{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T02:40:57Z","timestamp":1760236857190,"version":"build-2065373602"},"reference-count":45,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2021,12,29]],"date-time":"2021-12-29T00:00:00Z","timestamp":1640736000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["20-19-00386"],"award-info":[{"award-number":["20-19-00386"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>This work addresses the Suzuki cross-coupling between 4-bromoanisole (BrAn) and phenylboronic acid (PBA) in an environmentally benign ethanol\u2013water solvent catalysed by mono- (Pd) and bimetallic (PdAu, PdCu, PdZn) nanoparticles (NPs) stabilised within hyper-cross-linked polystyrene (HPS) bearing tertiary amino groups. Small Pd NPs of about 2 nm in diameters were formed and stabilized by HPS independently in the presence of other metals. High catalytic activity and complete conversion of BrAn was attained at low Pd loading. Introduction of Zn to the catalyst composition resulted in the formation of Pd\/Zn\/ZnO NPs, which demonstrated nearly double activity as compared to Pd\/HPS. Bimetallic core-shell PdAu\/HPS samples were 3-fold more active as compared to Pd\/HPS. Both Pd\/HPS and PdAu\/HPS samples revealed promising stability confirmed by catalyst recycling in repeated reaction runs.<\/jats:p>","DOI":"10.3390\/nano12010094","type":"journal-article","created":{"date-parts":[[2021,12,29]],"date-time":"2021-12-29T23:31:35Z","timestamp":1640820695000},"page":"94","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Mono- and Bimetallic Nanoparticles Stabilized by an Aromatic Polymeric Network for a Suzuki Cross-Coupling Reaction"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6348-3623","authenticated-orcid":false,"given":"Linda Zh.","family":"Nikoshvili","sequence":"first","affiliation":[{"name":"Department of Biotechnology, Chemistry and Standardization, Tver State Technical University, Afanasy Nikitina Street 22, 170026 Tver, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kristina N.","family":"Shkerina","sequence":"additional","affiliation":[{"name":"Department of Biotechnology, Chemistry and Standardization, Tver State Technical University, Afanasy Nikitina Street 22, 170026 Tver, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexey V.","family":"Bykov","sequence":"additional","affiliation":[{"name":"Department of Biotechnology, Chemistry and Standardization, Tver State Technical University, Afanasy Nikitina Street 22, 170026 Tver, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander I.","family":"Sidorov","sequence":"additional","affiliation":[{"name":"Department of Biotechnology, Chemistry and Standardization, Tver State Technical University, Afanasy Nikitina Street 22, 170026 Tver, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander L.","family":"Vasiliev","sequence":"additional","affiliation":[{"name":"National Research Centre \u201cKurchatov Institute\u201d, Kurchatov Square 1, 123182 Moscow, Russia"},{"name":"Institute of Crystallography of the Russian Academy of Sciences, Leninsky Prospekt 59, 117333 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mikhail G.","family":"Sulman","sequence":"additional","affiliation":[{"name":"Department of Biotechnology, Chemistry and Standardization, Tver State Technical University, Afanasy Nikitina Street 22, 170026 Tver, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lioubov","family":"Kiwi-Minsker","sequence":"additional","affiliation":[{"name":"Regional Technological Centre, Tver State University, Zhelyabova Street 33, 170100 Tver, Russia"},{"name":"Department of Basic Sciences, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, ISIC-FSB-EPFL, CH-1015 Lausanne, Switzerland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,12,29]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"720","DOI":"10.1016\/j.jcis.2018.11.065","article-title":"Ultra-fine Pd nanoparticles confined in a porous organic polymer: A leaching-and-aggregation-resistant catalyst for the efficient reduction of nitroarenes by NaBH4","volume":"538","author":"Yuan","year":"2019","journal-title":"J. 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