{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T12:28:21Z","timestamp":1786364901232,"version":"build-2736575974"},"reference-count":68,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2025,6,19]],"date-time":"2025-06-19T00:00:00Z","timestamp":1750291200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>This study evaluates the corrosion-inhibiting effects of the methanolic (P1) and the hydroalcoholic (P2) extracts of the Rhus typhina L. leaves on carbon steel (OL37) in 1 M HCl. Extracts were prepared with microwave-assisted extraction and characterized using HPLC and LC-MS. Electrochemical methods (OCP, EIS, PDP) and surface analyses (SEM, EDX) assessed the performance of both extracts. The results showed that the P1 and P2 extracts significantly reduced corrosion rates by forming protective layers on the metal surface, with inhibition efficiencies exceeding 90%, at 1000 ppm concentration, for P1 (93%), for P2 at 800 ppm (91%) and 1000 ppm (94%). The P2 extract demonstrated superior long-term performance, maintaining protection after 96 h of immersion. The extracts function as mixed-type inhibitors, affecting both anodic and cathodic reactions, with physicochemical adsorption demonstrated by the Langmuir isotherm. Overall, the Rhus typhina leaf extracts, particularly the P2 extract, offer a promising, eco-friendly approach to corrosion prevention in acidic environments.<\/jats:p>","DOI":"10.3390\/molecules30122660","type":"journal-article","created":{"date-parts":[[2025,6,19]],"date-time":"2025-06-19T09:57:48Z","timestamp":1750327068000},"page":"2660","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Electrochemical Assessment of Rhus typhina L. Leaf Extract as a Novel Green Corrosion Inhibitor for OL37 in 1 M HCl Medium"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-0690-525X","authenticated-orcid":false,"given":"Denisa-Ioana","family":"R\u0103u\u021b\u0103 (Gheorghe)","sequence":"first","affiliation":[{"name":"Biotechnical Systems Engineering Doctoral School, National University of Science and Technology Politehnica Bucharest, 060042 Bucharest, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6892-0052","authenticated-orcid":false,"given":"Florina","family":"Br\u00e2nzoi","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry-Ilie Murgulescu, 202 Splaiul Independentei, 060021 Bucharest, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5029-3134","authenticated-orcid":false,"given":"Roxana-Doina","family":"Tru\u015fc\u0103","sequence":"additional","affiliation":[{"name":"Faculty of Applied Chemistry and Material Science, National University of Science and Technology Politehnica Bucharest, Splaiul Independentei 313, 060042 Bucharest, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sorin-Marius","family":"Avramescu","sequence":"additional","affiliation":[{"name":"Faculty of Animal Productions Engineering and Management, University of Agronomic, Sciences and Veterinary Medicine of Bucharest, 011464 Bucharest, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8672-9078","authenticated-orcid":false,"given":"Ecaterina","family":"Matei","sequence":"additional","affiliation":[{"name":"Faculty of Materials Sciences and Engineering, National University of Science and Technology Politehnica Bucharest, 060042 Bucharest, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,6,19]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"5","DOI":"10.1038\/s41529-021-00201-5","article-title":"A review of plant extracts as green corrosion inhibitors for CO2 corrosion of carbon steel","volume":"6","author":"Fazal","year":"2022","journal-title":"npj Mater. 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