{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T11:48:15Z","timestamp":1791287295340,"version":"4.1.0"},"reference-count":105,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2025,5,12]],"date-time":"2025-05-12T00:00:00Z","timestamp":1747008000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"\u201cAndreas Mentzelopoulos foundation\u201d","award":["33720000"],"award-info":[{"award-number":["33720000"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The CO2 (Dry) Reforming of Methane (DRM) is a key process for reducing CO2 and CH4 emissions while producing syngas with an H2\/CO ratio of 1, ideal for Fischer\u2013Tropsch synthesis. This study explores DRM and the Reverse Water Gas Shift (RWGS) reaction under mild conditions using Ru-based catalysts supported on CeO2, YSZ, TiO2, and SiO2, with three reactant ratios: (i) stoichiometric, PCO2 = 1 kPa, PCH4 = 1 kPa, (ii) oxidizing, PCO2 = 2 kPa, PCH4 = 1 kPa, and (iii) reducing, PCO2 = 1 kPa, PCH4 = 4 kPa. The results highlight the importance of redox support for catalyst stability, with mobile lattice oxygen aiding carbon gasification. While Ru\/CeO2 is stable at high temperatures, it rapidly deactivates at low temperatures, emphasizing the need for precise metal particle size control. This work demonstrates the necessity of fine-tuning catalyst properties for more sustainable DRM, offering insights for next-generation CO2 utilization catalysts.<\/jats:p>","DOI":"10.3390\/molecules30102135","type":"journal-article","created":{"date-parts":[[2025,5,12]],"date-time":"2025-05-12T09:13:38Z","timestamp":1747041218000},"page":"2135","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["CO2 Reforming of Methane over Ru Supported Catalysts Under Mild Conditions"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-3322-1560","authenticated-orcid":false,"given":"Alexandros K.","family":"Bikogiannakis","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering, University of Patras, 26504 Patras, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-8126-0168","authenticated-orcid":false,"given":"Andriana","family":"Lymperi","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, University of Patras, 26504 Patras, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paraskevas","family":"Dimitropoulos","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, University of Patras, 26504 Patras, Greece"},{"name":"Institute of Chemical Engineering Sciences, Foundation for Research and Technology, 26504 Patras, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4793-1163","authenticated-orcid":false,"given":"Kyriakos","family":"Bourikas","sequence":"additional","affiliation":[{"name":"School of Science and Technology, Hellenic Open University, 26335 Patras, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6634-6459","authenticated-orcid":false,"given":"Alexandros","family":"Katsaounis","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, University of Patras, 26504 Patras, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6295-844X","authenticated-orcid":false,"given":"Georgios","family":"Kyriakou","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, University of Patras, 26504 Patras, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,5,12]]},"reference":[{"key":"ref_1","unstructured":"(2025, January 21). The Paris Agreement, UNFCCC. Available online: https:\/\/unfccc.int\/process-and-meetings\/the-paris-agreement."},{"key":"ref_2","unstructured":"(2025, January 21). WMO Greenhouse Gas Bulletin, No. 20, WMO. Available online: https:\/\/wmo.int\/publication-series\/wmo-greenhouse-gas-bulletin-no-20."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"102980","DOI":"10.1016\/j.jcou.2024.102980","article-title":"Unraveling the Role of EPOC during the Enhancement of RWGS Reaction in a Pt\/YSZ\/Au Single Chamber Reactor","volume":"90","author":"Chatzilias","year":"2024","journal-title":"J. CO2 Util."