107","doi-asserted-by":"crossref","first-page":"2011","DOI":"10.1016\/S0957-4166(02)00544-X","article-title":"Synthesis of enantiopure 2-aminoalkylphenols by stereoselective addition of Grignard reagents to chiral 2-imidoylphenols","volume":"13","author":"Cimarelli","year":"2002","journal-title":"Tetrahedron Asymmetry"},{"key":"ref_108","doi-asserted-by":"crossref","unstructured":"Mondal, B., Chakraborty, S., Munshi, P., Walawalkar, M.G., and Lahiri, G.K. (2000). Ruthenium-(II)\/-(III) terpyridine complexes incorporating imine functionalities. Synthesis, structure, spectroscopic and electrochemical properties. J. Chem. Soc. Dalton Trans., 2327\u20132335.","DOI":"10.1039\/b000257g"},{"key":"ref_109","doi-asserted-by":"crossref","first-page":"1387","DOI":"10.1016\/S0277-5387(97)00277-5","article-title":"Ruthenium(II) bipyridine complexes with modified phenolic Schiff base ligands. Synthesis, spectroscopic characterization and redox properties","volume":"17","author":"Keerthi","year":"1998","journal-title":"Polyhedron"},{"key":"ref_110","doi-asserted-by":"crossref","first-page":"1517","DOI":"10.1016\/S0277-5387(96)00436-6","article-title":"New tetradentate Schiff bases, their oxovanadium(IV) complexes, and some complexes of bidentate Schiff bases with vanadium(III)","volume":"16","author":"Choudhary","year":"1997","journal-title":"Polyhedron"},{"key":"ref_111","doi-asserted-by":"crossref","unstructured":"Pellei, M., Santini, C., Bagnarelli, L., Caviglia, M., Sgarbossa, P., De Franco, M., Zancato, M., Marzano, C., and Gandin, V. (2023). Novel Silver Complexes Based on Phosphanes and Ester Derivatives of Bis(pyrazol-1-yl)acetate Ligands Targeting TrxR: New Promising Chemotherapeutic Tools Relevant to SCLC Management. Int. J. Mol. Sci., 24.","DOI":"10.3390\/ijms24044091"},{"key":"ref_112","doi-asserted-by":"crossref","first-page":"4919","DOI":"10.1021\/acs.inorgchem.1c03658","article-title":"Cu(I) and Cu(II) Complexes Based on Lonidamine-Conjugated Ligands Designed to Promote Synergistic Antitumor Effects","volume":"61","author":"Pellei","year":"2022","journal-title":"Inorg. Chem."},{"key":"ref_113","doi-asserted-by":"crossref","unstructured":"Pellei, M., Bagnarelli, L., Luciani, L., Del Bello, F., Giorgioni, G., Piergentili, A., Quaglia, W., De Franco, M., Gandin, V., and Marzano, C. (2020). Synthesis and Cytotoxic Activity Evaluation of New Cu(I) Complexes of Bis(pyrazol-1-yl) Acetate Ligands Functionalized with an NMDA Receptor Antagonist. Int. J. Mol. Sci., 21.","DOI":"10.3390\/ijms21072616"},{"key":"ref_114","doi-asserted-by":"crossref","first-page":"11878","DOI":"10.1039\/C8NJ01763H","article-title":"Novel antitumor copper(II) complexes designed to act through synergistic mechanisms of action, due to the presence of an NMDA receptor ligand and copper in the same chemical entity","volume":"42","author":"Morelli","year":"2018","journal-title":"New J. Chem."},{"key":"ref_115","doi-asserted-by":"crossref","unstructured":"Gandin, V., Ceresa, C., Esposito, G., Indraccolo, S., Porchia, M., Tisato, F., Santini, C., Pellei, M., and Marzano, C. (2017). Therapeutic potential of the phosphino Cu(I) complex (HydroCuP) in the treatment of solid tumors. Sci. Rep., 7.","DOI":"10.1038\/s41598-017-13698-1"},{"key":"ref_116","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1016\/j.jinorgbio.2016.07.007","article-title":"Insights into the cytotoxic activity of the phosphane copper(I) complex Cu(thp)(4) PF6","volume":"165","author":"Tisato","year":"2016","journal-title":"J. Inorg. Biochem."