{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T04:30:24Z","timestamp":1786336224576,"version":"build-2736575974"},"reference-count":48,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T00:00:00Z","timestamp":1786147200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["42274137"],"award-info":[{"award-number":["42274137"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["42302047"],"award-info":[{"award-number":["42302047"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"award":["42274137"],"award-info":[{"award-number":["42274137"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"publisher"}]},{"award":["42302047"],"award-info":[{"award-number":["42302047"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Guizhou Normal University Academic New Talent Fund","award":["GZNUD[2025]10"],"award-info":[{"award-number":["GZNUD[2025]10"]}]},{"name":"Guizhou Normal University Academic New Talent Fund","award":["GZNUD[2025]12"],"award-info":[{"award-number":["GZNUD[2025]12"]}]},{"award":["GZNUD[2025]10"],"award-info":[{"award-number":["GZNUD[2025]10"]}],"id":[{"id":"https:\/\/ror.org\/02x1pa065","id-type":"ROR","asserted-by":"publisher"}]},{"award":["GZNUD[2025]12"],"award-info":[{"award-number":["GZNUD[2025]12"]}],"id":[{"id":"https:\/\/ror.org\/02x1pa065","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Yibin University Science and Technology Program","award":["2025XJQH18"],"award-info":[{"award-number":["2025XJQH18"]}]},{"award":["2025XJQH18"],"award-info":[{"award-number":["2025XJQH18"]}],"id":[{"id":"https:\/\/ror.org\/03w8m2977","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Open Research Fund of Computational Physics Key Laboratory of Sichuan Province, Yibin University","award":["YBUJSWL-ZD-2024-01"],"award-info":[{"award-number":["YBUJSWL-ZD-2024-01"]}]},{"award":["YBUJSWL-ZD-2024-01"],"award-info":[{"award-number":["YBUJSWL-ZD-2024-01"]}],"id":[{"id":"https:\/\/ror.org\/03w8m2977","id-type":"ROR","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Cadmium phosphorous trisulfide (CdPS3), a prototypical member of metal thio- and selenophosphates (MTPs), has garnered tremendous research interest due to its fundamental properties and potential for novel applications. In this paper, we conducted a comprehensive investigation on the structural evolution and electrical transport behaviors of CdPS3 up to 59.1 GPa under different hydrostatic environments by means of Raman spectroscopy and electrical conductivity measurements. Under non-hydrostatic compression, CdPS3 experienced a succession of structural modifications from C2\/m to R3\u00af phases at 1.4(5) GPa, then to the isostructural R3\u00af phase at 7.8(5) GPa and sequentially to the P3\u00af1m phase at 29.8(11) GPa, followed by a semiconductor-to-metal transition at 51.3(8) GPa. Under hydrostatic pressurization, ~2.0 GPa pressure hysteresis for the R3\u00af-to-P3\u00af1m structural modification and metallization was identified, which can be reasonably interpreted by the impact of deviatoric stress. Upon decompression, the structural transitions of CdPS3 were demonstrated to be reversible with the existence of considerable pressure hysteresis under different hydrostatic environments. Our findings on CdPS3 not only lay a solid foundation for exploring the physicochemical properties of other MTPs under extreme conditions but also push forward its applications in high-performance multifunctional devices.<\/jats:p>","DOI":"10.3390\/molecules31162760","type":"journal-article","created":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T01:20:03Z","timestamp":1786324803000},"page":"2760","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Experimental Observations on the Structural Transitions and Metallization in the Two-Dimensional Layered Compound of Cadmium Phosphide Sulfide Under Extreme Conditions"],"prefix":"10.3390","volume":"31","author":[{"given":"Xinyu","family":"Zhang","sequence":"first","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lidong","family":"Dai","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7748-8919","authenticated-orcid":false,"given":"Haiying","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziqiang","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juxiang","family":"Shao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongchun","family":"Luo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajun","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongying","family":"Mi","sequence":"additional","affiliation":[{"name":"Key Laboratory of High-Temperature and High-Pressure Study of the Earth\u2019s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miao","family":"Ren","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Gao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meiling","family":"Hong","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physics