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"309","DOI":"10.1016\/bs.aibe.2020.04.006","article-title":"Chapter Seven\u2014Biogas Upgrading","volume":"Volume 5","author":"Li","year":"2020","journal-title":"Advances in Bioenergy"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"110949","DOI":"10.1016\/j.rser.2021.110949","article-title":"Upgrading Biogas into Syngas through Dry Reforming","volume":"143","author":"Jung","year":"2021","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"1521","DOI":"10.1016\/j.ssi.2007.12.049","article-title":"Electricity Production from Wastewater Treatment via a Novel Biogas-SOFC Aided Process","volume":"179","author":"Yentekakis","year":"2008","journal-title":"Solid State Ion."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"3027","DOI":"10.1016\/j.chempr.2021.08.019","article-title":"Development of Direct Conversion of Syngas to Unsaturated Hydrocarbons Based on Fischer-Tropsch Route","volume":"7","author":"Zhai","year":"2021","journal-title":"Chem"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"5606","DOI":"10.1039\/D0CS01003K","article-title":"Recent Advances in the Routes and Catalysts for Ethanol Synthesis from Syngas","volume":"51","author":"Liu","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"ref_9","first-page":"125","article-title":"Chapter Three\u2014Advances in Catalysis for Syngas Conversion to Hydrocarbons","volume":"Volume 60","author":"Song","year":"2017","journal-title":"Advances in Catalysis"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"887","DOI":"10.1007\/s11426-016-0464-1","article-title":"Advances in Direct Production of Value-Added Chemicals via Syngas Conversion","volume":"60","author":"An","year":"2017","journal-title":"Sci. China Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/j.cattod.2018.07.032","article-title":"A Review on Dry Reforming of Methane in Aspect of Catalytic Properties","volume":"311","author":"Jang","year":"2019","journal-title":"Catal. Today"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"33886","DOI":"10.1016\/j.ijhydene.2023.03.114","article-title":"Dry Reforming of Methane over Supported Rh and Ru Catalysts: Effect of the Support (Al2O3, TiO2, ZrO2, YSZ) on the Activity and Reaction Pathway","volume":"48","author":"Androulakis","year":"2023","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"121886","DOI":"10.1016\/j.apcatb.2022.121886","article-title":"Impact of Nanoparticle Exsolution on Dry Reforming of Methane: Improving Catalytic Activity by Reductive Pre-Treatment of Perovskite-Type Catalysts","volume":"318","author":"Schrenk","year":"2022","journal-title":"Appl. Catal. B Environ."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"13890","DOI":"10.1016\/j.ijhydene.2022.12.299","article-title":"Coke-Resistance over Rh\u2013Ni Bimetallic Catalyst for Low Temperature Dry Reforming of Methane","volume":"48","author":"Mao","year":"2023","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"108668","DOI":"10.1039\/C6RA20450C","article-title":"An Overview on Dry Reforming of Methane: Strategies to Reduce Carbonaceous Deactivation of Catalysts","volume":"6","author":"Arora","year":"2016","journal-title":"RSC Adv."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2570","DOI":"10.1016\/j.rser.2017.09.076","article-title":"Catalyst Design for Dry Reforming of Methane: Analysis Review","volume":"82","author":"Aramouni","year":"2018","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"42213","DOI":"10.1016\/j.ijhydene.2021.11.172","article-title":"A Review on Recent Advances in Dry Reforming of Methane over Ni- and Co-Based Nanocatalysts","volume":"47","author":"Sharifianjazi","year":"2022","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"31041","DOI":"10.1016\/j.ijhydene.2020.12.064","article-title":"Dry Reforming of Methane on Ni\/Mesoporous-Al2O3 Catalysts: Effect of Calcination Temperature","volume":"46","author":"Bian","year":"2021","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"120321","DOI":"10.1016\/j.apcatb.2021.120321","article-title":"Dry Reforming of Methane over Ni\/Ce0.8Ti0.2O2-\u03b4: The Effect of Ni Particle Size on the Carbon Pathways Studied by Transient and Isotopic Techniques","volume":"296","author":"Damaskinos","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"314","DOI":"10.1016\/j.joei.2022.10.004","article-title":"Enhancement of Syngas Production from Dry Reforming of Methane over Co\/Al2O3 Catalyst: Insight into the Promotional Effects of Europium and Neodymium","volume":"105","author":"Pham","year":"2022","journal-title":"J. Energy Inst."