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Atomic metal species recently emerged as highly effective catalysts for organic reactions with high activity and metal utilization. However, developing efficient atomic catalysts is always an attractive and challenging topic in the modern chemical industry. In this work, we report the preparation and activity enhancement of nitrogen- and sulfur-codoped holey graphene (NSHG) with the anchoring of atomic metal Pd. When employed as the catalyst for nitroarenes reduction reactions, the resultant Pd\/NSHG composite exhibits remarkably high catalytic activity due to the co-existence of dual-active components (i.e., catalytically active NSHG support and homogeneous dispersion of atomic metal Pd). In the catalytic 4-nitrophenol (4-NP) reduction reaction, the efficiency (turnover frequency) is 3.99 \u00d7 10\u22122 mmol 4-NP\/(mg cat.\u00b7min), which is better than that of metal-free nitrogen-doped holey graphene (NHG) (2.3 \u00d7 10\u22123 mmol 4-NP\/(mg cat.\u00b7min)) and NSHG carbocatalyst (3.8 \u00d7 10\u22123 mmol 4-NP\/(mg cat.\u00b7min)), the conventional Pd\/C and other reported metal-based catalysts. This work provides a rational design strategy for the atomic metal catalysts loaded on active doped graphene support. The resultant Pd\/NSHG dual-active component catalyst (DACC) is also anticipated to bring great application potentials for a broad range of organic fields, such as organic synthesis, environment treatment, energy storage and conversion.<\/jats:p>","DOI":"10.3390\/nano13172434","type":"journal-article","created":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T02:23:25Z","timestamp":1693189405000},"page":"2434","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Probing the Activity Enhancement of Carbocatalyst with the Anchoring of Atomic Metal"],"prefix":"10.3390","volume":"13","author":[{"given":"Zhe","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemistry and Environmental Engineering, Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry, Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430205, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Environmental Engineering, Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry, Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430205, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Environmental Engineering, Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry, Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430205, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jufang","family":"Hao","sequence":"additional","affiliation":[{"name":"Staff Development Institute of China National Tobacco Corporation (CNTC), Zhengzhou 450008, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7882-3689","authenticated-orcid":false,"given":"Jiangbo","family":"Xi","sequence":"additional","affiliation":[{"name":"School of Chemistry and Environmental Engineering, Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry, Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430205, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Xiao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baojiang","family":"He","sequence":"additional","affiliation":[{"name":"Zhengzhou Tobacco Research Institute of China National Tobacco Corporation (CNTC), Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Environmental Engineering, Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry, Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430205, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,8,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2886","DOI":"10.1021\/acscatal.5b00375","article-title":"Nitrogen-Doped, Metal-Free Activated Carbon Catalysts for Aerobic Oxidation of Alcohols","volume":"5","author":"Watanabe","year":"2015","journal-title":"ACS Catal."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"5255","DOI":"10.1039\/D2GC01162J","article-title":"N-Doped Holey Graphene Assembled on Fibrous Aluminum Silicate for Efficient Carbocatalysis in Fixed-Bed Systems","volume":"24","author":"Hu","year":"2022","journal-title":"Green Chem."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"8991","DOI":"10.1039\/C8CC03711F","article-title":"P-Doped Carbons Derived from Cellulose as Highly Efficient Metal-Free Catalysts for Aerobic Oxidation of Benzyl Alcohol in Water Under an Air Atmosphere","volume":"54","author":"Long","year":"2018","journal-title":"Chem. Commun."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.catcom.2015.02.018","article-title":"Sulphur-Doped Graphene as Metal-Free Carbocatalysts for the Solventless Aerobic Oxidation of Styrenes","volume":"65","author":"Dhakshinamoorthy","year":"2015","journal-title":"Catal. Commun."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"233","DOI":"10.1016\/j.jcat.2018.01.003","article-title":"N,P-Dual-Doped Multilayer Graphene as an Efficient Carbocatalyst for Nitroarene Reduction: A Mechanistic Study of Metal-Free Catalysis","volume":"359","author":"Xi","year":"2018","journal-title":"J. Catal."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"5795","DOI":"10.1039\/C8SC01801D","article-title":"Modulating the Oxygen Reduction Activity of Heteroatom-Doped Carbon Catalysts via the Triple Effect: Charge, Spin Density and Ligand Effect","volume":"9","author":"Yang","year":"2018","journal-title":"Chem. Sci."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"1805121","DOI":"10.1002\/adma.201805121","article-title":"Efficient Metal-Free Electrocatalysts from N-doped Carbon Nanomaterials: Mono-Doping and Co-Doping","volume":"31","author":"Gao","year":"2019","journal-title":"Adv. Mater."