of Sichuan Province, College of Mathematics and Physics, Yibin University, Yibin 644007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,8,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2400517","DOI":"10.1002\/pssb.202400517","article-title":"Structural and magnetic properties of van der Waals layered metal phosphorous trichalcogenides","volume":"262","author":"Peng","year":"2025","journal-title":"Phys. Status Solidi B"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"15851","DOI":"10.1039\/D4NR01577K","article-title":"Understanding and tuning magnetism in van der Waals-type metal thiophosphates","volume":"16","author":"Basnet","year":"2024","journal-title":"Nanoscale"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"1802151","DOI":"10.1002\/adfm.201802151","article-title":"New frontiers on van der Waals layered metal phosphorous trichalcogenides","volume":"28","author":"Wang","year":"2018","journal-title":"Adv. Funct. Mater."},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Matsuoka, T., Kim, H., Samanta, S., Musfeldt, J.L., and Mandrus, D.G. (2024). MPX3 van der Waals magnets under pressure (M = Mn, Ni, V, Fe, Co, Cd; X = S, Se). Front. Mater., 11.","DOI":"10.3389\/fmats.2024.1362744"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"12563","DOI":"10.1021\/acsami.6b16553","article-title":"Layered metal thiophosphate materials: Magnetic, electrochemical, and electronic properties","volume":"9","author":"Sofer","year":"2017","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"233104","DOI":"10.1063\/5.0089478","article-title":"Pressure-induced phase transitions in weak interlayer coupling CdPS3","volume":"120","author":"Niu","year":"2022","journal-title":"Appl. Phys. Lett."},{"key":"ref_7","doi-asserted-by":"crossref","unstructured":"Rahman, S., Ngyuen, H., Macdonald, D., and Lu, Y.R. (2024). Temperature-dependent phase variations in van der Waals CdPS3 revealed by Raman spectroscopy. Symmetry, 16.","DOI":"10.3390\/sym16020140"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"165109","DOI":"10.1063\/5.0084258","article-title":"Acoustic phonons and elastic stiffnesses from Brillouin scattering of CdPS3","volume":"131","author":"Reed","year":"2022","journal-title":"J. Appl. Phys."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"165125","DOI":"10.1103\/PhysRevB.107.165125","article-title":"Pressure-induced insulator-to-metal transition in the van der Waals compound CoPS3","volume":"107","author":"Matsuoka","year":"2023","journal-title":"Phys. Rev. B"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"40","DOI":"10.1038\/s41699-022-00313-9","article-title":"Symmetry progression and possible polar metallicity in NiPS3 under pressure","volume":"6","author":"Harms","year":"2022","journal-title":"npj 2D Mater. Appl."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"15751","DOI":"10.1021\/jacs.6b10225","article-title":"Pressure-driven cooperative spin-crossover, large-volume collapse, and semiconductor-to-metal transition in manganese(II) honeycomb lattices","volume":"138","author":"Wang","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"2500093","DOI":"10.1002\/aelm.202500093","article-title":"Thermal and dimensional stability of photocatalytic material ZnPS3 under extreme environmental conditions","volume":"11","author":"Mukherjee","year":"2025","journal-title":"Adv. Electron. Mater."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"054801","DOI":"10.1103\/PhysRevMaterials.7.054801","article-title":"Pressure-induced superconductivity in the metal thiophosphate Pb2P2S6","volume":"7","author":"He","year":"2023","journal-title":"Phys. Rev. Mater."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"107330","DOI":"10.1016\/j.rinp.2024.107330","article-title":"Tuning the electronic and vibrational properties of Sn2P2S6: Pressure induced metallization and superconductivity","volume":"57","author":"Karaca","year":"2024","journal-title":"Results Phys."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"013511","DOI":"10.1063\/1.4772624","article-title":"Raman spectroscopy of ferroelectric Sn2P2S6 under high pressure up to 40 GPa: Phase transitions and metallization","volume":"113","author":"Ovsyannikov","year":"2013","journal-title":"J. Appl. Phys."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"4245","DOI":"10.1039\/C6DT03854A","article-title":"Tuning the electronic and vibrational properties of Sn2P2Se6 and Pb2P2S6 crystals and their metallization under high pressure","volume":"46","author":"Ovsyannikov","year":"2017","journal-title":"Dalton Trans."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1914","DOI":"10.1038\/s41467-018-04326-1","article-title":"Emergent superconductivity in an iron-based honeycomb lattice initiated by pressure-driven spin-crossover","volume":"9","author":"Wang","year":"2018","journal-title":"Nat. Commun."