{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T01:45:11Z","timestamp":1760060711878,"version":"build-2065373602"},"reference-count":62,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2025,9,17]],"date-time":"2025-09-17T00:00:00Z","timestamp":1758067200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Jilin Province Science and Technology Development Plan Project","award":["20230204040YY","21875085"],"award-info":[{"award-number":["20230204040YY","21875085"]}]},{"name":"NSFC","award":["20230204040YY","21875085"],"award-info":[{"award-number":["20230204040YY","21875085"]}]},{"name":"Innovation &amp; Opening Program of the State Key Laboratory of Supramolecular Structure and Materials, Jilin University","award":["20230204040YY","21875085"],"award-info":[{"award-number":["20230204040YY","21875085"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>We have developed a highly sensitive colorimetric probe based on starch\u2013iodine (I2) crystallization for the precise discrimination of ethanol\u2013water clusters (E-Wc) within binary ethanol\u2013water solutions (E-Ws). This probe enables the identification of specific E-Wc species and their corresponding transition points. Notably, two distinct transition points were identified at ethanol volume fractions of 40\u201345% and 75\u201377%. The former corresponds to the structural transition from (H2O)m(EtOH) to (H2O)m(EtOH)n, characterized by a significant loss of blue coloration, while the latter signifies the transition from (H2O)m(EtOH)n to (H2O)(EtOH)n, as evidenced by alterations in the absorption intensity of the starch\u2013I2 complex. Mechanistic studies demonstrate that the observed starch\u2013I2 crystallization is governed by supramolecular E-Wc rather than individual ethanol or water molecules in the binary solution. By leveraging starch\u2013I2 crystallization as a colorimetric bridge, we establish a direct correlation between E-Wc transitions and the iodine chromogenic effect. This approach enables the visual detection of transitions in colorless supramolecular assemblies, offering new insights into supramolecular science. Furthermore, as a simple, rapid, and visually interpretable detection method, this colorimetric probe holds promising applications in fields such as the food industry and supramolecular science.<\/jats:p>","DOI":"10.3390\/molecules30183785","type":"journal-article","created":{"date-parts":[[2025,9,17]],"date-time":"2025-09-17T15:12:44Z","timestamp":1758121964000},"page":"3785","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Colorimetric Revealing of Ethanol\u2013Water Cluster (E-Wc) Transitions in Binary Solution Based on Starch\u2013I2 Crystallization"],"prefix":"10.3390","volume":"30","author":[{"given":"Hui-Shuang","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, No. 2699 Qianjin Street, Changchun 130012, China"},{"name":"Institute of Theoretical Chemistry, College of Chemistry, Jilin University, No. 2 Liutiao Road, Changchun 130023, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hao-Jie","family":"Bai","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, No. 2699 Qianjin Street, Changchun 130012, China"},{"name":"Institute of Theoretical Chemistry, College of Chemistry, Jilin University, No. 2 Liutiao Road, Changchun 130023, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hong-Wei","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, No. 2699 Qianjin Street, Changchun 130012, China"},{"name":"Institute of Theoretical Chemistry, College of Chemistry, Jilin University, No. 2 Liutiao Road, Changchun 130023, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4883-5982","authenticated-orcid":false,"given":"Yu-Qing","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, No. 2699 Qianjin Street, Changchun 130012, China"},{"name":"Institute of Theoretical Chemistry, College of Chemistry, Jilin University, No. 2 Liutiao Road, Changchun 130023, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,9,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1016\/j.molliq.2010.05.001","article-title":"Effect of Impurity Compounds on Ethanol Hydration","volume":"155","author":"Hu","year":"2010","journal-title":"J. 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