},{"key":"ref_117","doi-asserted-by":"crossref","first-page":"1103","DOI":"10.1016\/j.inoche.2008.06.005","article-title":"New homoleptic carbene transfer ligands and related coinage metal complexes","volume":"11","author":"Papini","year":"2008","journal-title":"Inorg. Chem. Commun."},{"key":"ref_118","doi-asserted-by":"crossref","first-page":"1765","DOI":"10.1080\/00397910701315989","article-title":"Practical method for 2-hydroxyphenylketimine synthesis","volume":"37","author":"Elo","year":"2007","journal-title":"Synth. Commun."},{"key":"ref_119","doi-asserted-by":"crossref","first-page":"369","DOI":"10.1080\/00304940109356602","article-title":"An improved solvent-free preparation of 2-imidoylphenols","volume":"33","author":"Cimarelli","year":"2001","journal-title":"Org. Prep. Proced. Int."},{"key":"ref_120","doi-asserted-by":"crossref","first-page":"15711","DOI":"10.1016\/S0040-4020(98)00985-5","article-title":"Alkylation of dianions derived from 2-(1-iminoalkyl) phenols: Synthesis of functionalized 2-acyl phenols","volume":"54","author":"Cimarelli","year":"1998","journal-title":"Tetrahedron"},{"key":"ref_121","first-page":"1097","article-title":"Steric Modification of the Intramolecular Hydrogen Bond in 2-(Methylimino-phenyl-methyl)-phenols","volume":"130","author":"Filarowski","year":"1999","journal-title":"Monatshefte Chem."},{"key":"ref_122","doi-asserted-by":"crossref","first-page":"245","DOI":"10.1016\/j.jcat.2020.06.015","article-title":"Infrared spectra of surface nitrates: Revision of the current opinions based on the case study of ceria","volume":"394","author":"Mihaylov","year":"2021","journal-title":"J. Catal."},{"key":"ref_123","doi-asserted-by":"crossref","unstructured":"Nakamoto, K. (2008). Applications in Coordination Chemistry. Infrared and Raman Spectra of Inorganic and Coordination Compounds: Part B: Applications in Coordination, Organometallic, and Bioinorganic Chemistry, John Wiley & Sons.","DOI":"10.1002\/9780470405888"},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"120857","DOI":"10.1016\/j.ica.2022.120857","article-title":"Synthesis and structural characterization of some 1:1 and 1:2 adducts of silver(I) salts with hindered Pmes3, PPhmes2 and PPh2mes bases (Ph = phenyl, mes=2,4,6-trimethylpheny1))","volume":"535","author":"Effendy","year":"2022","journal-title":"Inorg. Chim. Acta"},{"key":"ref_125","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1016\/j.ccr.2008.03.001","article-title":"Coordination complexes of silver(I) with tertiary phosphine and related ligands","volume":"253","author":"Meijboom","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"ref_126","doi-asserted-by":"crossref","first-page":"1965","DOI":"10.1039\/DT9860001965","article-title":"Lewis Base Adducts of Group 11 Metal Compounds. Part 24. Co-ordination of Triphenylphosphine with Silver Nitrate. A Solid-state Cross-polarization Magic Angle Spinning 31P Nuclear Magnetic Resonance, Crystal Structure, and Infrared Spectroscopic Study of Ag(PPh3)nNO3 (n = 1\u20134)","volume":"9","author":"Barron","year":"1986","journal-title":"J. Chem. Soc.-Dalton Trans."},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"12098","DOI":"10.1039\/D3DT02179C","article-title":"Synthesis and cytotoxicity studies of Cu(I) and Ag(I) complexes based on sterically hindered \u03b2-diketonates with different degrees of fluorination","volume":"52","author":"Pellei","year":"2023","journal-title":"Dalton Trans."},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"8569","DOI":"10.1039\/c1dt10524h","article-title":"Silver(I) and copper(I) complexes supported by fully fluorinated 1,3,5-triazapentadienyl ligands","volume":"40","author":"Dias","year":"2011","journal-title":"Dalton Trans."