{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T04:49:47Z","timestamp":1793076587952,"version":"4.5.0"},"reference-count":59,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2022,11,27]],"date-time":"2022-11-27T00:00:00Z","timestamp":1669507200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Key Research and Development Program of China","award":["2019YFE0121800"],"award-info":[{"award-number":["2019YFE0121800"]}]},{"name":"National Key Research and Development Program of China","award":["2021YFF0603500"],"award-info":[{"award-number":["2021YFF0603500"]}]},{"name":"National Key Research and Development Program of China","award":["61705070"],"award-info":[{"award-number":["61705070"]}]},{"name":"National Key Research and Development Program of China","award":["11974266"],"award-info":[{"award-number":["11974266"]}]},{"name":"National Key Research and Development Program of China","award":["62075174"],"award-info":[{"award-number":["62075174"]}]},{"name":"National Key Research and Development Program of China","award":["11704293"],"award-info":[{"award-number":["11704293"]}]},{"name":"National Key Research and Development Program of China","award":["WUT:2021VA056"],"award-info":[{"award-number":["WUT:2021VA056"]}]},{"name":"National Natural Science Foundation of China","award":["2019YFE0121800"],"award-info":[{"award-number":["2019YFE0121800"]}]},{"name":"National Natural Science Foundation of China","award":["2021YFF0603500"],"award-info":[{"award-number":["2021YFF0603500"]}]},{"name":"National Natural Science Foundation of China","award":["61705070"],"award-info":[{"award-number":["61705070"]}]},{"name":"National Natural Science Foundation of China","award":["11974266"],"award-info":[{"award-number":["11974266"]}]},{"name":"National Natural Science Foundation of China","award":["62075174"],"award-info":[{"award-number":["62075174"]}]},{"name":"National Natural Science Foundation of China","award":["11704293"],"award-info":[{"award-number":["11704293"]}]},{"name":"National Natural Science Foundation of China","award":["WUT:2021VA056"],"award-info":[{"award-number":["WUT:2021VA056"]}]},{"name":"Fundamental Research Funds for the Central Universities","award":["2019YFE0121800"],"award-info":[{"award-number":["2019YFE0121800"]}]},{"name":"Fundamental Research Funds for the Central Universities","award":["2021YFF0603500"],"award-info":[{"award-number":["2021YFF0603500"]}]},{"name":"Fundamental Research Funds for the Central Universities","award":["61705070"],"award-info":[{"award-number":["61705070"]}]},{"name":"Fundamental Research Funds for the Central Universities","award":["11974266"],"award-info":[{"award-number":["11974266"]}]},{"name":"Fundamental Research Funds for the Central Universities","award":["62075174"],"award-info":[{"award-number":["62075174"]}]},{"name":"Fundamental Research Funds for the Central Universities","award":["11704293"],"award-info":[{"award-number":["11704293"]}]},{"name":"Fundamental Research Funds for the Central Universities","award":["WUT:2021VA056"],"award-info":[{"award-number":["WUT:2021VA056"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>Two-dimensional (2D) organic\u2212inorganic perovskites have great potential for the fabrication of next-generation photodetectors owing to their outstanding optoelectronic features, but their utilization has encountered a bottleneck in anisotropic carrier transportation induced by the unfavorable continuity of the thin films. We propose a facile approach for the fabrication of 0D ZnO quantum dot (QD)\/2D (PEA)2PbI4 nanosheet hybrid photodetectors under the atmospheric conditions associated with the ZnO QD chloroform antisolvent. Profiting from the antisolvent, the uniform morphology of the perovskite thin films is obtained owing to the significantly accelerated nucleation site formation and grain growth rates, and ZnO QDs homogeneously decorate the surface of (PEA)2PbI4 nanosheets, which spontaneously passivate the defects on perovskites and enhance the carrier separation by the well-matched band structure. By varying the ZnO QD concentration, the Ion\/Ioff ratio of the photodetectors radically elevates from 78.3 to 1040, and a 12-fold increase in the normalized detectivity is simultaneously observed. In addition, the agglomeration of perovskite grains is governed by the annealing temperature, and the photodetector fabricated at a relatively low temperature of 120 \u00b0C exhibits excellent stability after a 50-cycle test in the air condition without any encapsulation.