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"11664","DOI":"10.1002\/ange.201206720","article-title":"Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance","volume":"124","author":"Liang","year":"2012","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1007\/s40820-020-00579-y","article-title":"Defect and Doping Co-Engineered Non-Metal Nanocarbon ORR Electrocatalyst","volume":"13","author":"Zhang","year":"2021","journal-title":"Nano-Micro Lett."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"108","DOI":"10.1016\/j.snb.2018.06.039","article-title":"Multi-Element Doping Design of High-Efficient Carbocatalyst for Electrochemical Sensing of Cancer Cells","volume":"273","author":"Xi","year":"2018","journal-title":"Sensors Actuators B Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"3036","DOI":"10.1002\/smll.201403715","article-title":"Sulfur and Nitrogen Co-Doped Graphene for Metal-Free Catalytic Oxidation Reactions","volume":"11","author":"Duan","year":"2015","journal-title":"Small"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1616","DOI":"10.1016\/j.apsusc.2019.05.144","article-title":"P\/N Co-Doped Carbon Derived from Cellulose: A Metal-Free Photothermal Catalyst for Transfer Hydrogenation of Nitroarenes","volume":"487","author":"Zhang","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"3895","DOI":"10.1039\/D2SE00896C","article-title":"Heteroatom Doped M-N-C Single-Atom Catalysts for High-Efficiency Oxygen Reduction Reaction: Regulation of Coordination Configurations","volume":"6","author":"Zha","year":"2020","journal-title":"Sustain. Energy Fuels"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"2765","DOI":"10.1002\/cctc.201500350","article-title":"Metal-Free Carbonaceous Materials as Promising Heterogeneous Catalysts","volume":"7","author":"Liu","year":"2015","journal-title":"ChemCatChem"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"3550","DOI":"10.1002\/smll.201200861","article-title":"Nanostructured Metal-Free Electrochemical Catalysts for Highly Efficient Oxygen Reduction","volume":"8","author":"Zheng","year":"2012","journal-title":"Small"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"768","DOI":"10.1126\/science.1170335","article-title":"N-Doping of Graphene through Electrothermal Reactions with Ammonia","volume":"324","author":"Wang","year":"2009","journal-title":"Science"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1016\/j.jcat.2019.07.017","article-title":"Metal-Free Carbocatalyst for Catalytic Hydrogenation of N-Containing Unsaturated Compounds","volume":"377","author":"He","year":"2019","journal-title":"J. Catal."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"15939","DOI":"10.1021\/ja907098f","article-title":"Simultaneous Nitrogen Doping and Reduction of Graphene Oxide","volume":"131","author":"Li","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1360","DOI":"10.6023\/A21070340","article-title":"Graphene-derived Materials for Metal-free Carbocatalysis of Organic Reactions","volume":"79","author":"Huang","year":"2021","journal-title":"Acta Chim. Sin."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1016\/j.carbon.2017.06.046","article-title":"Soft Template-Assisted Method for Synthesis of Nitrogen and Sulfur Co-Doped Three-Dimensional Reduced Graphene Oxide as an Efficient Metal Free Catalyst for Oxygen Reduction Reaction","volume":"122","author":"Li","year":"2017","journal-title":"Carbon"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"5549","DOI":"10.1039\/c2nr31467c","article-title":"Three-Dimensional Graphene Architectures","volume":"4","author":"Li","year":"2012","journal-title":"Nanoscale"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"2376","DOI":"10.1039\/c000051e","article-title":"A pH-Sensitive Graphene Oxide Composite Hydrogel","volume":"46","author":"Bai","year":"2010","journal-title":"Chem. Commun."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"4324","DOI":"10.1021\/nn101187z","article-title":"Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process","volume":"4","author":"Xu","year":"2010","journal-title":"ACS Nano"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"1477","DOI":"10.1007\/s12274-014-0508-x","article-title":"Three-Dimensional Porous Graphene Sponges Assembled with The Combination of Surfactant and Freeze-Drying","volume":"7","author":"Zhang","year":"2014","journal-title":"Nano Res."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"7103","DOI":"10.1021\/nn3021772","article-title":"Strong, Conductive, Lightweight, Neat Graphene Aerogel Fibers with Aligned Pores","volume":"6","author":"Xu","year":"2012","journal-title":"ACS Nano"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"11810","DOI":"10.1021\/acs.chemrev.0c00094","article-title":"Surface Coordination Chemistry of Atomically Dispersed Metal Catalysts","volume":"120","author":"Qin","year":"2020","journal-title":"Chem. Rev."},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Qi, Z., Zhou, Y., Guan, R., Fu, Y., and Baek, J.B. (2023). Tuning the Coordination Environment of Carbon-Based Single-Atom Catalysts via Doping with Multiple Heteroatoms and Their Applications in Electrocatalysis. Adv. Mater., 2210575.","DOI":"10.1002\/adma.202210575"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"2963","DOI":"10.1038\/s41467-022-30702-z","article-title":"Iron Atom-Cluster Interactions Increase Activity and Improve Durability in Fe-N-C Fuel Cells","volume":"13","author":"Wan","year":"2022","journal-title":"Nat. Commun."