{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T23:20:57Z","timestamp":1785799257178,"version":"3.56.0"},"reference-count":61,"publisher":"MDPI AG","issue":"21","license":[{"start":{"date-parts":[[2025,10,27]],"date-time":"2025-10-27T00:00:00Z","timestamp":1761523200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["22-73-10089"],"award-info":[{"award-number":["22-73-10089"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Synthesis of anionic metal\u2013organic framework Na[Ce(BDC)2(DMF)2] based on cerium (III)\u2013sodium terephthalate was performed. The crystal structure, studied by the Rietveld method, consists of anionic [Ce(BDC)2]\u2212 layers, connected by interlayer sodium cations in a 3D network. Variable-temperature PXRD, total X-ray scattering with pair distribution function analysis, and DFT calculations revealed framework structure stability upon DMF elimination and thermal treatment up to 300 \u00b0C. Modification with copper cations was performed using wetness impregnation with a Cu(NO3)2 methanol solution to obtain a catalyst for carbon monoxide oxidation. Cu2+@Na[Ce(BDC)2(DMF)2] in situ decomposition leads to the catalytic activity of the resulting CuO\/CeO2 composite during CO gas oxidation by air.<\/jats:p>","DOI":"10.3390\/molecules30214195","type":"journal-article","created":{"date-parts":[[2025,10,29]],"date-time":"2025-10-29T02:23:28Z","timestamp":1761704608000},"page":"4195","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Robust Anionic Framework Based on Sodium\u2013Cerium Terephthalate"],"prefix":"10.3390","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5229-7131","authenticated-orcid":false,"given":"Nikita","family":"Nikandrov","sequence":"first","affiliation":[{"name":"Faculty of Materials Science, Lomonosov Moscow State University, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sofya","family":"Spasskaya","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marina","family":"Tedeeva","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Kustov","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia"},{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2818-5639","authenticated-orcid":false,"given":"Dmitry","family":"Tsymbarenko","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,10,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"13308","DOI":"10.1021\/jacs.5b07053","article-title":"MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage","volume":"137","author":"Alezi","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"8161","DOI":"10.1021\/acs.chemrev.0c00119","article-title":"MOF-Based Membranes for Gas Separations","volume":"120","author":"Qian","year":"2020","journal-title":"Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"5949","DOI":"10.2174\/0929867326666190618152518","article-title":"Metal-Organic Framework (MOF)-Based Drug Delivery","volume":"27","author":"Cao","year":"2020","journal-title":"Curr. Med. Chem."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"11849","DOI":"10.1038\/srep11849","article-title":"Synthesis of Magnetic Metal-Organic Framework (MOF) for Efficient Removal of Organic Dyes from Water","volume":"5","author":"Zhao","year":"2015","journal-title":"Sci. Rep."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"11193","DOI":"10.1021\/acs.inorgchem.5b01623","article-title":"Design and Synthesis of an MOF Thermometer with High Sensitivity in the Physiological Temperature Range","volume":"54","author":"Zhao","year":"2015","journal-title":"Inorg. Chem."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"2370308","DOI":"10.1002\/adma.202370308","article-title":"MOF-Based Chemiresistive Gas Sensors: Toward New Functionalities","volume":"35","author":"Jo","year":"2023","journal-title":"Adv. Mater."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"4044","DOI":"10.1039\/C7CE90106B","article-title":"Metal\u2013Organic Framework Catalysis","volume":"19","author":"Doonan","year":"2017","journal-title":"CrystEngComm"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"4489","DOI":"10.1021\/cm800832w","article-title":"On the Reasons for High Activity of CeO2 Catalyst for Soot Oxidation","volume":"20","author":"Machida","year":"2008","journal-title":"Chem. Mater."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"5987","DOI":"10.1021\/acs.chemrev.5b00603","article-title":"Fundamentals and Catalytic Applications of CeO2-Based Materials","volume":"116","author":"Montini","year":"2016","journal-title":"Chem. Rev."