<\/jats:p>","DOI":"10.3390\/nano12234217","type":"journal-article","created":{"date-parts":[[2022,11,28]],"date-time":"2022-11-28T04:56:25Z","timestamp":1669611385000},"page":"4217","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["High Performance 0D ZnO Quantum Dot\/2D (PEA)2PbI4 Nanosheet Hybrid Photodetectors Fabricated via a Facile Antisolvent Method"],"prefix":"10.3390","volume":"12","author":[{"given":"Shijie","family":"Liu","sequence":"first","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Li","sequence":"additional","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haifei","family":"Lu","sequence":"additional","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanran","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyan","family":"Wen","sequence":"additional","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuo","family":"Deng","sequence":"additional","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4812-8604","authenticated-orcid":false,"given":"Ming-Yu","family":"Li","sequence":"additional","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sisi","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Science, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2863-0309","authenticated-orcid":false,"given":"Cong","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Electronics and Information Engineering, Harbin Institute of Technology, Harbin 150001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Li","sequence":"additional","affiliation":[{"name":"Hisense Visual Technology Co., Ltd., Qingdao 266555, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"9900","DOI":"10.1109\/JSEN.2021.3054475","article-title":"Design and Modeling of High-Performance DBR-Based Resonant-Cavity-Enhanced GeSn Photodetector for Fiber-Optic Telecommunication Networks","volume":"21","author":"Ghosh","year":"2021","journal-title":"IEEE Sens. J."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1901657","DOI":"10.1002\/admi.201901657","article-title":"Flexible Photodetector Based on 2D Materials: Processing, Architectures, and Applications","volume":"7","author":"Dong","year":"2020","journal-title":"Adv. Mater. Interfaces"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"19024","DOI":"10.1364\/OE.421857","article-title":"Avalanche Photodetectors with Photon Trapping Structures for Biomedical Imaging Applications","volume":"29","author":"Chandiparsi","year":"2021","journal-title":"Opt. Express"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"104630","DOI":"10.1016\/j.nanoen.2020.104630","article-title":"Enhanced Performances of P-Si\/N-ZnO Self-Powered Photodetector by Interface State Modification and Pyro-Phototronic Effect","volume":"71","author":"Zhang","year":"2020","journal-title":"Nano Energy"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"1909909","DOI":"10.1002\/adfm.201909909","article-title":"Recent Progress of Heterojunction Ultraviolet Photodetectors: Materials, Integrations, and Applications","volume":"30","author":"Chen","year":"2020","journal-title":"Adv. Funct. Mater."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"56358","DOI":"10.1021\/acsami.1c19323","article-title":"Defect Passivation via Additive Engineering to Improve Photodetection Performance in CsPbI2Br Perovskite Photodetectors","volume":"13","author":"Li","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"6326","DOI":"10.1039\/D0TC00922A","article-title":"Perovskite CsPbBr3 Crystals: Growth and Applications","volume":"8","author":"Yu","year":"2020","journal-title":"J. Mater. Chem. C"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"2000776","DOI":"10.1002\/advs.202000776","article-title":"Gradient 2D\/3D Perovskite Films Prepared by Hot-Casting for Sensitive Photodetectors","volume":"7","author":"Loi","year":"2020","journal-title":"Adv. Sci."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"382","DOI":"10.1021\/acs.nanolett.0c03759","article-title":"High-Performance Two-Dimensional Perovskite ca2Nb3O10 UV Photodetectors","volume":"21","author":"Zhang","year":"2020","journal-title":"Nano Lett."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"067802","DOI":"10.1088\/1674-1056\/abe92b","article-title":"Low-Dimensional Phases Engineering for Improving the Emission Efficiency and Stability of Quasi-2D Perovskite Films*","volume":"30","author":"Wang","year":"2021","journal-title":"Chin. Phys. B"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"135997","DOI":"10.1016\/j.cej.2022.135997","article-title":"One-Step Anti-Solvent Associated Method for High Performance Two-Dimensional Perovskite Photodetectors Fabrication at Low Temperature","volume":"441","author":"Yue","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"5196","DOI":"10.1038\/s41467-018-07656-2","article-title":"Layer-Edge Device of Two-Dimensional Hybrid Perovskites","volume":"9","author":"Cheng","year":"2018","journal-title":"Nat. Commun."