{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T15:11:19Z","timestamp":1791385879226,"version":"4.3.3"},"reference-count":187,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2025,5,20]],"date-time":"2025-05-20T00:00:00Z","timestamp":1747699200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Scientific Research Projects of Hebei Education Department","award":["QN2019050"],"award-info":[{"award-number":["QN2019050"]}]},{"name":"Scientific Research Projects of Hebei Education Department","award":["B2020202004"],"award-info":[{"award-number":["B2020202004"]}]},{"name":"Natural Science Foundation of Hebei Province","award":["QN2019050"],"award-info":[{"award-number":["QN2019050"]}]},{"name":"Natural Science Foundation of Hebei Province","award":["B2020202004"],"award-info":[{"award-number":["B2020202004"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Single-ring aromatic compounds including BTX (benzene, toluene, xylene) serve as essential building blocks for high-performance fuels and specialty chemicals, with extensive applications spanning polymer synthesis, pharmaceutical manufacturing, and aviation fuel formulation. Current industrial production predominantly relies on non-renewable petrochemical feedstocks, posing the dual challenges of resource depletion and environmental sustainability. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic substrates emerges as a technologically viable pathway for sustainable aromatic hydrocarbon synthesis, offering critical opportunities for lignin valorization and biorefinery advancement. This article reviews the relevant research on the conversion of lignin-derived phenolic compounds\u2019 HDO to benzene and aromatic hydrocarbons, systematically categorizing and summarizing the different types of catalysts and their reaction mechanisms. Furthermore, we propose a strategic framework addressing current technical bottlenecks, highlighting the necessity for the synergistic development of robust heterogeneous catalysts with tailored active sites and energy-efficient process engineering to achieve scalable biomass conversion systems.<\/jats:p>","DOI":"10.3390\/molecules30102225","type":"journal-article","created":{"date-parts":[[2025,5,20]],"date-time":"2025-05-20T09:33:47Z","timestamp":1747733627000},"page":"2225","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["A Comprehensive Review of Catalytic Hydrodeoxygenation of Lignin-Derived Phenolics to Aromatics"],"prefix":"10.3390","volume":"30","author":[{"given":"Sitong","family":"Dong","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gang","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,5,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Ye, K., Liu, Y., Wu, S., and Zhuang, J. 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