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/S0920-5861(01)00322-4","article-title":"Catalytic Activity of CeO2\u2013ZrO2 Mixed Oxide Catalysts Prepared via Sol\u2013Gel Technique: CO Oxidation","volume":"68","author":"Thammachart","year":"2001","journal-title":"Catal. Today"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"11396","DOI":"10.1039\/D0DT02455D","article-title":"Ce-MIL-140: Expanding the Synthesis Routes for Cerium(IV) Metal\u2013Organic Frameworks","volume":"49","author":"Jacobsen","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"13850","DOI":"10.1021\/ja8057953","article-title":"A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability","volume":"130","author":"Cavka","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"12578","DOI":"10.1039\/C5CC02606G","article-title":"Cerium-Based Metal Organic Frameworks with UiO-66 Architecture: Synthesis, Properties and Redox Catalytic Activity","volume":"51","author":"Lammert","year":"2015","journal-title":"Chem. Commun."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.jssc.2012.01.046","article-title":"New Metal-Organic Frameworks of [M(C6H5O7)(C6H6O7)(C6H7O7)(H2O)]\u22c5H2O (M=La, Ce) and [Ce2(C2O4)(C6H6O7)2]\u22c54H2O","volume":"188","author":"Weng","year":"2012","journal-title":"J. Solid State Chem."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"787","DOI":"10.1021\/acs.cgd.8b01369","article-title":"Disclosing the Properties of a New Ce(III)-Based MOF: Ce2(NDC)3(DMF)2","volume":"19","author":"Atzori","year":"2019","journal-title":"Cryst. Growth Des."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1237","DOI":"10.1039\/b803168a","article-title":"Syntheses, Structures, Photoluminescence, and Magnetic Properties of Nanoporous 3D Lanthanide Coordination Polymers with 4,4\u2032-Biphenyldicarboxylate Ligand","volume":"10","author":"Han","year":"2008","journal-title":"CrystEngComm"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"16551","DOI":"10.1039\/D0DT02813D","article-title":"The Chemistry of Ce-Based Metal\u2013Organic Frameworks","volume":"49","author":"Jacobsen","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2635","DOI":"10.1039\/c2ce06496k","article-title":"Homochiral Lanthanoid(III) Mesoxalate Metal\u2013Organic Frameworks: Synthesis, Crystal Growth, Chirality, Magnetic and Luminescent Properties","volume":"14","author":"Maclaren","year":"2012","journal-title":"CrystEngComm"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"10618","DOI":"10.1039\/c3ce41740a","article-title":"New Ce(Iii) Sulfate\u2013Tartrate-Based MOFs: An Insight into the Controllable Self-Assembly of Acentric Metal\u2013Organic Complexes","volume":"15","author":"Qi","year":"2013","journal-title":"CrystEngComm"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"10781","DOI":"10.1021\/ic902194g","article-title":"Structures and Properties of Porous Coordination Polymers Based on Lanthanide Carboxylate Building Units","volume":"49","author":"Han","year":"2010","journal-title":"Inorg. Chem."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"1477","DOI":"10.1039\/C3NJ01371E","article-title":"Fast and Continuous Processing of a New Sub-Micronic Lanthanide-Based Metal\u2013Organic Framework","volume":"38","author":"Sassoye","year":"2014","journal-title":"New J. Chem."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"17961","DOI":"10.1021\/acsami.7b03555","article-title":"Palladium Nanoparticles Supported on Ce-Metal\u2013Organic Framework for Efficient CO Oxidation and Low-Temperature CO2 Capture","volume":"9","author":"Lin","year":"2017","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"12911","DOI":"10.1007\/s10853-019-03786-0","article-title":"Synthesis, Structure and Properties of Pd@MOF-808","volume":"54","author":"Xu","year":"2019","journal-title":"J. Mater. Sci."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"11302","DOI":"10.1021\/ja9047653","article-title":"Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal\u2212Organic Framework","volume":"131","author":"Jiang","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"129","DOI":"10.3866\/PKU.WHXB201311201","article-title":"Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al): An Active Catalyst for CO Oxidation","volume":"30","author":"Qian","year":"2014","journal-title":"Acta Phys.-Chim. Sin."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1061","DOI":"10.1039\/C5GC02082D","article-title":"Efficient and Selective Aerobic Oxidation of Alcohols Catalysed by MOF-Derived Co Catalysts","volume":"18","author":"Bai","year":"2016","journal-title":"Green Chem."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1016\/j.fuel.2018.04.071","article-title":"Metal-Organic-Framework Derived Controllable Synthesis of Mesoporous Copper-Cerium Oxide Composite Catalysts for the Preferential Oxidation of Carbon Monoxide","volume":"229","author":"Gong","year":"2018","journal-title":"Fuel"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"1754","DOI":"10.1021\/ja511495j","article-title":"Quest for Anionic MOF Membranes: Continuous Sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity","volume":"137","author":"Shekhah","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"10514","DOI":"10.1002\/ange.201605547","article-title":"Design and Synthesis of a Water-Stable Anionic Uranium-Based Metal\u2013Organic Framework (MOF) with Ultra Large Pores","volume":"128","author":"Li","year":"2016","journal-title":"Angew. Chem."