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Although magnesium alloys are widely used in the automotive and aerospace industries, severe corrosion issues still hinder their long-term service in naval architecture. In the present work, an epoxy composite coating containing sericite nanosheets is prepared on the AZ31B Mg alloy using a one-step electrophoretic deposition method to improve corrosion resistance. Due to the polyetherimide (PEI) modification, positively charged sericite nanosheets can be highly orientated in an epoxy coating under the influence of an electric field. The sericite-incorporated epoxy coating prepared in the emulsion with 4 wt.% sericite exhibits the highest corrosion resistance, with its corrosion current density being 6 orders of magnitude lower than that of the substrate. Electrochemical measurements and immersion tests showed that the highly orientated sericite nanosheets in the epoxy coating have an excellent barrier effect against corrosive media, thus significantly improving the long-term anti-corrosion performance of the epoxy coating. This work provides new insight into the design of lamellar filler\/epoxy coatings with superior anticorrosion performance and shows promise in the corrosion protection of magnesium alloys.<\/jats:p>","DOI":"10.3390\/nano13162310","type":"journal-article","created":{"date-parts":[[2023,8,11]],"date-time":"2023-08-11T10:33:23Z","timestamp":1691750003000},"page":"2310","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Highly Orientated Sericite Nanosheets in Epoxy Coating for Excellent Corrosion Protection of AZ31B Mg Alloy"],"prefix":"10.3390","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8277-9289","authenticated-orcid":false,"given":"Hao","family":"Wu","sequence":"first","affiliation":[{"name":"Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, Guangzhou Maritime University, Guangzhou 510725, China"},{"name":"School of Naval Architecture and Ocean Engineering, Guangzhou Maritime University, Guangzhou 510725, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ke","family":"Xi","sequence":"additional","affiliation":[{"name":"School of Mechanical and Automobile Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-8991-7690","authenticated-orcid":false,"given":"Yan","family":"Huang","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, Guangzhou Maritime University, Guangzhou 510725, China"},{"name":"School of Naval Architecture and Ocean Engineering, Guangzhou Maritime University, Guangzhou 510725, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zena","family":"Zheng","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, Guangzhou Maritime University, Guangzhou 510725, China"},{"name":"School of Naval Architecture and Ocean Engineering, Guangzhou Maritime University, Guangzhou 510725, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenghua","family":"Wu","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, Guangzhou Maritime University, Guangzhou 510725, China"},{"name":"School of Naval Architecture and Ocean Engineering, Guangzhou Maritime University, Guangzhou 510725, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruolin","family":"Liu","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, Guangzhou Maritime University, Guangzhou 510725, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3105-6205","authenticated-orcid":false,"given":"Chilou","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Mechanical and Automobile Engineering, South China University of Technology, Guangzhou 510641, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Xu","sequence":"additional","affiliation":[{"name":"Guangdong Institute of Special Equipment Inspection and Research, Foshan 510655, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Du","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, Guangzhou Maritime University, Guangzhou 510725, China"},{"name":"School of Naval Architecture and Ocean Engineering, Guangzhou Maritime University, Guangzhou 510725, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yansheng","family":"Yin","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, Guangzhou Maritime University, Guangzhou 510725, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,8,11]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"294","DOI":"10.1038\/nature11475","article-title":"Opportunities and challenges for a sustainable energy future","volume":"488","author":"Chu","year":"2012","journal-title":"Nature"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"92","DOI":"10.1016\/j.pmatsci.2017.04.011","article-title":"Fundamentals and advances in magnesium alloy corrosion","volume":"89","author":"Esmaily","year":"2017","journal-title":"Prog. Mater. Sci."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"4331","DOI":"10.1021\/acsbiomaterials.9b00456","article-title":"One-Pot but Two-Step Vapor-Based Amine- and Fluorine-Bearing Dual-Layer Coating for Improving Anticorrosion and Biocompatibility of Magnesium Alloy","volume":"5","author":"Yu","year":"2019","journal-title":"ACS Biomater. Sci. Eng."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"109924","DOI":"10.1016\/j.corsci.2021.109924","article-title":"Effect of hierarchical precipitates on corrosion behavior of fine-grain magnesium-gadolinium-silver alloy","volume":"194","author":"Xu","year":"2022","journal-title":"Corros. Sci."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1016\/j.corsci.2018.12.025","article-title":"Unveiling the inhibition mechanism of an effective inhibitor for AZ91 Mg alloy","volume":"148","author":"Lu","year":"2019","journal-title":"Corros. Sci."