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"118859","DOI":"10.1016\/j.apcatb.2020.118859","article-title":"Dry Reforming of Methane over the Cobalt Catalyst: Theoretical Insights into the Reaction Kinetics and Mechanism for Catalyst Deactivation","volume":"270","author":"Chen","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"327","DOI":"10.1016\/S1003-9953(07)60014-0","article-title":"Syngas Production by Methane Reforming with Carbon Dioxide on Noble Metal Catalysts","volume":"15","author":"Rezaei","year":"2006","journal-title":"J. Nat. Gas Chem."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1016\/S0926-860X(00)00525-1","article-title":"Mechanistic Aspects of the Dry Reforming of Methane over Ruthenium Catalysts","volume":"202","author":"Anderson","year":"2000","journal-title":"Appl. Catal. Gen."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"102221","DOI":"10.1016\/j.jcou.2022.102221","article-title":"Theoretical Insight into the Strong Size-Dependence of Dry Reforming of Methane over Ru\/CeO2","volume":"65","author":"Qu","year":"2022","journal-title":"J. CO2 Util."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1007\/s11244-013-0167-2","article-title":"Catalytic Dry Reforming of Methane on Ruthenium-Doped Ceria and Ruthenium Supported on Ceria","volume":"57","author":"Derk","year":"2014","journal-title":"Top. Catal."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"101893","DOI":"10.1016\/j.jcou.2022.101893","article-title":"CO2 Conversion via Dry Reforming of Methane on a Core-Shell Ru@SiO2 Catalyst","volume":"57","author":"Yang","year":"2022","journal-title":"J. CO2 Util."},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Nikolaraki, E., Goula, G., Panagiotopoulou, P., Taylor, M.J., Kousi, K., Kyriakou, G., Kondarides, D.I., Lambert, R.M., and Yentekakis, I.V. (2021). Support Induced Effects on the Ir Nanoparticles Activity, Selectivity and Stability Performance under CO2 Reforming of Methane. Nanomaterials, 11.","DOI":"10.3390\/nano11112880"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"123503","DOI":"10.1016\/j.apcatb.2023.123503","article-title":"Operando Induced Strong Metal-Support Interaction of Rh\/CeO2 Catalyst in Dry Reforming of Methane","volume":"343","author":"Gangarajula","year":"2024","journal-title":"Appl. Catal. B Environ."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"121809","DOI":"10.1016\/j.apcatb.2022.121809","article-title":"Synergistic Pt-CeO2 Interface Boosting Low Temperature Dry Reforming of Methane","volume":"318","author":"Shen","year":"2022","journal-title":"Appl. Catal. B Environ."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"e202408668","DOI":"10.1002\/anie.202408668","article-title":"Surface Carbon Formation and Its Impact on Methane Dry Reforming Kinetics on Rhodium-Based Catalysts by Operando Raman Spectroscopy","volume":"63","author":"Colombo","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"4012","DOI":"10.1016\/j.ces.2007.04.044","article-title":"Kinetics, Experimental and Reactor Modeling Studies of the Carbon Dioxide Reforming of Methane (CDRM) over a New Ni\/CeO2-ZrO2 Catalyst in a Packed Bed Tubular Reactor","volume":"62","author":"Akpan","year":"2007","journal-title":"Chem. Eng. Sci."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2130","DOI":"10.1002\/cctc.201902142","article-title":"Catalytic Dry Reforming of Methane: Insights from Model Systems","volume":"12","author":"Wittich","year":"2020","journal-title":"ChemCatChem"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"589","DOI":"10.1016\/0920-5861(94)80183-5","article-title":"Carbon Dioxide Reforming of Methane to Synthesis Gas over Supported Ni Catalysts","volume":"21","author":"Zhang","year":"1994","journal-title":"Catal. Today"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"260","DOI":"10.1016\/j.cattod.2009.08.022","article-title":"DFT Studies of Dry Reforming of Methane on Ni Catalyst","volume":"148","author":"Zhu","year":"2009","journal-title":"Catal. Today"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"370","DOI":"10.1016\/j.jcat.2004.02.032","article-title":"Isotopic and Kinetic Assessment of the Mechanism of Reactions of CH4 with CO2 or H2O to Form Synthesis Gas and Carbon on Nickel Catalysts","volume":"224","author":"Wei","year":"2004","journal-title":"J. Catal."