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"20122","DOI":"10.1039\/D0TA06646J","article-title":"Chemical Vapor Deposited Polymer Layer for Efficient Passivation of Planar Perovskite Solar Cells","volume":"8","author":"Trouillet","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1903030","DOI":"10.1002\/adma.201903030","article-title":"Lasing from Mechanically Exfoliated 2D Homologous Ruddlesden\u2013Popper Perovskite Engineered by Inorganic Layer Thickness","volume":"31","author":"Liang","year":"2019","journal-title":"Adv. Mater."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"138806","DOI":"10.1016\/j.tsf.2021.138806","article-title":"Controlled Solution-Based Fabrication of Perovskite Thin Films Directly on Conductive Substrate","volume":"733","author":"Zanca","year":"2021","journal-title":"Thin Solid Film."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"100213","DOI":"10.1016\/j.mtadv.2022.100213","article-title":"Electrochemical Characterization of Halide Perovskites: Stability & Doping","volume":"13","author":"Jha","year":"2022","journal-title":"Mater. Today Adv."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"2100993","DOI":"10.1002\/solr.202100993","article-title":"Electrodeposition as a Versatile Preparative Tool for Perovskite Photovoltaics: Aspects of Metallization and Selective Contacts\/Active Layer Formation","volume":"6","author":"Dini","year":"2022","journal-title":"Sol. RRL"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1002\/eem2.12043","article-title":"Scalable Deposition Methods for Large-Area Production of Perovskite Thin Films","volume":"2","author":"Swartwout","year":"2019","journal-title":"Energy Environ. Mater."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"3985","DOI":"10.1021\/acsnano.1c09513","article-title":"Two-Dimensional Cs2AgBiBr6\/WS2 Heterostructure-Based Photodetector with Boosted Detectivity via Interfacial Engineering","volume":"16","author":"Fang","year":"2022","journal-title":"ACS Nano"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1021\/acsaelm.9b00705","article-title":"High-Performance Photodetector Based on a Graphene Quantum Dot\/CH3NH3PbI3 Perovskite Hybrid","volume":"2","author":"Subramanian","year":"2019","journal-title":"ACS Appl. Electron. Mater."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"162570","DOI":"10.1016\/j.jallcom.2021.162570","article-title":"High Performance Hybrid MXene Nanosheet\/CsPbBr3 Quantum Dot Photodetectors with an Excellent Stability","volume":"895","author":"Li","year":"2022","journal-title":"J. Alloys Compd."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"474","DOI":"10.1016\/j.electacta.2019.03.077","article-title":"Single-Crystal-like ZnO Mesoporous Spheres Derived from Metal Organic Framework Delivering High Electron Mobility for Enhanced Energy Conversion and Storage Performances","volume":"305","author":"Wu","year":"2019","journal-title":"Electrochim. Acta"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"6134","DOI":"10.1039\/C9TA00230H","article-title":"Enhanced Performance of ZnO Nanoparticle Decorated All-Inorganic CsPbBr3 Quantum Dot Photodetectors","volume":"7","author":"Shen","year":"2019","journal-title":"J. Mater. Chem. A"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"152352","DOI":"10.1016\/j.apsusc.2021.152352","article-title":"High Performance ZnO Quantum Dot (QD)\/ Magnetron Sputtered ZnO Homojunction Ultraviolet Photodetectors","volume":"582","author":"Li","year":"2022","journal-title":"Appl. Surf. Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1609","DOI":"10.1007\/s12274-020-3050-z","article-title":"Space-Confined Growth of Metal Halide Perovskite Crystal Films","volume":"14","author":"Li","year":"2020","journal-title":"Nano Res."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"124959","DOI":"10.1016\/j.cej.2020.124959","article-title":"Controlled Crystallinity and Morphologies of 2D Ruddlesden-Popper Perovskite Films Grown without Anti-Solvent for Solar Cells","volume":"394","author":"Huang","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1181","DOI":"10.1039\/D0CE01469A","article-title":"Exploration of Two-Dimensional Perovskites Incorporating Methylammonium for High Performance Solar Cells","volume":"23","author":"Jung","year":"2021","journal-title":"CrystEngComm"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"40","DOI":"10.1016\/j.matchemphys.2017.09.049","article-title":"Green Synthesis, Characterization and Antimicrobial Activity of Zinc Oxide Quantum Dots Using Eclipta Alba","volume":"203","author":"Singh","year":"2018","journal-title":"Mater. Chem. Phys."