{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T18:58:27Z","timestamp":1790794707322,"version":"4.1.0"},"reference-count":58,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2022,6,17]],"date-time":"2022-06-17T00:00:00Z","timestamp":1655424000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Slovenian Research Agency research programs P1-0021"},{"name":"STOREHEAT (MATERA ERA-NET) project"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>Three porous aluminium benzene-1,3,5-tricarboxylates MIL-96(Al), MIL-100(Al) and MIL-110(Al) materials were studied for their hydrothermal stability. The 40-cycles water vapour sorption experiments for the three samples were performed by varying the temperature between 40 and 140 \u00b0C at 75% relative humidity to simulate working conditions for materials used in water sorption-based low-T heat storage and reallocation applications. The materials were characterized by powder X-ray diffraction, N2 physisorption, and Nuclear Magnetic Resonance and Infrared spectroscopies before and after the cycling tests. The results showed that the structure of MIL-110(Al) lost its crystallinity and porosity under the tested conditions, while MIL-96(Al) and MIL-100(Al) exhibited excellent hydrothermal stability. The selection of structures, which comprise the same type of metal and ligand, enabled us to attribute the differences in stability primarily to the known variances in secondary building units and the shielding of potential water coordination sites due to the differences in pore accessibility for water molecules. Additionally, our results revealed that water adsorption and desorption at tested conditions (T, RH) is very slow for all three materials, being most pronounced for the MIL-100(Al) structure.<\/jats:p>","DOI":"10.3390\/nano12122092","type":"journal-article","created":{"date-parts":[[2022,6,19]],"date-time":"2022-06-19T10:14:52Z","timestamp":1655633692000},"page":"2092","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["New Insight into Sorption Cycling Stability of Three Al-Based MOF Materials in Water Vapour"],"prefix":"10.3390","volume":"12","author":[{"given":"Tadeja Birsa","family":"\u010celi\u010d","sequence":"first","affiliation":[{"name":"National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4114-1374","authenticated-orcid":false,"given":"Alja\u017e","family":"\u0160krjanc","sequence":"additional","affiliation":[{"name":"National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia"},{"name":"School of Science, University of Nova Gorica, Vipavska 13, 5000 Nova Gorica, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1919-8371","authenticated-orcid":false,"given":"Juan Manuel","family":"Coronado","sequence":"additional","affiliation":[{"name":"IMDEA Energy Institute, Avenida Ram\u00f3n de la Sagra, 3, Parque Tecnol\u00f3gico de M\u00f3stoles, M\u00f3stoles, 28935 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Toma\u017e","family":"\u010cendak","sequence":"additional","affiliation":[{"name":"National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5762-4787","authenticated-orcid":false,"given":"Victor Antonio","family":"de la Pe\u00f1a O\u2019Shea","sequence":"additional","affiliation":[{"name":"IMDEA Energy Institute, Avenida Ram\u00f3n de la Sagra, 3, Parque Tecnol\u00f3gico de M\u00f3stoles, M\u00f3stoles, 28935 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David Pedro","family":"Serrano","sequence":"additional","affiliation":[{"name":"IMDEA Energy Institute, Avenida Ram\u00f3n de la Sagra, 3, Parque Tecnol\u00f3gico de M\u00f3stoles, M\u00f3stoles, 28935 Madrid, Spain"},{"name":"Chemical and Environmental Engineering Group, Rey Juan Carlos University, C. Tulip\u00e1n, s\/n, M\u00f3stoles, 28933 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8972-0087","authenticated-orcid":false,"given":"Nata\u0161a","family":"Zabukovec Logar","sequence":"additional","affiliation":[{"name":"National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia"},{"name":"School of Science, University of Nova Gorica, Vipavska 13, 5000 Nova Gorica, Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,6,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3104","DOI":"10.1039\/C7CS90049J","article-title":"The New Age of MOFs and of Their Porous-Related Solids","volume":"46","author":"Maurin","year":"2017","journal-title":"Chem. Soc. 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