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"1876","DOI":"10.1016\/j.jmst.2018.01.015","article-title":"Electrochemical noise analysis on the pit corrosion susceptibility of biodegradable AZ31 magnesium alloy in four types of simulated body solutions","volume":"34","author":"Wang","year":"2018","journal-title":"J. Mater. Sci. Technol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"379","DOI":"10.1016\/j.surfcoat.2018.01.022","article-title":"Formation of self-lubricating PEO coating via in-situ incorporation of PTFE particles","volume":"337","author":"Chen","year":"2018","journal-title":"Surf. Coat. Technol."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"127699","DOI":"10.1016\/j.colsurfa.2021.127699","article-title":"Preparation of corrosion-resistant MgAl-LDH\/Ni composite coating on Mg alloy AZ31B","volume":"632","author":"Song","year":"2022","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"110","DOI":"10.1016\/j.porgcoat.2013.08.008","article-title":"A hybrid polyacrylate\/OMMT nanocomposite latex: Synthesis, characterization and its application as a coating binder","volume":"77","author":"Yilmaz","year":"2014","journal-title":"Prog. Org. Coat."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"3514","DOI":"10.1016\/j.corsci.2007.03.018","article-title":"Electrochemical and structural properties of a polyurethane coating on steel substrates for corrosion protection","volume":"49","author":"Souto","year":"2007","journal-title":"Corros. Sci."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"18400","DOI":"10.1021\/acsami.8b01982","article-title":"Cationic Reduced Graphene Oxide as Self-Aligned Nanofiller in the Epoxy Nanocomposite Coating with Excellent Anticorrosive Performance and Its High Antibacterial Activity","volume":"10","author":"Luo","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1016\/j.cej.2019.02.032","article-title":"Fabrication of ZnO\/epoxy resin superhydrophobic coating on AZ31 magnesium alloy","volume":"368","author":"Zhou","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"10189","DOI":"10.1021\/acsnano.8b05183","article-title":"Thin Nacre-Biomimetic Coating with Super-Anticorrosion Performance","volume":"12","author":"Zhang","year":"2018","journal-title":"ACS Nano"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"144","DOI":"10.1016\/j.jmst.2020.05.002","article-title":"Amino-functionalized Ti3C2T with anti-corrosive\/wear function for waterborne epoxy coating","volume":"54","author":"Yan","year":"2020","journal-title":"J. Mater. Sci. Technol."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"2093","DOI":"10.1007\/s40843-020-1661-1","article-title":"Advances in layer-by-layer self-assembled coatings upon biodegradable magnesium alloys","volume":"64","author":"He","year":"2021","journal-title":"Sci. China Mater."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"124435","DOI":"10.1016\/j.cej.2020.124435","article-title":"Self-alignment of cationic graphene oxide nanosheets for anticorrosive reinforcement of epoxy coatings","volume":"389","author":"Zhu","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"280","DOI":"10.1016\/j.surfcoat.2011.07.012","article-title":"Effect of polyaniline\u2013montmorillonite nanocomposite powders addition on corrosion performance of epoxy coatings on Al 5000","volume":"206","author":"Hosseini","year":"2011","journal-title":"Surf. Coat. Technol."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"1455","DOI":"10.1016\/j.jmst.2018.03.003","article-title":"Layered double hydroxide coatings on magnesium alloys: A review","volume":"34","author":"Guo","year":"2018","journal-title":"J. Mater. Sci. Technol."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"5763","DOI":"10.1021\/nn4014356","article-title":"Graphene as a long-term metal oxidation barrier: Worse than nothing","volume":"7","author":"Schriver","year":"2013","journal-title":"ACS Nano"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"834","DOI":"10.1038\/nnano.2017.187","article-title":"A cautionary note on graphene anti-corrosion coatings","volume":"12","author":"Cui","year":"2017","journal-title":"Nat. Nanotechnol."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"152693","DOI":"10.1016\/j.apsusc.2022.152693","article-title":"Improved corrosion and wear resistance of micro-arc oxidation coatings on the 2024 aluminum alloy by incorporation of quasi-two-dimensional sericite microplates","volume":"585","author":"Xi","year":"2022","journal-title":"Appl. Surf. Sci."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"110275","DOI":"10.1016\/j.matchar.2020.110275","article-title":"Low cost and efficient synthesis of magnetic iron oxide\/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes","volume":"163","author":"Abdullah","year":"2020","journal-title":"Mater. Charact."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"2974","DOI":"10.1038\/s41467-018-05355-6","article-title":"Transforming ground mica into high-performance biomimetic polymeric mica film","volume":"9","author":"Pan","year":"2018","journal-title":"Nat. Commun."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"282","DOI":"10.1016\/j.clay.2008.09.006","article-title":"Swelling of sericite by LiNO3-hydrothermal treatment","volume":"43","author":"Shih","year":"2009","journal-title":"Appl. Clay Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"480138","DOI":"10.1155\/2014\/480138","article-title":"Preparation and Characterization of Cetyl Trimethylammonium Intercalated Sericite","volume":"2014","author":"Ding","year":"2014","journal-title":"Adv. Mater. Sci. Eng."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1414","DOI":"10.1016\/j.cej.2015.08.072","article-title":"Surface-functionalized activated sericite for the simultaneous removal of cadmium and phenol from aqueous solutions: Mechanistic insights","volume":"283","author":"Lalhmunsiama","year":"2016","journal-title":"Chem. Eng. J."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"088303","DOI":"10.1103\/PhysRevLett.95.088303","article-title":"Influence of Aspect Ratio on Barrier Properties of Polymer-Clay Nanocomposites","volume":"95","author":"Lu","year":"2005","journal-title":"Phys. Rev. Lett."