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"4252","DOI":"10.1002\/anie.201701134","article-title":"Ultrathin Two-Dimensional Organic-Inorganic Hybrid Perovskite Nanosheets with Bright, Tunable Photoluminescence and High Stability","volume":"56","author":"Yang","year":"2017","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1080\/15275922.2013.781080","article-title":"Identification of Chrome Pigments in Paints with Fourier Transform Infrared Spectroscopy (FTIR), Confocal Raman Microscopy, and Scanning Electron Microscope-Energy Dispersive Spectrometer","volume":"14","author":"Lan","year":"2013","journal-title":"Environ. Forensics"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"12026","DOI":"10.1007\/s10854-022-08163-3","article-title":"Optical Absorption and Light-Generated Current Density in Chemically Deposited Antimony Sulfide Selenide Thin Films Used for Solar Cell Development","volume":"33","author":"Messina","year":"2022","journal-title":"J. Mater. Sci. Mater. Electron."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"8058","DOI":"10.1039\/C9TA14207J","article-title":"Enhanced Stability of \u03b1-Phase FAPbI3 Perovskite Solar Cells by Insertion of 2D (PEA)2PbI4 Nanosheets","volume":"8","author":"Hu","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"2693","DOI":"10.1039\/C5NR06687E","article-title":"Crystallization of a Perovskite Film for Higher Performance Solar Cells by Controlling Water Concentration in Methyl Ammonium Iodide Precursor Solution","volume":"8","author":"Adhikari","year":"2016","journal-title":"Nanoscale"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"2005626","DOI":"10.1002\/smll.202005626","article-title":"Ultrathin Single-Crystalline 2D Perovskite Photoconductor for High-Performance Narrowband and Wide Linear Dynamic Range Photodetection","volume":"16","author":"Tu","year":"2020","journal-title":"Small"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"1805409","DOI":"10.1002\/adma.201805409","article-title":"Organic\u2013Inorganic Hybrid Passivation Enables Perovskite QLEDs with an EQE of 16.48%","volume":"30","author":"Song","year":"2018","journal-title":"Adv. Mater."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"656","DOI":"10.1016\/j.apsusc.2018.08.211","article-title":"Tunable Photoluminescence of CsPbBr3 Perovskite Quantum Dots for Their Physical Research","volume":"465","author":"Chen","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"6224","DOI":"10.1039\/C7TC01611E","article-title":"Insight into the Effect of Ligand-Exchange on Colloidal CsPbBr3 Perovskite Quantum Dot\/Mesoporous-TiO2 Composite-Based Photodetectors: Much Faster Electron Injection","volume":"5","author":"Zhou","year":"2017","journal-title":"J. Mater. Chem. C"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"7913","DOI":"10.1039\/C9NR00967A","article-title":"Neutral and Defect-Induced Exciton Annihilation in Defective Monolayer WS2","volume":"11","author":"Liu","year":"2019","journal-title":"Nanoscale"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"15812","DOI":"10.1021\/acsami.8b00940","article-title":"Color-Tunable ZnO\/GaN Heterojunction LEDs Achieved by Coupling with Ag Nanowire Surface Plasmons","volume":"10","author":"Yang","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"2259","DOI":"10.1016\/j.cclet.2020.12.052","article-title":"Graded Interface Engineering of 3D\/2D Halide Perovskite Solar Cells through Ultrathin (PEA)2PbI4 Nanosheets","volume":"32","author":"Zhu","year":"2021","journal-title":"Chin. Chem. Lett."},{"key":"ref_41","doi-asserted-by":"crossref","unstructured":"Lee, S.-W., Cha, S.-H., Choi, K.-J., Kang, B.-H., Lee, J.-S., Kim, S.-W., Kim, J.-S., Jeong, H.-M., Gopalan, S.-A., and Kwon, D.-H. (2016). Low Dark-Current, High Current-Gain of PVK\/ZnO Nanoparticles Composite-Based UV Photodetector by PN-Heterojunction Control. Sensors, 16.","DOI":"10.3390\/s16010074"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"6285","DOI":"10.1021\/nn1022878","article-title":"Enhancing Sensitivity of a Single ZnO Micro-\/Nanowire Photodetector by Piezo-Phototronic Effect","volume":"4","author":"Yang","year":"2010","journal-title":"ACS Nano"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1665","DOI":"10.1126\/science.1176706","article-title":"High-Detectivity Polymer Photodetectors with Spectral Response from 300 nm to 1450 nm","volume":"325","author":"Gong","year":"2009","journal-title":"Science"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1901767","DOI":"10.1002\/smll.201901767","article-title":"Growth of Ultraflat PbI2 Nanoflakes by Solvent Evaporation Suppression for High-Performance UV Photodetectors","volume":"15","author":"Xiao","year":"2019","journal-title":"Small"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"18508","DOI":"10.1039\/C4TA04007D","article-title":"Understanding the Formation and Evolution of Interdiffusion Grown Organolead Halide Perovskite Thin Films by Thermal Annealing","volume":"2","author":"Bi","year":"2014","journal-title":"J. Mater. Chem. A"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1617","DOI":"10.1002\/adfm.200500211","article-title":"Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology","volume":"15","author":"Ma","year":"2005","journal-title":"Adv. Funct. Mater."