{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T10:57:16Z","timestamp":1778756236338,"version":"3.51.4"},"reference-count":67,"publisher":"MDPI AG","issue":"9","license":[{"start":{"date-parts":[[2025,5,5]],"date-time":"2025-05-05T00:00:00Z","timestamp":1746403200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea (NRF)","doi-asserted-by":"publisher","award":["2020R1A6A1A06046728"],"award-info":[{"award-number":["2020R1A6A1A06046728"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea (NRF)","doi-asserted-by":"publisher","award":["2021R1A2C2010917"],"award-info":[{"award-number":["2021R1A2C2010917"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea (NRF)","doi-asserted-by":"publisher","award":["2024K2A9A2A08000126"],"award-info":[{"award-number":["2024K2A9A2A08000126"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The formation, surface structure, and thermal annealing effects of self-assembled monolayers (SAMs) via vapor deposition of 4-fluorobenzeneselenol (4-FBSeH) on Au(111) at room temperature were investigated using scanning tunneling microscopy (STM). The most prominent structural feature is that 4-fluorobenzeneselenolate (4-FBSe) SAMs on Au(111) are composed of numerous SAM-covered Au adatom islands, regardless of the deposition time. High-resolution STM observations revealed that the ordered phase of 4-FBSe SAMs was formed after very short deposition times of 30 s and 3 min, whereas the disordered phase was formed after long deposition times of 1 h and 24 h. The ordered phase can be described as a (4 \u00d7 2\u221a3) structure, and the average areal molecular density of the SAMs was calculated to be 29.0 \u00c52\/molecule, suggesting the formation of densely packed monolayers with a standing-up adsorption structure. Interestingly, after thermal annealing at 373 K for 30 min, the (4 \u00d7 2\u221a3) ordered phase of the SAMs was transformed to randomly distributed, short, single-molecular rows ranging from several nanometers to approximately ten nanometers in length, which has not been observed previously in organic thiolate SAMs. The high-resolution STM results of this study can provide very meaningful information for understanding the formation, surface structure, and thermal annealing effects of 4-FBSe SAMs on Au(111).<\/jats:p>","DOI":"10.3390\/molecules30092057","type":"journal-article","created":{"date-parts":[[2025,5,5]],"date-time":"2025-05-05T21:42:09Z","timestamp":1746481329000},"page":"2057","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Formation, Structure, and Thermal Annealing Effects of Ordered Self-Assembled Monolayers of 4-Fluorobenzeneselenol on Au(111)"],"prefix":"10.3390","volume":"30","author":[{"given":"Sicheon","family":"Seong","sequence":"first","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jin Wook","family":"Han","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gayeong","family":"Joo","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hyun Sun","family":"Sung","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hong Kyu","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6115-7971","authenticated-orcid":false,"given":"Jaegeun","family":"Noh","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"},{"name":"Research Institute for Convergence of Basic Science, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,5,5]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1103","DOI":"10.1021\/cr0300789","article-title":"Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology","volume":"105","author":"Love","year":"2005","journal-title":"Chem. 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