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"13567","DOI":"10.1039\/C4CC05991C","article-title":"A Bimodal Anionic MOF: Turn-off Sensing of Cu II and Specific Sensitization of Eu III","volume":"50","author":"Bhattacharyya","year":"2014","journal-title":"Chem. Commun."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"12277","DOI":"10.1039\/D3RA01746J","article-title":"Improving the Performance of an Anionic MOF by Counter Cation Replacement as Electrode Material in a Full Cell Setup of a Potassium Ion Capacitor","volume":"13","author":"Aphirakaramwong","year":"2023","journal-title":"RSC Adv."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"313","DOI":"10.1016\/j.jechem.2023.02.048","article-title":"Deep Dive into Anionic Metal-Organic Frameworks Based Quasi-Solid-State Electrolytes","volume":"81","author":"Hou","year":"2023","journal-title":"J. Energy Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"4798","DOI":"10.1039\/D2DT00089J","article-title":"A Multifunctional Anionic Metal\u2013Organic Framework for High Proton Conductivity and Photoreduction of CO2 Induced by Cation Exchange","volume":"51","author":"Sun","year":"2022","journal-title":"Dalton Trans."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"2831","DOI":"10.1039\/C5CC09814A","article-title":"Post-Synthetic Metalation in an Anionic MOF for Efficient Catalytic Activity and Removal of Heavy Metal Ions from Aqueous Solution","volume":"52","author":"Chakraborty","year":"2016","journal-title":"Chem. Commun."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"48394","DOI":"10.1021\/acsomega.3c07906","article-title":"Tuning the Cerium-Based Metal\u2013Organic Framework Formation by Template Effect and Precursor Selection","volume":"8","author":"Grebenyuk","year":"2023","journal-title":"ACS Omega"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"749","DOI":"10.1515\/MGMC.2002.25.12.749","article-title":"Crystal structure of a 3D coordination polymer: Sodium lanthanide terephthalate N, N-dimethylformamide solvate","volume":"25","author":"Long","year":"2002","journal-title":"Main Group Met. Chem."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"134","DOI":"10.1016\/j.micromeso.2011.08.020","article-title":"Algorithms and Tools for High-Throughput Geometry-Based Analysis of Crystalline Porous Materials","volume":"149","author":"Willems","year":"2012","journal-title":"Micropor. Mesopor. Mat."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"180","DOI":"10.1016\/j.cej.2012.04.091","article-title":"HKUST-1 MOF: A Matrix to Synthesize CuO and CuO\u2013CeO2 Nanoparticle Catalysts for CO Oxidation","volume":"195\u2013196","author":"Zamaro","year":"2012","journal-title":"Chem. Eng. J."},{"key":"ref_39","doi-asserted-by":"crossref","unstructured":"Stawowy, M., Jag\u00f3dka, P., Matus, K., Samojeden, B., Silvestre-Albero, J., Trawczy\u0144ski, J., and \u0141amacz, A. (2020). HKUST-1-Supported Cerium Catalysts for CO Oxidation. Catalysts, 10.","DOI":"10.3390\/catal10010108"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"3962","DOI":"10.1021\/acs.jpclett.4c00324","article-title":"Unveiling the Role and Stabilization Mechanism of Cu + into Defective Ce-MOF Clusters during CO Oxidation","volume":"15","author":"Salusso","year":"2024","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1006\/jcat.2000.2981","article-title":"Comparative Study on Redox Properties and Catalytic Behavior for CO Oxidation of CuO\/CeO2 and CuO\/ZrCeO4 Catalysts","volume":"195","author":"Coronado","year":"2000","journal-title":"J. Catal."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"132","DOI":"10.1016\/j.apsusc.2018.05.101","article-title":"A Comparative Study of CO Oxidation over Cu-O-Ce Solid Solutions and CuO\/CeO2 Nanorods Catalysts","volume":"455","author":"Hossain","year":"2018","journal-title":"Appl. Surf. Sci."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"603","DOI":"10.1007\/s11705-017-1661-z","article-title":"Effects of Preparation Methods on the Activity of CuO\/CeO2 Catalysts for CO Oxidation","volume":"11","author":"Shang","year":"2017","journal-title":"Front. Chem. Sci. Eng."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1016\/j.micromeso.2017.10.019","article-title":"A Strawsheave-like Metal Organic Framework Ce-BTC Derivative Containing High Specific Surface Area for Improving the Catalytic Activity of CO Oxidation Reaction","volume":"259","author":"Zhang","year":"2018","journal-title":"Micropor. Mesopor. Mat."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"74","DOI":"10.1016\/j.inoche.2017.03.023","article-title":"Metal Organic Framework Cu\/MIL-53(Ce)-Mediated Synthesis of Highly Active and Stable CO Oxidation Catalysts","volume":"79","author":"Tan","year":"2017","journal-title":"Inorg. Chem. Commun."