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"4094","DOI":"10.1021\/jp036985z","article-title":"Mechanism and Site Requirements for Activation and Chemical Conversion of Methane on Supported Pt Clusters and Turnover Rate Comparisons among Noble Metals","volume":"108","author":"Wei","year":"2004","journal-title":"J. Phys. Chem. B"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1023\/A:1024167919727","article-title":"Catalytic Activity of a Nickel on Alumina Catalyst in the CO2 Reforming of Methane","volume":"79","author":"Becerra","year":"2003","journal-title":"React. Kinet. Catal. Lett."},{"key":"ref_38","doi-asserted-by":"crossref","unstructured":"Guczi, L., and Erd\u00f4helyi, A. (2012). Utilization of Biogas as a Renewable Carbon Source: Dry Reforming of Methane. Catalysis for Alternative Energy Generation, Springer.","DOI":"10.1007\/978-1-4614-0344-9"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"415401","DOI":"10.1088\/0957-4484\/26\/41\/415401","article-title":"Amorphous Ruthenium Nanoparticles for Enhanced Electrochemical Water Splitting","volume":"26","author":"Tee","year":"2015","journal-title":"Nanotechnology"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1381","DOI":"10.1007\/s12034-016-1279-7","article-title":"Rose Bengal-Sensitized Nanocrystalline Ceria Photoanode for Dye-Sensitized Solar Cell Application","volume":"39","author":"Sayyed","year":"2016","journal-title":"Bull. Mater. Sci."},{"key":"ref_41","doi-asserted-by":"crossref","unstructured":"Tang, M., Xia, Y., Yang, D., Liu, J., Zhu, X., and Tang, R. (2021). Effects of Hydrothermal Time on Structure and Photocatalytic Property of Titanium Dioxide for Degradation of Rhodamine B and Tetracycline Hydrochloride. Materials, 14.","DOI":"10.3390\/ma14195674"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"012011","DOI":"10.1088\/1742-6596\/2048\/1\/012011","article-title":"R&D on Surrogate Kernel Fabrication in Support of Reaktor Daya Eksperimental (RDE) Project","volume":"2048","author":"Sarjono","year":"2021","journal-title":"J. Phys. Conf. Ser."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"812","DOI":"10.1590\/1980-5373-MR-2016-0196","article-title":"Synthesis and Characterization of Yttrium Stabilized Zirconia Nanoparticles","volume":"19","author":"Maridurai","year":"2016","journal-title":"Mater. Res."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"100534","DOI":"10.1016\/j.apsadv.2023.100534","article-title":"Avoiding Common Errors in X-Ray Photoelectron Spectroscopy Data Collection and Analysis, and Properly Reporting Instrument Parameters","volume":"19","author":"Pinder","year":"2024","journal-title":"Appl. Surf. Sci. Adv."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"1072","DOI":"10.1002\/sia.5852","article-title":"Resolving Ruthenium: XPS Studies of Common Ruthenium Materials","volume":"47","author":"Morgan","year":"2015","journal-title":"Surf. Interface Anal."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1016\/0021-9517(82)90149-X","article-title":"XPS Investigation of Strong Metal-Support Interactions on Group IIIa\u2013Va Oxides","volume":"77","author":"Sexton","year":"1982","journal-title":"J. Catal."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"5973","DOI":"10.1039\/D0CY00897D","article-title":"The Effect of Strong Metal\u2013Support Interaction (SMSI) on Pt\u2013Ti\/SiO2 and Pt\u2013Nb\/SiO2 Catalysts for Propane Dehydrogenation","volume":"10","author":"Chen","year":"2020","journal-title":"Catal. Sci. Technol."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"4491","DOI":"10.1021\/jp070485e","article-title":"Electron Impact-Assisted Carbon Film Growth on Ru(0001):\u2009 Implications for Next-Generation EUV Lithography","volume":"111","author":"Kyriakou","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"1048","DOI":"10.1080\/1536383X.2020.1794851","article-title":"A Review on C1s XPS-Spectra for Some Kinds of Carbon Materials","volume":"28","author":"Chen","year":"2020","journal-title":"Fuller. Nanotub. Carbon. Nanostructures"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"38924","DOI":"10.1039\/D4RA07600A","article-title":"Biochar Made from Luffa Cylindrica and Applied as a Bifunctional Electrocatalyst in Zn\u2013Air Batteries","volume":"14","author":"Tsoukala","year":"2024","journal-title":"RSC Adv."