{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T01:59:16Z","timestamp":1790387956152,"version":"4.1.0"},"reference-count":57,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2020,12,11]],"date-time":"2020-12-11T00:00:00Z","timestamp":1607644800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51771076"],"award-info":[{"award-number":["51771076"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Guangdong \u201cPearl River Talents Plan\u201d","award":["2017GC010218"],"award-info":[{"award-number":["2017GC010218"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>The cathode, a crucial constituent part of Li-ion batteries, determines the output voltage and integral energy density of batteries to a great extent. Among them, Ni-rich LiNixCoyMnzO2 (x + y + z = 1, x \u2265 0.6) layered transition metal oxides possess a higher capacity and lower cost as compared to LiCoO2, which have stimulated widespread interests. However, the wide application of Ni-rich cathodes is seriously hampered by their poor diffusion dynamics and severe voltage drops. To moderate these problems, a nanobrick Ni-rich layered LiNi0.6Co0.2Mn0.2O2 cathode with a preferred orientation (110) facet was designed and successfully synthesized via a modified co-precipitation route. The galvanostatic intermittent titration technique (GITT) and electrochemical impedance spectroscopy (EIS) analysis of LiNi0.6Co0.2Mn0.2O2 reveal its superior kinetic performance endowing outstanding rate performance and long-term cycle stability, especially the voltage drop being as small as 67.7 mV at a current density of 0.5 C for 200 cycles. Due to its unique architecture, dramatically shortened ion\/electron diffusion distance, and more unimpeded Li-ion transmission pathways, the current nanostructured LiNi0.6Co0.2Mn0.2O2 cathode enhances the Li-ion diffusion dynamics and suppresses the voltage drop, thus resulting in superior electrochemical performance.<\/jats:p>","DOI":"10.3390\/nano10122495","type":"journal-article","created":{"date-parts":[[2020,12,13]],"date-time":"2020-12-13T20:56:57Z","timestamp":1607893017000},"page":"2495","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Ni-Rich Layered Oxide with Preferred Orientation (110) Plane as a Stable Cathode Material for High-Energy Lithium-Ion Batteries"],"prefix":"10.3390","volume":"10","author":[{"given":"Fangkun","family":"Li","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengbo","family":"Liu","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiadong","family":"Shen","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7646-3624","authenticated-orcid":false,"given":"Xijun","family":"Xu","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liyan","family":"Zeng","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Li","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dechao","family":"Zhang","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyong","family":"Zuo","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7078-8046","authenticated-orcid":false,"given":"Jun","family":"Liu","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2020,12,11]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"652","DOI":"10.1038\/451652a","article-title":"Building better batteries","volume":"451","author":"Armand","year":"2008","journal-title":"Nature"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"8986","DOI":"10.1021\/acsnano.9b02903","article-title":"Mechanistic Understanding of Metal Phosphide Host for Sulfur Cathode in High-Energy-Density Lithium-Sulfur Batteries","volume":"13","author":"Shen","year":"2019","journal-title":"ACS Nano"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"9033","DOI":"10.1021\/acsnano.7b03530","article-title":"Robust Pitaya-Structured Pyrite as High Energy Density Cathode for High-Rate Lithium Batteries","volume":"11","author":"Xu","year":"2017","journal-title":"ACS Nano"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1702028","DOI":"10.1002\/aenm.201702028","article-title":"Prospect and Reality of Ni-Rich Cathode for Commercialization","volume":"8","author":"Kim","year":"2018","journal-title":"Adv. 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