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"266801","DOI":"10.1103\/PhysRevLett.121.266801","article-title":"Pressure-induced electronic and structural phase evolution in the van der Waals compound FePS3","volume":"121","author":"Haines","year":"2018","journal-title":"Phys. Rev. Lett."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"071127","DOI":"10.1063\/5.0274796","article-title":"Symmetry progression and band vs Mott character of CdPS3 under pressure","volume":"13","author":"Shah","year":"2025","journal-title":"APL Mater."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"16144","DOI":"10.1007\/s10853-023-08998-z","article-title":"Pressure-induced phase transition and electronic properties of CdPX3 (X = S and Se) by first-principles calculation","volume":"58","author":"Li","year":"2023","journal-title":"J. Mater. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"5108","DOI":"10.1039\/D3TC04196D","article-title":"Pressure-induced superconductivity in van der Waals layered semiconductor SnPSe3","volume":"12","author":"Qi","year":"2024","journal-title":"J. Mater. Chem. C"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"124008","DOI":"10.1103\/PhysRevMaterials.5.124008","article-title":"Quasihydrostatic versus nonhydrostatic pressure effects on the electrical properties of NiPS3","volume":"5","author":"Cui","year":"2021","journal-title":"Phys. Rev. Mater."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"144103","DOI":"10.1103\/PhysRevB.110.144103","article-title":"Structural, ferroelectric, and electronic transitions in the van der Waals multiferroic material CuCrP2S6 under high temperature and high pressure","volume":"110","author":"Hong","year":"2024","journal-title":"Phys. Rev. B"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"104501","DOI":"10.1063\/5.0251653","article-title":"Structural, electronic, and ferroelectric transitions in van der Waals ferroelectric CuInP2Se6 under high temperature and high pressure","volume":"162","author":"Hong","year":"2025","journal-title":"J. Chem. Phys."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"9196","DOI":"10.1039\/D6TC00306K","article-title":"Pressure-induced structural transitions and metallization in two-dimensional semiconductor CuInP2S6","volume":"14","author":"Hong","year":"2026","journal-title":"J. Mater. Chem. C"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"33191","DOI":"10.1021\/acsomega.6c03322","article-title":"Observation of structural transition and metallization in a van der Waals diamagnet ZnPS3 via pressure manipulation","volume":"11","author":"Zhang","year":"2026","journal-title":"ACS Omega"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"075413","DOI":"10.1088\/0022-3727\/42\/7\/075413","article-title":"Hydrostatic limits of 11 pressure transmitting media","volume":"42","author":"Klotz","year":"2009","journal-title":"J. Phys. D Appl. Phys."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"038402","DOI":"10.1063\/5.0044893","article-title":"Structural transitions of 4:1 methanol-ethanol mixture and silicone oil under high pressure","volume":"6","author":"Chen","year":"2021","journal-title":"Matter Radiat. Extrem."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"235421","DOI":"10.1103\/PhysRevB.104.235421","article-title":"Pressure-driven phase transformations and phase segregation in ferrielectric CuInP2S6-In4\/3P2S6 self-assembled heterostructures","volume":"104","author":"Rao","year":"2021","journal-title":"Phys. Rev. B"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1002\/(SICI)1097-4555(199602)27:2<185::AID-JRS932>3.0.CO;2-G","article-title":"Raman evidence for a phase transition in CdPS3","volume":"27","author":"Sourisseau","year":"1996","journal-title":"J. Raman Spectrosc."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"4821","DOI":"10.1021\/acs.chemmater.3c00791","article-title":"Pressure-induced reversible and irreversible multistate switching in NiAs-type chromium selenides","volume":"35","author":"Li","year":"2023","journal-title":"Chem. Mater."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"19783","DOI":"10.1021\/acs.inorgchem.4c02983","article-title":"Structural and electronic phase transitions in three stable tin\u2013sulfur metallic chalcogenides under high pressure","volume":"63","author":"Hong","year":"2024","journal-title":"Inorg. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"112903","DOI":"10.1063\/5.0194490","article-title":"Pressure-induced ferroelectric and electronic transitions in two-dimensional ferroelectric semiconductor of NbOCl2 up to 41.7 GPa","volume":"124","author":"Hong","year":"2024","journal-title":"Appl. Phys. Lett."