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"e35634","DOI":"10.1016\/j.heliyon.2024.e35634","article-title":"Visible-Light-Activated Antibacterial and Antipollutant Properties of Biocompatible Cu-Doped and Ag-Decorated TiO2 Nanoparticles","volume":"10","author":"Tzevelekidis","year":"2024","journal-title":"Heliyon"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"79898","DOI":"10.1039\/C5RA12551K","article-title":"Influence of the Surface Layer of Hydrated Silicon on the Stabilization of Co2+ Cations in Zr\u2013Si Fiberglass Materials According to XPS, UV-Vis DRS, and Differential Dissolution Phase Analysis","volume":"5","author":"Larina","year":"2015","journal-title":"RSC Adv."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"845","DOI":"10.1002\/sia.7254","article-title":"Photoelectron Spectroscopy of Ceria: Reduction, Quantification and the Myth of the Vacancy Peak in XPS Analysis","volume":"55","author":"Morgan","year":"2023","journal-title":"Surf. Interface Anal."},{"key":"ref_54","doi-asserted-by":"crossref","unstructured":"Bumajdad, A., Nazeer, A.A., Al Sagheer, F., Nahar, S., and Zaki, M.I. (2018). Controlled Synthesis of ZrO2 Nanoparticles with Tailored Size, Morphology and Crystal Phases via Organic\/Inorganic Hybrid Films. Sci. Rep., 8.","DOI":"10.1038\/s41598-018-22088-0"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2887","DOI":"10.1515\/nanoph-2019-0563","article-title":"Yttrium Oxide as a Q-Switcher for the near-Infrared Erbium-Doped Fiber Laser","volume":"9","author":"Liu","year":"2020","journal-title":"Nanophotonics"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"9240","DOI":"10.1039\/C4TC01405G","article-title":"Atomic Layer Deposition of Y2O3 Films Using Heteroleptic Liquid (iPrCp)2Y(iPr-Amd) Precursor","volume":"2","author":"Park","year":"2014","journal-title":"J. Mater. Chem. C"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"666","DOI":"10.1016\/j.jcis.2022.01.112","article-title":"The Interplay between Acid-Base Properties and Fermi Level Pinning of a Nano Dispersed Tungsten Oxide\u2014Titania Catalytic System","volume":"614","author":"Tsatsos","year":"2022","journal-title":"J. Colloid. Interface Sci."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1002\/sia.2686","article-title":"Ce 3d XPS Investigation of Cerium Oxides and Mixed Cerium Oxide (CeTiO)","volume":"40","author":"Charvin","year":"2008","journal-title":"Surf. Interface Anal."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1002\/sia.740180110","article-title":"An XPS Analysis of Different SiO2 Modifications Employing a C 1s as Well as an Au 4f7\/2 Static Charge Reference","volume":"18","author":"Gross","year":"1992","journal-title":"Surf. Interface Anal."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"331","DOI":"10.1016\/0926-860X(95)00211-1","article-title":"Chlorine as a Poison of the Fused Iron Catalyst for Ammonia Synthesis","volume":"134","author":"Arabczyk","year":"1996","journal-title":"Appl. Catal. Gen."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"4786","DOI":"10.1007\/s12274-022-5260-z","article-title":"Switching of CO2 Hydrogenation Selectivity via Chlorine Poisoning over Ru\/TiO2 Catalyst","volume":"16","author":"Zhang","year":"2023","journal-title":"Nano Res."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"373","DOI":"10.1016\/j.apcatb.2011.03.003","article-title":"Impact of Induced Chlorine-Poisoning on the Catalytic Behaviour of Ce0.5Zr0.5O2 and Ce0.15Zr0.85O2 in the Gas-Phase Oxidation of Chlorinated VOCs","volume":"104","year":"2011","journal-title":"Appl. Catal. B Environ."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"119292","DOI":"10.1016\/j.apcata.2023.119292","article-title":"Influence of Residual Chlorine on Ru\/TiO2 Active Sites during CO2 Methanation","volume":"663","author":"Crawford","year":"2023","journal-title":"Appl. Catal. Gen."