},{"key":"ref_129","doi-asserted-by":"crossref","unstructured":"Pellei, M., Alidori, S., Papini, G., Gioia Lobbia, G., Gorden, J.D., Dias, H.V.R., and Santini, C. (2007). Silver(I)-organophosphane complexes of electron withdrawing CF3- or NO2-substituted scorpionate ligands. Dalton Trans., 4845\u20134853.","DOI":"10.1039\/b708436f"},{"key":"ref_130","doi-asserted-by":"crossref","first-page":"9708","DOI":"10.1021\/ic701041k","article-title":"Small Scorpionate Ligands:\u2009 Silver(I)-Organophosphane Complexes of 5-CF3-Substituted Scorpionate Ligand Combining a B\u2212H\u00b7\u00b7\u00b7Ag Coordination Motif","volume":"46","author":"Dias","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref_131","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/j.poly.2015.01.035","article-title":"Coordination polymers and molecular structures among complexes of mercury(II) halides with selected 1-benzoylthioureas","volume":"90","author":"Okuniewski","year":"2015","journal-title":"Polyhedron"},{"key":"ref_132","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1039\/B617136B","article-title":"Structural variation in copper(I) complexes with pyridylmethylamide ligands:: Structural analysis with a new four-coordinate geometry index, \u03c44","volume":"9","author":"Yang","year":"2007","journal-title":"Dalton Trans."},{"key":"ref_133","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1107\/S0108768102003890","article-title":"The Cambridge Structural Database: A quarter of a million crystal structures and rising","volume":"B58","author":"Allen","year":"2002","journal-title":"Acta Cryst."},{"key":"ref_134","first-page":"186","article-title":"Crystal structure of N-(diphenylmethylene)diphenylmethanamine, C26H21N","volume":"224","author":"Wang","year":"2009","journal-title":"Z. Krist.-New Cryst. Struct."},{"key":"ref_135","doi-asserted-by":"crossref","first-page":"2118","DOI":"10.1021\/ol500522d","article-title":"Aminative Umpolung Synthesis of Aryl Vicinal Diamines from Aromatic Aldehydes","volume":"16","author":"Liu","year":"2014","journal-title":"Org. Lett."},{"key":"ref_136","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1016\/j.tetasy.2010.03.038","article-title":"Novel ligands based on bromosubstituted hydroxycarbonyl 2.2 paracyclophane derivatives: Synthesis and application in asymmetric catalysis","volume":"21","author":"Vorontsova","year":"2010","journal-title":"Tetrahedron Asymmetry"},{"key":"ref_137","doi-asserted-by":"crossref","first-page":"1400","DOI":"10.1021\/om011086n","article-title":"Solution and solid-state characteristics of imine adducts with tris(pentafluorophenyl)borane","volume":"21","author":"Blackwell","year":"2002","journal-title":"Organometallics"},{"key":"ref_138","doi-asserted-by":"crossref","first-page":"3295","DOI":"10.1002\/1099-0690(200010)2000:19<3295::AID-EJOC3295>3.0.CO;2-0","article-title":"Regioselective Fries Rearrangement and Friedel\u2212Crafts Acylation as Efficient Routes to Novel Enantiomerically Enriched ortho-Acylhydroxy [2.2]paracyclophanes","volume":"2000","author":"Rozenberg","year":"2000","journal-title":"Eur. J. Org. Chem."},{"key":"ref_139","first-page":"1259","article-title":"Crystal structures and circular dichroism of {2,20-[(1S,2S)-1,2-diphenylethane-1,2-diylbis(nitrilo-phenylmethanylylidene)]diphenolato} nickel(II) and its ethanol solvate","volume":"E80","author":"Ito","year":"2024","journal-title":"Acta Cryst."