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"1539","DOI":"10.1016\/j.progpolymsci.2003.08.002","article-title":"Polymer\/layered silicate nanocomposites: A review from preparation to processing","volume":"28","author":"Okamoto","year":"2003","journal-title":"Prog. Polym. Sci."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"5552","DOI":"10.1016\/j.apsusc.2011.01.034","article-title":"Organosilane grafted acid-activated beidellite clay for the removal of non-ionic alachlor and anionic imazaquin","volume":"257","author":"Paul","year":"2011","journal-title":"Appl. Surf. Sci."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"50","DOI":"10.1016\/j.jenvman.2014.07.026","article-title":"Cu(II) and Zn(II) adsorption capacity of three different clay liner materials","volume":"146","author":"Musso","year":"2014","journal-title":"J. Environ. Manag."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.clay.2014.05.028","article-title":"Adsorption of arsenic on modified montmorillonite","volume":"97\u201398","author":"Ren","year":"2014","journal-title":"Appl. Clay Sci."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"17617","DOI":"10.1021\/acsami.8b03185","article-title":"Highly Stable Graphene-Based Nanocomposite (GO-PEI-Ag) with Broad-Spectrum, Long-Term Antimicrobial Activity and Antibiofilm Effects","volume":"10","author":"Zhao","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"109256","DOI":"10.1016\/j.corsci.2021.109256","article-title":"Corrosion resistance of a novel ceria doped aluminum phosphate ceramic coating on cast Al-Si alloy by steam-assisted curing","volume":"182","author":"Huang","year":"2021","journal-title":"Corros. Sci."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"402","DOI":"10.1016\/j.corsci.2014.10.041","article-title":"Fabrication and corrosion resistance of a hydrophobic micro-arc oxidation coating on AZ31 Mg alloy","volume":"90","author":"Cui","year":"2015","journal-title":"Corros. Sci."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1016\/S0022-0728(97)00490-7","article-title":"On the electrical capacitance of interfaces exhibiting constant phase element behaviour","volume":"443","author":"Zoltowski","year":"1998","journal-title":"J. Electroanal. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1016\/j.surfcoat.2018.08.043","article-title":"Magnetron-sputtered fluorocarbon polymeric film on magnesium for corrosion protection","volume":"352","author":"Wu","year":"2018","journal-title":"Surf. Coat. Technol."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"126251","DOI":"10.1016\/j.surfcoat.2020.126251","article-title":"Formation of self-layered hydrothermal coating on magnesium aided by titanium ion implantation: Synergistic control of corrosion resistance and cytocompatibility","volume":"401","author":"Wu","year":"2020","journal-title":"Surf. Coat. Technol."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/j.corsci.2013.09.007","article-title":"Plasma modified Mg\u2013Nd\u2013Zn\u2013Zr alloy with enhanced surface corrosion resistance","volume":"78","author":"Wu","year":"2014","journal-title":"Corros. Sci."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"2816","DOI":"10.1016\/j.corsci.2005.01.010","article-title":"Electrochemical behavior of anodized Mg alloy AZ91D in chloride containing aqueous solution","volume":"47","author":"Zhang","year":"2005","journal-title":"Corros. Sci."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1522","DOI":"10.1016\/j.corsci.2011.01.015","article-title":"Degradation behaviour of pure magnesium in simulated body fluids with different concentrations of HCO3","volume":"53","author":"Xin","year":"2011","journal-title":"Corros. Sci."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"38135","DOI":"10.1039\/C7RA04878E","article-title":"A new understanding of the failure of waterborne acrylic coatings","volume":"7","author":"Wan","year":"2017","journal-title":"RSC Adv."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.jallcom.2014.09.168","article-title":"Corrosion characterization of micro-arc oxidization composite electrophoretic coating on AZ31B magnesium alloy","volume":"621","author":"Wang","year":"2015","journal-title":"J. Alloys Compd."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"136","DOI":"10.1016\/j.surfcoat.2017.06.067","article-title":"Preparation of Ca doping ZrO2 coating on NiTi shape memory alloy by cathodic plasma electrolytic deposition and its structure, in-vitro bioactivity and biocompatibility analysis","volume":"325","author":"Wang","year":"2017","journal-title":"Surf. Coat. Technol."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1016\/j.apsusc.2019.01.181","article-title":"Achieving an acid resistant surface on magnesium alloy via bio-inspired design","volume":"478","author":"Wu","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"109581","DOI":"10.1016\/j.compositesb.2021.109581","article-title":"Achieving parallelly-arranged Ti3C2Tx in epoxy coating for anti-corrosive\/wear high-efficiency protection","volume":"231","author":"Fan","year":"2022","journal-title":"Compos. Part. B Eng."}],"container-title":["Nanomaterials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2079-4991\/13\/16\/2310\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:31:36Z","timestamp":1760128296000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2079-4991\/13\/16\/2310"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,8,11]]},"references-count":45,"journal-issue":{"issue":"16","published-online":{"date-parts":[[2023,8]]}},"alternative-id":["nano13162310"],"URL":"https:\/\/doi.org\/10.3390\/nano13162310","relation":{},"ISSN":["2079-4991"],"issn-type":[{"value":"2079-4991","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,8,11]]}}}