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"120652","DOI":"10.1016\/j.apcatb.2021.120652","article-title":"PdCu Single Atom Alloys Supported on Alumina for the Selective Hydrogenation of Furfural","volume":"299","author":"Islam","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1016\/j.apcatb.2015.07.006","article-title":"Highly Selective Hydrogenation of Furfural over Supported Pt Nanoparticles under Mild Conditions","volume":"180","author":"Taylor","year":"2016","journal-title":"Appl. Catal. B Environ."},{"key":"ref_66","doi-asserted-by":"crossref","unstructured":"Lymperi, A., Chatzilias, C., Xydas, F., Martino, E., Kyriakou, G., and Katsaounis, A. (2023). Electrochemical Promotion of CO2 Hydrogenation Using a Pt\/YSZ Fuel Cell Type Reactor. Nanomaterials, 13.","DOI":"10.20944\/preprints202304.0685.v2"},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"148360","DOI":"10.1016\/j.cej.2023.148360","article-title":"Insights into the Contribution of Oxygen Vacancies on CO2 Activation for Dry Reforming of Methane over Ceria-Based Solid Solutions","volume":"481","author":"Wang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"3601","DOI":"10.1039\/c3nr00476g","article-title":"Defective TiO2 with Oxygen Vacancies: Synthesis, Properties and Photocatalytic Applications","volume":"5","author":"Pan","year":"2013","journal-title":"Nanoscale"},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"598","DOI":"10.1016\/j.apsusc.2017.09.199","article-title":"Support Structure Effect on CO Oxidation: A Comparative Study on SiO2 Nanospheres and CeO2 Nanorods Supported CuOx Catalysts","volume":"428","author":"Hossain","year":"2018","journal-title":"Appl. Surf. Sci."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"06GC03","DOI":"10.7567\/JJAP.54.06GC03","article-title":"Cause of the Appearance of Oxygen Vacancies in Yttria-Stabilized Zirconia and Its Relation to 2.8 eV Photoluminescence","volume":"54","author":"Kaneko","year":"2015","journal-title":"Jpn. J. Appl. Phys."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"4545","DOI":"10.1021\/jp0273934","article-title":"Explaining the Enhanced Photocatalytic Activity of Degussa P25 Mixed-Phase TiO2 Using EPR","volume":"107","author":"Hurum","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"3019","DOI":"10.1007\/s11164-019-03776-6","article-title":"Modulating of Facets-Dependent Oxygen Vacancies on Ceria and Its Catalytic Oxidation Performance","volume":"45","author":"Ren","year":"2019","journal-title":"Res. Chem. Intermed."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1007\/BF00816306","article-title":"Role of Support in Reforming of CH4 with CO2 over Rh Catalysts","volume":"25","author":"Nakamura","year":"1994","journal-title":"Catal. Lett."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"490","DOI":"10.1016\/j.apcatb.2018.10.048","article-title":"Effect of Support Oxygen Storage Capacity on the Catalytic Performance of Rh Nanoparticles for CO2 Reforming of Methane","volume":"243","author":"Yentekakis","year":"2019","journal-title":"Appl. Catal. B Environ."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"710","DOI":"10.1016\/j.rser.2015.02.026","article-title":"Dry Reforming of Methane: Influence of Process Parameters\u2014A Review","volume":"45","author":"Usman","year":"2015","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1006\/jcat.1999.2385","article-title":"CO2 Reforming of CH4 over Supported Ru Catalysts","volume":"183","author":"Bradford","year":"1999","journal-title":"J. Catal."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"5265","DOI":"10.1021\/ie061645w","article-title":"Kinetic Analysis of Rate Data for Dry Reforming of Methane","volume":"46","author":"Quiroga","year":"2007","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"150369","DOI":"10.1016\/j.cej.2024.150369","article-title":"Transforming CO2 to Valuable Feedstocks: Emerging Catalytic and Technological Advances for the Reverse Water Gas Shift Reaction","volume":"487","author":"Arriola","year":"2024","journal-title":"Chem. Eng. J."