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"224107","DOI":"10.1103\/k3fv-9hss","article-title":"Structural, electronic, and magnetic transitions in the breathing Kagome magnet Nb3Br8 under high temperature and high pressure","volume":"111","author":"Hong","year":"2025","journal-title":"Phys. Rev. B"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"112901","DOI":"10.1063\/5.0257969","article-title":"Observation of electronic and structural transitions in two-dimensional ferroelastic semiconductor of Nb2GeTe4 via pressure manipulation","volume":"126","author":"Hong","year":"2025","journal-title":"Appl. Phys. Lett."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1248","DOI":"10.1039\/D5DT02937F","article-title":"Pressure-induced metallization and electronic transition in a two-dimensional ferroelastic semiconductor of Nb2SiTe4 in different hydrostatic environments","volume":"55","author":"Zhang","year":"2026","journal-title":"Dalton Trans."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1016\/S0031-9201(99)00135-1","article-title":"Pressure effect on electrical conductivity of mantle olivine","volume":"118","author":"Xu","year":"2000","journal-title":"Phys. Earth Planet. Inter."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"2001068","DOI":"10.1002\/smtd.202001068","article-title":"Recent advances in 2D layered phosphorous compounds","volume":"5","author":"Zhang","year":"2021","journal-title":"Small Methods"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"36486","DOI":"10.1021\/jacs.5c11030","article-title":"Anomalous metallic cubic CsCuBr3 perovskites: Pressure- and temperature-driven suppression of Jahn-Teller distortion","volume":"147","author":"Li","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"346229","DOI":"10.1088\/0953-8984\/19\/34\/346229","article-title":"Variation of the Jahn-Teller distortion with pressure in the layered perovskite Rb2CuCl4: Local and crystal compressibilities","volume":"19","author":"Aguado","year":"2007","journal-title":"J. Phys. Condens. Matter"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"1217","DOI":"10.1063\/10.0002477","article-title":"First-principles LCAO study of the low- and room-temperature phases of CdPS3","volume":"46","author":"Kuzmin","year":"2020","journal-title":"Low temp. Phys."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"10042","DOI":"10.1007\/s12274-024-6941-6","article-title":"Solar-bind ultraviolet photodetector derived from direct carrier transition beyond the bandgap of CdPS3 single crystals","volume":"17","author":"Zhou","year":"2024","journal-title":"Nano Res."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"115116","DOI":"10.1016\/j.ssc.2023.115116","article-title":"Narrowing the optical gap of CdPS3 single crystal via chemical intercalation using liquid ammonia method","volume":"363","author":"Sun","year":"2023","journal-title":"Solid State Commun."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"22855","DOI":"10.1039\/C7TA06971E","article-title":"Recent advances in ternary two-dimensional materials: Synthesis, properties and applications","volume":"5","author":"Wang","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"800","DOI":"10.1143\/JPSJ.62.800","article-title":"Raman scattering study of structural phase transition in layered compound CdPS3","volume":"62","author":"Sekine","year":"1993","journal-title":"J. Phys. Soc. Jpn."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1181","DOI":"10.1016\/0025-5408(85)90092-3","article-title":"Structural determination of some MPS3 layered phases (M = Mn, Fe, Co, Ni and Cd)","volume":"20","author":"Ouvrard","year":"1985","journal-title":"Mater. Res. Bull."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"4673","DOI":"10.1029\/JB091iB05p04673","article-title":"Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions","volume":"91","author":"Mao","year":"1986","journal-title":"J. Geophys. Res. Solid Earth"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"122516","DOI":"10.1016\/j.jnoncrysol.2023.122516","article-title":"Pressure-induced reversible structural phase transitions and metallization in GeTe under hydrostatic and non-hydrostatic environments up to 22.9 GPa","volume":"618","author":"Zhang","year":"2023","journal-title":"J. Non-Cryst. Solids"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/31\/16\/2760\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T04:15:51Z","timestamp":1786335351000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/31\/16\/2760"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,8]]},"references-count":48,"journal-issue":{"issue":"16","published-online":{"date-parts":[[2026,8]]}},"alternative-id":["molecules31162760"],"URL":"https:\/\/doi.org\/10.3390\/molecules31162760","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,8]]}}}