},{"key":"ref_140","doi-asserted-by":"crossref","unstructured":"Hirotsu, M., Kuwamura, N., Kinoshita, I., Kojima, M., Yoshikawa, Y., and Ueno, K. (2009). Steric, geometrical and solvent effects on redox potentials in salen-type copper(II) complexes. Dalton Trans., 7678\u20137683.","DOI":"10.1039\/b906013h"},{"key":"ref_141","doi-asserted-by":"crossref","first-page":"2549","DOI":"10.1246\/bcsj.69.2549","article-title":"Stereochemistry and electrochemistry of cobalt(II) and cobalt(III) complexes containing optically active tetradentate Schiff base ligands","volume":"69","author":"Hirotsu","year":"1996","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_142","doi-asserted-by":"crossref","first-page":"6173","DOI":"10.1021\/ic00128a031","article-title":"Manganese(III) Complexes Containing Optically Active Tetradentate Schiff Base Ligands. Effect of Phenyl Substituents","volume":"34","author":"Hirotsu","year":"1995","journal-title":"Inorg. Chem."},{"key":"ref_143","doi-asserted-by":"crossref","first-page":"2183","DOI":"10.1246\/cl.1994.2183","article-title":"Steric Control of Redox Potentials of Cobalt(II) Schiff Base Complexes with Phenyl Substituents","volume":"23","author":"Hirotsu","year":"1994","journal-title":"Chem. Lett."},{"key":"ref_144","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/j.ica.2019.02.033","article-title":"Silver(I) and copper(I) complexes with a Schiff base derived from 2-aminofluorene with promising antibacterial activity","volume":"489","author":"Laguna","year":"2019","journal-title":"Inorg. Chim. Acta"},{"key":"ref_145","doi-asserted-by":"crossref","first-page":"1117","DOI":"10.1351\/pac199567071117","article-title":"Critical evaluation of the stability constants of metal complexes of amino acids* with polar side chains (TechnicaI report)","volume":"67","author":"Berthon","year":"1995","journal-title":"Pure Appl. Chem."},{"key":"ref_146","doi-asserted-by":"crossref","first-page":"139496","DOI":"10.1016\/j.molstruc.2024.139496","article-title":"Exploration of iron(III) complexes with bidentate N, O-donor Schiff base ligands through synthesis, characterization, DFT, and antibacterial studies","volume":"1319","author":"Kumar","year":"2025","journal-title":"J. Mol. Struct."},{"key":"ref_147","doi-asserted-by":"crossref","first-page":"e7751","DOI":"10.1002\/aoc.7751","article-title":"New Metal Complexes Incorporating Schiff Base Ligand Based on Pyridine Moiety: Synthesis, Spectral Characterization, DFT, Biological Evaluation, and Molecular Docking","volume":"39","author":"Salah","year":"2025","journal-title":"Appl. Organomet. Chem."},{"key":"ref_148","doi-asserted-by":"crossref","first-page":"6379","DOI":"10.1016\/j.arabjc.2020.05.039","article-title":"In vitro biological studies of heteroleptic Ag(I) and Cu(I) unsymmetrical N,N\u2019-diarylformamidine dithiocarbamate phosphine complexes; the effect of the metal center","volume":"13","author":"Oladipo","year":"2020","journal-title":"Arab. J. Chem."},{"key":"ref_149","doi-asserted-by":"crossref","first-page":"117007","DOI":"10.1016\/j.ejmech.2024.117007","article-title":"Gold(I) complexes of the type [AuL{\u03baC-2-C6H4P(S)Ph2}] [L = PTA, PPh3, PPh2(C6H4-3-SO3Na) and PPh2(2-py)]: Synthesis, characterisation, crystal structures, and In Vitro and In Vivo anticancer properties","volume":"281","author":"Reddy","year":"2025","journal-title":"Eur. J. Med. Chem."},{"key":"ref_150","doi-asserted-by":"crossref","unstructured":"Singh, K., Singh, V.K., Mishra, R., Sharma, A., Pandey, A., Srivastava, S.K., and Chaurasia, H. (2024). Design, Synthesis, DFT, docking Studies, and antimicrobial evaluation of novel benzimidazole containing sulphonamide derivatives. Bioorg. Chem., 149.","DOI":"10.1016\/j.bioorg.2024.107473"},{"key":"ref_151","doi-asserted-by":"crossref","unstructured":"Yan, Y., Xia, X.X., Fatima, A., Zhang, L., Yuan, G.J., Lian, F.X., and Wang, Y. (2024). Antibacterial Activity and Mechanisms of Plant Flavonoids against Gram-Negative Bacteria Based on the Antibacterial Statistical Model. Pharmaceuticals, 17.","DOI":"10.20944\/preprints202401.0115.v3"},{"key":"ref_152","doi-asserted-by":"crossref","first-page":"100580","DOI":"10.1016\/j.rechem.2022.100580","article-title":"Synthesis, structure and antibacterial properties of a mononuclear Ag(I) complex, [Ag(OBz)(PTA)2] (OBz =benzoate, PTA =1,3,5-triaza-7-phospadamantane)","volume":"4","author":"Hasan","year":"2022","journal-title":"Results Chem."