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1007\/BF00806097","article-title":"On the Activation Energies of the Forward and Reverse Water-Gas Shift Reaction","volume":"32","author":"Spencer","year":"1995","journal-title":"Catal. Lett."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1016\/j.jcat.2012.09.011","article-title":"Particle Size Effect in the Low Temperature Reforming of Methane by Carbon Dioxide on Silica-Supported Ni Nanoparticles","volume":"297","author":"Baudouin","year":"2013","journal-title":"J. Catal."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"12147","DOI":"10.1016\/j.ijhydene.2010.08.091","article-title":"Preparation and Characterization of Ni Based Catalysts for the Catalytic Partial Oxidation of Methane: Effect of Support Basicity on H2\/CO Ratio and Carbon Deposition","volume":"35","year":"2010","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1016\/j.apcata.2011.04.035","article-title":"Methane Conversion Reactions on Ni Catalysts Promoted with Rh: Influence of Support","volume":"400","author":"Assaf","year":"2011","journal-title":"Appl. Catal. Gen."},{"key":"ref_83","doi-asserted-by":"crossref","unstructured":"Manan, W.N., Isahak, W.N.R.W., and Yaakob, Z. (2022). CeO2-Based Heterogeneous Catalysts in Dry Reforming Methane and Steam Reforming Methane: A Short Review. Catalysts, 12.","DOI":"10.3390\/catal12050452"},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"382","DOI":"10.1016\/j.jcat.2004.06.011","article-title":"Study of the Origin of the Deactivation of a Pt\/CeO2 Catalyst during Reverse Water Gas Shift (RWGS) Reaction","volume":"226","author":"Goguet","year":"2004","journal-title":"J. Catal."},{"key":"ref_85","doi-asserted-by":"crossref","unstructured":"He, L., Ren, Y., Fu, Y., Yue, B., Tsang, S.C.E., and He, H. (2019). Morphology-Dependent Catalytic Activity of Ru\/CeO2 in Dry Reforming of Methane. Molecules, 24.","DOI":"10.3390\/molecules24030526"},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"128366","DOI":"10.1016\/j.fuel.2023.128366","article-title":"Microwave-Assisted Hydrothermal Synthesis of Ru\/CeO2 Catalyst for Efficient and Stable Low-Temperature Dry Reforming of Methane","volume":"346","author":"Zhou","year":"2023","journal-title":"Fuel"},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"3349","DOI":"10.1021\/acscatal.8b05162","article-title":"Highly Active Ceria-Supported Ru Catalyst for the Dry Reforming of Methane: In Situ Identification of Ru\u03b4+\u2013Ce3+ Interactions for Enhanced Conversion","volume":"9","author":"Liu","year":"2019","journal-title":"ACS Catal."},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"548","DOI":"10.1021\/acsearthspacechem.7b00144","article-title":"Mechanism of Chemical Reactions between SiO2 and CO2 under Mantle Conditions","volume":"2","author":"Yong","year":"2018","journal-title":"ACS Earth Space Chem."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1016\/0021-9517(78)90024-6","article-title":"Infrared Study of CO2 Adsorption on SiO2","volume":"54","author":"Ueno","year":"1978","journal-title":"J. Catal."},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"334","DOI":"10.1063\/1.4895218","article-title":"Adsorption of CO2 on Silica Dioxide Catalyst Impregnated with Various Alkylamine","volume":"1614","author":"Tahari","year":"2014","journal-title":"AIP Conf. Proc."},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1016\/S0926-860X(98)00048-9","article-title":"Comparative Study at Low and Medium Reaction Temperatures of Syngas Production by Methane Reforming with Carbon Dioxide over Silica and Alumina Supported Catalysts","volume":"170","year":"1998","journal-title":"Appl. Catal. Gen."},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"625","DOI":"10.1016\/j.apcatb.2016.10.069","article-title":"Uncoupling the Size and Support Effects of Ni Catalysts for Dry Reforming of Methane","volume":"203","author":"Han","year":"2017","journal-title":"Appl. Catal. B Environ."},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"128973","DOI":"10.1016\/j.colsurfa.2022.128973","article-title":"Influence of Particle Size and Metal-Support Interaction on the Catalytic Performance of Ni-Al2O3 Catalysts for the Dry and Oxidative-Dry Reforming of Methane","volume":"646","author":"Chaudhary","year":"2022","journal-title":"Colloids Surf. Physicochem. Eng. Asp."