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The results confirmed that the catalyst exhibited a high electron transfer capacity, and the synergistic effect between the bimetals enhanced the reversible redox cycle of Co3+\/Co2+. Under optimal conditions, complete removal of RhB was achieved in just 6 min using the Co3O4\/ZnO composite, which demonstrated excellent stability after five cycles. Furthermore, the catalyst exhibited a high degradation efficiency in real water samples with a total organic carbon (TOC) removal rate of approximately 65% after 60 min. The electrochemical measurements, identification of active species, and X-ray photoelectron spectroscopy (XPS) analysis revealed that non-radicals (1O2 and direct charge transfer) played a major role in the degradation of RhB. Finally, the potential mechanisms and degradation pathways for RhB degradation using this catalyst were systematically investigated. This study opens new avenues for the development of efficient and stable PMS catalysts, and provides insights into the preparation of other emerging metal oxides.<\/jats:p>","DOI":"10.3390\/molecules30102237","type":"journal-article","created":{"date-parts":[[2025,5,21]],"date-time":"2025-05-21T06:31:27Z","timestamp":1747809087000},"page":"2237","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Efficiently Degrading RhB Using Bimetallic Co3O4\/ZnO Oxides: Ultra-Fast and Persistent Activation of Permonosulfate"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9054-6864","authenticated-orcid":false,"given":"Bai","family":"Sun","sequence":"first","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"},{"name":"Environmental Materials and Pollution Control Laboratory, Hefei Institute of Physical Science, Chinese Academy of Sciences, Hefei 230031, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Liu","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengshou","family":"Zhao","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengnan","family":"He","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yun","family":"Wang","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangxiang","family":"Wang","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Huang","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2785-0975","authenticated-orcid":false,"given":"Mingjian","family":"Yi","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuguang","family":"Zhu","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Building Energy Efficiency Control and Evaluation, Ministry of Education, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,5,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"129239","DOI":"10.1016\/j.colsurfa.2022.129239","article-title":"Facile hydrothermal synthesis of co-glycerate as an efficient peroxymonosulfate activator for rhodamine B degradation","volume":"648","author":"Yang","year":"2022","journal-title":"Colloid Surf. 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