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"1301287","DOI":"10.1002\/aenm.201301287","article-title":"Benign Solutions and Innovative Sequential Annealing Processes for High Performance Cu2ZnSn(Se,S)4Photovoltaics","volume":"4","author":"Hsu","year":"2013","journal-title":"Adv. Energy Mater."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"6906","DOI":"10.1002\/adma.201601105","article-title":"Improving the Stability and Performance of Perovskite Light-Emitting Diodes by Thermal Annealing Treatment","volume":"28","author":"Yu","year":"2016","journal-title":"Adv. Mater."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"510","DOI":"10.1016\/j.ssc.2009.01.014","article-title":"Photoluminescence and Photoconducting Properties of ZnO Nanoparticles","volume":"149","author":"Vivekchand","year":"2009","journal-title":"Solid State Commun."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"721","DOI":"10.1002\/jrs.2511","article-title":"Improved Surface-Enhanced Raman Scattering Properties of TiO2Nanoparticles by Zn Dopant","volume":"41","author":"Yang","year":"2009","journal-title":"J. Raman Spectrosc."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"2244","DOI":"10.1007\/s12274-016-1413-2","article-title":"High-Performance UV\u2013Vis Photodetectors Based on Electrospun ZnO Nanofiber-Solution Processed Perovskite Hybrid Structures","volume":"10","author":"Cao","year":"2017","journal-title":"Nano Res."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"5622","DOI":"10.1002\/smll.201602366","article-title":"Improving All-Inorganic Perovskite Photodetectors by Preferred Orientation and Plasmonic Effect","volume":"12","author":"Dong","year":"2016","journal-title":"Small"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1800060","DOI":"10.1002\/lpor.201800060","article-title":"Exploring a Polar Two-Dimensional Multi-Layered Hybrid Perovskite of (C5H11NH3)2(CH3NH3)Pb2I7 for Ultrafast-Responding Photodetection","volume":"12","author":"Han","year":"2018","journal-title":"Laser Photonics Rev."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"3781","DOI":"10.1021\/acs.jpclett.5b01666","article-title":"CH3NH3PbCl3 Single Crystals: Inverse Temperature Crystallization and Visible-Blind UV-Photodetector","volume":"6","author":"Maculan","year":"2015","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"8419","DOI":"10.1021\/acsami.8b20538","article-title":"High-Performance Photodetectors Based on Lead-Free 2D Ruddlesden\u2013Popper Perovskite\/MoS2 Heterostructures","volume":"11","author":"Fang","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"2003145","DOI":"10.1002\/smll.202003145","article-title":"(Frank) 2D Perovskite Single Crystals with Suppressed Ion Migration for High-Performance Planar-Type Photodetectors","volume":"16","author":"Zhang","year":"2020","journal-title":"Small"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"679","DOI":"10.1038\/nphoton.2015.156","article-title":"Highly Narrowband Perovskite Single-Crystal Photodetectors Enabled by Surface-Charge Recombination","volume":"9","author":"Fang","year":"2015","journal-title":"Nat. Photonics"},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1021\/jacs.9b10919","article-title":"Trilayered Lead Chloride Perovskite Ferroelectric Affording Self-Powered Visible-Blind Ultraviolet Photodetection with Large Zero-Bias Photocurrent","volume":"142","author":"Wang","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"ref_59","first-page":"1168","article-title":"Orthogonal Lithography for Halide Perovskite Optoelectronic Nanodevices","volume":"13","author":"Lin","year":"2018","journal-title":"ACS Nano"}],"container-title":["Nanomaterials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2079-4991\/12\/23\/4217\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:27:47Z","timestamp":1760146067000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2079-4991\/12\/23\/4217"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,27]]},"references-count":59,"journal-issue":{"issue":"23","published-online":{"date-parts":[[2022,12]]}},"alternative-id":["nano12234217"],"URL":"https:\/\/doi.org\/10.3390\/nano12234217","relation":{},"ISSN":["2079-4991"],"issn-type":[{"value":"2079-4991","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,27]]}}}