},{"key":"ref_94","doi-asserted-by":"crossref","first-page":"118252","DOI":"10.1016\/j.enconman.2024.118252","article-title":"Recent Developments and Current Trends on Catalytic Dry Reforming of Methane: Hydrogen Production, Thermodynamics Analysis, Techno Feasibility, and Machine Learning","volume":"304","author":"Awad","year":"2024","journal-title":"Energy Convers. Manag."},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"25706","DOI":"10.1016\/j.ijhydene.2019.08.081","article-title":"Production of Hydrogen by Methane Dry Reforming over Ruthenium-Nickel Based Catalysts Deposited on Al2O3, MgAl2O4, and YSZ","volume":"44","author":"Andraos","year":"2019","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"6337","DOI":"10.1021\/acs.jpcc.3c00377","article-title":"Copper Growth on a Stepped Nickel Surface: Electronic and Geometric Effects on CO Reactivity","volume":"127","author":"Tsatsos","year":"2023","journal-title":"J. Phys. Chem. C"},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"161672","DOI":"10.1016\/j.apsusc.2024.161672","article-title":"Phthalocyanine Interfaces with MoS2(0001): The Effect of the Metal Centre on the Charge Transfer","volume":"682","author":"Drivas","year":"2025","journal-title":"Appl. Surf. Sci."},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"1612","DOI":"10.1021\/j100475a011","article-title":"Quantitative Analysis of XPS Intensities for Supported Catalysts","volume":"83","author":"Kerkhof","year":"1979","journal-title":"J. Phys. Chem."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"4348","DOI":"10.1039\/c0cc00581a","article-title":"High Activity and Selectivity of Ag\/SiO2 Catalyst for Hydrogenation of Dimethyl Oxalate","volume":"46","author":"Yin","year":"2010","journal-title":"Chem. Commun."},{"key":"ref_100","first-page":"106","article-title":"Furfuryl Alcohol from Furfural Hydrogenation over Copper Supported on SBA-15 Silica Catalysts","volume":"383\u2013384","year":"2014","journal-title":"J. Mol. Catal. Chem."},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"7844","DOI":"10.1021\/acscatal.6b02207","article-title":"Enhanced Chemoselective Hydrogenation through Tuning the Interaction between Pt Nanoparticles and Carbon Supports: Insights from Identical Location Transmission Electron Microscopy and X-Ray Photoelectron Spectroscopy","volume":"6","author":"Shi","year":"2016","journal-title":"ACS Catal."},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1016\/0368-2048(76)80015-1","article-title":"Hartree-Slater Subshell Photoionization Cross-Sections at 1254 and 1487 eV","volume":"8","author":"Scofield","year":"1976","journal-title":"J. Electron. Spectrosc. Relat. Phenom."},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"871","DOI":"10.1002\/sia.5789","article-title":"Calculations of Electron Inelastic Mean Free Paths. X. Data for 41 Elemental Solids over the 50 eV to 200 keV Range with the Relativistic Full Penn Algorithm","volume":"47","author":"Shinotsuka","year":"2015","journal-title":"Surf. Interface Anal."},{"key":"ref_104","doi-asserted-by":"crossref","first-page":"267","DOI":"10.1016\/j.cattod.2010.12.015","article-title":"The Influence of the Support Modification over Ni-Based Catalysts for Dry Reforming of Methane Reaction","volume":"176","author":"Pietraszek","year":"2011","journal-title":"Catal. Today"},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1016\/j.apcata.2015.01.024","article-title":"Dry Reforming of Methane on Ceria Prepared by Modified Precipitation Route","volume":"494","author":"Rotaru","year":"2015","journal-title":"Appl. Catal. Gen."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/10\/2135\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T17:31:19Z","timestamp":1760031079000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/10\/2135"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,12]]},"references-count":105,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2025,5]]}},"alternative-id":["molecules30102135"],"URL":"https:\/\/doi.org\/10.3390\/molecules30102135","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,12]]}}}