{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T04:44:12Z","timestamp":1790657052899,"version":"4.1.0"},"reference-count":53,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T00:00:00Z","timestamp":1787011200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["12075147"],"award-info":[{"award-number":["12075147"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["42177405"],"award-info":[{"award-number":["42177405"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"award":["12075147"],"award-info":[{"award-number":["12075147"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"publisher"}]},{"award":["42177405"],"award-info":[{"award-number":["42177405"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Natural Science Foundation of Shanghai","award":["22ZR1444300"],"award-info":[{"award-number":["22ZR1444300"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>MOF-derived catalysts have considerable potential for aqueous contaminant control, but their practical application is often constrained by the aggregation and difficult recovery of powder catalysts. In this study, a self-supporting N-doped Fe\/Ni-based monolithic catalyst, denoted N-101-NFF, was fabricated through the in situ growth of an Fe-based MOF precursor on nickel\u2013iron foam followed by pyrolysis. Under the conditions of 50 mg\/L chlortetracycline (CTC), 0.08 mmol\/L peroxymonosulfate (PMS), and an effective catalyst area of 1 cm2, N-101-NFF degraded 90.3% of CTC within 60 min and maintained a degradation efficiency of 88.6% after five consecutive cycles. Quenching experiments and EPR analysis indicated the involvement of \u2022OH, SO4\u2022\u2212, O2\u2022\u2212, and 1O2 in CTC degradation. Electrochemical measurements indicated improved interfacial charge-transfer characteristics, while post-reaction XPS analysis revealed changes in the Fe and Ni valence states and surface N- and O-containing groups, supporting the involvement of Fe and Ni redox cycling and these surface functionalities in PMS activation. In a fixed-bed reactor, the system maintained more than 86% CTC removal over 24 h of continuous-flow operation at a CTC feed rate of 200 mL\/h. These results highlight the potential of N-101-NFF as a recoverable monolithic catalyst for PMS-based treatment of antibiotic-contaminated water.<\/jats:p>","DOI":"10.3390\/molecules31162884","type":"journal-article","created":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:12:11Z","timestamp":1787069531000},"page":"2884","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Investigation of the Performance and Mechanism of an N-Doped Monolithic Fe\/Ni-Based Catalyst for PMS Activation Toward Chlortetracycline Degradation in Water"],"prefix":"10.3390","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4592-3031","authenticated-orcid":false,"given":"Yiqiong","family":"Yang","sequence":"first","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan","family":"Han","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cui","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pingchuan","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Panchen","family":"Li","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2217-6173","authenticated-orcid":false,"given":"Xiaodong","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,8,18]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"132387","DOI":"10.1016\/j.cej.2021.132387","article-title":"Degradation of antibiotic pollutants by persulfate activated with various carbon materials","volume":"429","author":"Gao","year":"2022","journal-title":"Chem. 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