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"8049","DOI":"10.1021\/acs.inorgchem.1c00581","article-title":"A Family of Lanthanide Hydroxo Carboxylates with 1D Polymeric Topology and Ln4 Butterfly Core Exhibits Switchable Supramolecular Arrangement","volume":"60","author":"Grebenyuk","year":"2021","journal-title":"Inorg. Chem."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"890","DOI":"10.1107\/S1600576722005878","article-title":"Quick and Robust PDF Data Acquisition Using a Laboratory Single-Crystal X-Ray Diffractometer for Study of Polynuclear Lanthanide Complexes in Solid Form and in Solution","volume":"55","author":"Tsymbarenko","year":"2022","journal-title":"J. Appl. Crystallogr."},{"key":"ref_48","unstructured":"Tsymbarenko, D. (2025, April 20). FormagiX v.0.9.9b. 2D XRD Processing Software. Available online: https:\/\/formagix.org\/."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"560","DOI":"10.1107\/S0021889813005190","article-title":"PDFgetX3: A Rapid and Highly Automatable Program for Processing Powder Diffraction Data into Total Scattering Pair Distribution Functions","volume":"46","author":"Davis","year":"2013","journal-title":"J. Appl. Crystallogr."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"562","DOI":"10.1107\/S2053273315014473","article-title":"Complex Modeling: A Strategy and Software Program for Combining Multiple Information Sources to Solve Ill Posed Structure and Nanostructure Inverse Problems","volume":"71","author":"Farrow","year":"2015","journal-title":"Acta Crystallogr. A Found. Adv."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"987","DOI":"10.1107\/S0021889891006441","article-title":"Indexing of Powder Diffraction Patterns for Low-Symmetry Lattices by the Successive Dichotomy Method","volume":"24","author":"Boultif","year":"1991","journal-title":"J. Appl. Crystallogr."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"345","DOI":"10.1515\/zkri-2014-1737","article-title":"Crystallographic Computing System JANA2006: General Features","volume":"229","author":"Palatinus","year":"2014","journal-title":"Z. Kristallogr. Cryst. Mater."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"786","DOI":"10.1107\/S0021889807029238","article-title":"SUPERFLIP\u2013A Computer Program for the Solution of Crystal Structures by Charge Flipping in Arbitrary Dimensions","volume":"40","author":"Palatinus","year":"2007","journal-title":"J. Appl. Crystallogr."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","article-title":"Efficiency of Ab-Initio Total Energy Calculations for Metals and Semiconductors Using a Plane-Wave Basis Set","volume":"6","author":"Kresse","year":"1996","journal-title":"Comput. Mater. Sci."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"14251","DOI":"10.1103\/PhysRevB.49.14251","article-title":"Ab Initio Molecular-Dynamics Simulation of the Liquid-Metal\u2013Amorphous-Semiconductor Transition in Germanium","volume":"49","author":"Kresse","year":"1994","journal-title":"Phys. Rev. B"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","article-title":"Efficient Iterative Schemes for Ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys. Rev. B"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"558","DOI":"10.1103\/PhysRevB.47.558","article-title":"Ab Initio Molecular Dynamics for Liquid Metals","volume":"47","author":"Kresse","year":"1993","journal-title":"Phys. Rev. B"},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","article-title":"A Consistent and Accurate Ab Initio Parametrization of Density Functional Dispersion Correction (DFT-D) for the 94 Elements H-Pu","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1021\/ar00109a003","article-title":"Atoms in Molecules","volume":"18","author":"Bader","year":"1985","journal-title":"Acc. Chem. Res."},{"key":"ref_60","first-page":"131","article-title":"AIM-UC: An Application for QTAIM Analysis","volume":"14","author":"Vega","year":"2014","journal-title":"J. Comput. Methods Sci. Eng."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"170","DOI":"10.1016\/S0009-2614(98)00036-0","article-title":"Hydrogen Bond Strengths Revealed by Topological Analyses of Experimentally Observed Electron Densities","volume":"285","author":"Espinosa","year":"1998","journal-title":"Chem. Phys. Lett."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/21\/4195\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,29]],"date-time":"2025-10-29T02:29:18Z","timestamp":1761704958000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/30\/21\/4195"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,27]]},"references-count":61,"journal-issue":{"issue":"21","published-online":{"date-parts":[[2025,11]]}},"alternative-id":["molecules30214195"],"URL":"https:\/\/doi.org\/10.3390\/molecules30214195","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,27]]}}}