{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T13:28:09Z","timestamp":1787664489710,"version":"build-2736575974"},"reference-count":60,"publisher":"MDPI AG","issue":"9","license":[{"start":{"date-parts":[[2022,4,23]],"date-time":"2022-04-23T00:00:00Z","timestamp":1650672000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Science, Innovation, and Universities of Spain","award":["RTI2018-095536-B-I00"],"award-info":[{"award-number":["RTI2018-095536-B-I00"]}]},{"name":"Ministry of Science, Innovation, and Universities of Spain","award":["RTI2018-100910-B-C44"],"award-info":[{"award-number":["RTI2018-100910-B-C44"]}]},{"DOI":"10.13039\/501100003359","name":"Generalitat Valenciana","doi-asserted-by":"publisher","award":["PROMETEO\/2019\/056"],"award-info":[{"award-number":["PROMETEO\/2019\/056"]}],"id":[{"id":"10.13039\/501100003359","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>In this work, sorbets based on UVM-7 mesoporous silica doped with Fe were synthesized and applied to solid-phase extraction of perfluoroalkyl substances from environmental water samples. These emerging pollutants were then determined by liquid chromatography coupled with a mass spectrometry detector. Thus, Fe-UVM-7 mesoporous silica materials with different contents of iron, as well as different pore sizes (by using alkyltrimethilamonium bromide surfactants with different organic tail lengths) were synthesized, and their structure was confirmed for the first time by transmission electron microscopy, nitrogen adsorption\u2013desorption, X-ray diffraction, and Raman spectroscopy. After comparison, Fe50-UVM-7-C12 was selected as the best material for analyte retention, and several extraction parameters were optimized regarding the loading and elution step. Once the method was developed and applied to real matrices, extraction efficiencies in the range of 61\u2013110% were obtained for analytes with C8\u2013C14 chain length, both perfluoroalkyl carboxylates, and perfluoroalkyl sulfonates. Likewise, limits of detection in the range of 3.0\u20138.1 ng L\u22121 were obtained for all target analytes. In the analysis of real well-water samples, no target compounds were detected. Spiked samples were analyzed in comparison to Oasis WAX cartridges, and statistically comparable results were achieved.<\/jats:p>","DOI":"10.3390\/nano12091441","type":"journal-article","created":{"date-parts":[[2022,4,23]],"date-time":"2022-04-23T21:39:45Z","timestamp":1650749985000},"page":"1441","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Iron-Doped Bimodal Mesoporous Silica Nanomaterials as Sorbents for Solid-Phase Extraction of Perfluoroalkyl Substances in Environmental Water Samples"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9180-6066","authenticated-orcid":false,"given":"Enric","family":"Pellicer-Castell","sequence":"first","affiliation":[{"name":"Department of Analytical Chemistry, Faculty of Chemistry, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Valencia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0545-8833","authenticated-orcid":false,"given":"Carolina","family":"Belenguer-Sapi\u00f1a","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry, Faculty of Chemistry, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Valencia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8895-1681","authenticated-orcid":false,"given":"Jamal","family":"El Haskouri","sequence":"additional","affiliation":[{"name":"Institute of Material Science (ICMUV), Universitat de Val\u00e8ncia, Catedr\u00e1tico Jos\u00e9 Beltr\u00e1n 2, 46980 Paterna, Valencia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8741-3769","authenticated-orcid":false,"given":"Pedro","family":"Amor\u00f3s","sequence":"additional","affiliation":[{"name":"Institute of Material Science (ICMUV), Universitat de Val\u00e8ncia, Catedr\u00e1tico Jos\u00e9 Beltr\u00e1n 2, 46980 Paterna, Valencia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8745-3795","authenticated-orcid":false,"given":"Jos\u00e9 Manuel","family":"Herrero-Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry, Faculty of Chemistry, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Valencia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2667-5631","authenticated-orcid":false,"given":"Adela R.","family":"Mauri-Aucejo","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry, Faculty of Chemistry, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Valencia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,4,23]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"513","DOI":"10.1002\/ieam.258","article-title":"Perfluoroalkyl and polyfluoroalkyl substances in the environment: Terminology, classification, and origins","volume":"7","author":"Buck","year":"2011","journal-title":"Integr. 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