},{"key":"ref_153","doi-asserted-by":"crossref","first-page":"109206","DOI":"10.1016\/j.inoche.2022.109206","article-title":"Design and synthesis of Schiff base Homobimetallic-Complexes as promising antimicrobial agents","volume":"137","author":"Pervaiz","year":"2022","journal-title":"Inorg. Chem. Commun."},{"key":"ref_154","doi-asserted-by":"crossref","unstructured":"Ejidike, I.P. (2018). Cu(II) Complexes of 4-[(1E)-N-{2-[(Z)-Benzylidene-amino]ethyl}ethanimidoyl]benzene-1,3-diol Schiff Base: Synthesis, Spectroscopic, In-Vitro Antioxidant, Antifungal and Antibacterial Studies. Molecules, 23.","DOI":"10.3390\/molecules23071581"},{"key":"ref_155","doi-asserted-by":"crossref","first-page":"1839","DOI":"10.1007\/s10973-018-7871-x","article-title":"Spectral, thermal and biological characterization of complexes with a Schiff base bearing triazole moiety as potential antimicrobial species","volume":"134","author":"Calu","year":"2018","journal-title":"J. Therm. Anal. Calorim."},{"key":"ref_156","doi-asserted-by":"crossref","first-page":"1066","DOI":"10.1080\/00958972.2017.1285399","article-title":"Synthesis, characterization, and antimicrobial activity of two Schiff base silver(I) complexes derived from 4-carboxybenzaldehyde","volume":"70","author":"Zhang","year":"2017","journal-title":"J. Coord. Chem."},{"key":"ref_157","unstructured":"(2024). CrysAlisPro Versions 1.171.43.141a, Rigaku Oxford Diffraction."},{"key":"ref_158","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","article-title":"OLEX2: A complete structure solution, refinement and analysis program","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Crystallogr."},{"key":"ref_159","first-page":"3","article-title":"SHELXT\u2014Integrated space-group and crystal-structure determination","volume":"A71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst."},{"key":"ref_160","first-page":"3","article-title":"Crystal structure refinement with SHELXL","volume":"C71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst."},{"key":"ref_161","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1107\/S0021889807067908","article-title":"Mercury CSD 2.0\u2014New features for the visualization and investigation of crystal structures","volume":"41","author":"Macrae","year":"2008","journal-title":"J. Appl. Crystallogr."},{"key":"ref_162","doi-asserted-by":"crossref","first-page":"153139","DOI":"10.1016\/j.cej.2024.153139","article-title":"Simultaneous sterilization and biosensing of pathogenic bacteria via copper phthalocyanine-based COF embedded with Cu-N4 single atomic sites and silver nanoparticles","volume":"494","author":"Liu","year":"2024","journal-title":"Chem. Eng. J."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/9\/1893\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T17:20:42Z","timestamp":1760030442000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/9\/1893"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,24]]},"references-count":162,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2025,5]]}},"alternative-id":["molecules30091893"],"URL":"https:\/\/doi.org\/10.3390\/molecules30091893","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,24]]}}}