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X2021073 Special Post D"]}]},{"name":"The cultivation project of Guizhou University","award":["NO. [2020]38"],"award-info":[{"award-number":["NO. [2020]38"]}]},{"name":"The cultivation project of Guizhou University","award":["NO. ZK[2022]088"],"award-info":[{"award-number":["NO. ZK[2022]088"]}]},{"name":"Natural Science Basic Research Program of Guizhou Province","award":["NO. 2021010"],"award-info":[{"award-number":["NO. 2021010"]}]},{"name":"Natural Science Basic Research Program of Guizhou Province","award":["NO. 20165655"],"award-info":[{"award-number":["NO. 20165655"]}]},{"name":"Natural Science Basic Research Program of Guizhou Province","award":["NO. 20195645"],"award-info":[{"award-number":["NO. 20195645"]}]},{"name":"Natural Science Basic Research Program of Guizhou Province","award":["NO. 20209"],"award-info":[{"award-number":["NO. 20209"]}]},{"name":"Natural Science Basic Research Program of Guizhou Province","award":["NO. X2021073 Special Post D"],"award-info":[{"award-number":["NO. X2021073 Special Post D"]}]},{"name":"Natural Science Basic Research Program of Guizhou Province","award":["NO. [2020]38"],"award-info":[{"award-number":["NO. [2020]38"]}]},{"name":"Natural Science Basic Research Program of Guizhou Province","award":["NO. ZK[2022]088"],"award-info":[{"award-number":["NO. ZK[2022]088"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>In this paper, the molecular sieve NaZSM-5 was modified with zirconium dioxide (ZrO2) by a hydrothermal coating process and other methods. By comparing the effects of the crystal phase structure of ZrO2 and the compositing method on the physicochemical properties and catalytic performance of the obtained composites, the structure\u2013performance relationship of these composite catalysts was revealed. The results indicate that in the hydrothermal system used for the preparation of NaZSM-5, Zr4+ is more likely to dissolve from m-ZrO2 than from t-ZrO2, which can subsequently enter the molecular sieve, causing a greater degree of desiliconization of the framework. The larger specific surface area (360 m2\/g) and pore volume (0.52 cm3\/g) of the m-ZrO2\/NaZSM-5 composite catalyst increase the exposure of its abundant acidic (0.078 mmol\/g) and basic (0.081 mmol\/g) active centers compared with other composites. Therefore, this catalyst exhibits a shorter induction period and better catalytic performance. Furthermore, compared with the impregnation method and mechanochemical method, the hydrothermal coating method produces a greater variety of acid\u2013base active centers in the composite catalyst due to the hydrothermal modifying effect.<\/jats:p>","DOI":"10.3390\/nano12111803","type":"journal-article","created":{"date-parts":[[2022,5,25]],"date-time":"2022-05-25T08:41:33Z","timestamp":1653468093000},"page":"1803","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Role of Zirconia in Oxide-Zeolite Composite for Thiolation of Methanol with Hydrogen Sulfide to Methanethiol"],"prefix":"10.3390","volume":"12","author":[{"given":"Tinglong","family":"Yang","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengqin","family":"Yao","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianxiang","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunliang","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianxin","family":"Cao","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China"},{"name":"Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang 550025, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,5,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1016\/j.enzmictec.2005.02.008","article-title":"Production of l-methionine by submerged fermentation: A review","volume":"37","author":"Gomes","year":"2005","journal-title":"Enzym. 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