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"127637","DOI":"10.1016\/j.fuel.2023.127637","article-title":"Defective N, S Co-Doped Carbon Sphere Supported Pd Catalyst for Selective HydrodeoxygenAtion of Biomass under Mild Conditions","volume":"341","author":"Kuang","year":"2023","journal-title":"Fuel"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"121029","DOI":"10.1016\/j.apcatb.2021.121029","article-title":"Single Palladium Site in Ordered Porous Heteroatom-Doped Carbon for High-Performance Alkaline Hydrogen Oxidation","volume":"306","author":"Liu","year":"2022","journal-title":"Appl. Catal. B Environ."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"11853","DOI":"10.1021\/acsnano.9b05913","article-title":"Markedly Enhanced Oxygen Reduction Activity of Single-Atom Fe Catalysts via Integration with Fe Nanoclusters","volume":"13","author":"Ao","year":"2019","journal-title":"ACS Nano"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2004855","DOI":"10.1002\/smll.202004855","article-title":"Engineering Atomic Sites via Adjacent Dual-Metal Sub-Nanoclusters for Efficient Oxygen Reduction Reaction and Zn-Air Battery","volume":"16","author":"Qi","year":"2020","journal-title":"Small"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"2001165","DOI":"10.1002\/smtd.202001165","article-title":"Synergies of Fe Single Atoms and Clusters on N-Doped Carbon Electrocatalyst for Ph-Universal Oxygen Reduction","volume":"5","author":"Liu","year":"2021","journal-title":"Small Methods"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"615","DOI":"10.1038\/s41929-021-00650-w","article-title":"Understanding the Inter-Site Distance Effect in Single-Atom Catalysts for Oxygen Electroreduction","volume":"4","author":"Jin","year":"2021","journal-title":"Nat. Catal."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"2107291","DOI":"10.1002\/adma.202107291","article-title":"Electronically and Geometrically Modified Single-Atom Fe Sites by Adjacent Fe Nanoparticles for Enhanced Oxygen Reduction","volume":"34","author":"Zhao","year":"2021","journal-title":"Adv. Mater."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"e202116068","DOI":"10.1002\/anie.202116068","article-title":"Clusters Induced Electron Redistribution to Tune Oxygen Reduction Activity of Transition Metal Single-Atom for Metal-Air Batteries","volume":"61","author":"Huang","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"1339","DOI":"10.1021\/ja01539a017","article-title":"Preparation of Graphitic Oxide","volume":"80","author":"Hummers","year":"1958","journal-title":"J. Am. Chem. Soc."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"4839","DOI":"10.1039\/C4CC00440J","article-title":"One-Pot Synthesis of Nitrogen and Sulfur Co-Doped Graphene as Efficient Metal-Free Electrocatalysts for the Oxygen Reduction Reaction","volume":"50","author":"Wang","year":"2014","journal-title":"Chem. Commun."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"6186","DOI":"10.1002\/adma.201401427","article-title":"Nitrogen and Sulfur Codoped Graphene: Multifunctional Electrode Materials for High Performance Li-Ion Batteries and Oxygen Reduction Reaction","volume":"26","author":"Ai","year":"2014","journal-title":"Adv. Mater."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"70","DOI":"10.1016\/j.jpowsour.2018.10.055","article-title":"Chemically Controlled In-Situ Growth of Cobalt Oxide Microspheres on N, S-Co-Doped Reduced Graphene Oxide as an Efficient Electrocatalyst for Oxygen Reduction Reaction","volume":"407","author":"Khandelwal","year":"2018","journal-title":"J. Power Sources"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"1610","DOI":"10.1002\/adma.201505243","article-title":"Sulfur and Nitrogen Co-Doped Graphene Electrodesfor High-Performance Ionic Artificial Muscles","volume":"28","author":"Kotal","year":"2016","journal-title":"Adv. Mater."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"1936","DOI":"10.1039\/C9CC09514D","article-title":"Tunable One-Step Double Functionalization of Graphene Based on Fluorographene Chemistry","volume":"56","author":"Chronopoulos","year":"2020","journal-title":"Chem. Commun."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"132618","DOI":"10.1016\/j.cej.2021.132618","article-title":"High Acidity- and Radiation-Resistant Triazine-Based POPs for Recovery of Pd(II) From Nuclear Fission Products","volume":"430","author":"Yuan","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"586","DOI":"10.1016\/j.jcis.2022.12.072","article-title":"Importance of Carbon Structure for Nitrogen and Sulfur Co-Doping to Promote Superior Ciprofloxacin Removal via Peroxymonosulfate Activation","volume":"643","author":"Gasim","year":"2023","journal-title":"J. Colloid Interface Sci."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"21904","DOI":"10.1038\/srep21904","article-title":"Mussel-Inspired Functionalization of Cotton for Nano-Catalyst Support and Its Application in a Fixed-Bed System with High Performance","volume":"6","author":"Xi","year":"2016","journal-title":"Sci. Rep."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"326","DOI":"10.1016\/j.carbon.2017.04.039","article-title":"Ultrafine Palladium Nanoparticles Supported on Nitrogen-Doped Carbon Microtubes as a High-Performance Organocatalyst","volume":"119","author":"Duan","year":"2017","journal-title":"Carbon"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"465","DOI":"10.1016\/j.jcis.2017.02.051","article-title":"Distinctive Morphology Effects of Porous-Spherical\/Yolk-Shell\/Hollow Pd-Nitrogen-Doped-Carbon Spheres Catalyst for Catalytic Reduction of 4-Nitrophenol","volume":"496","author":"Long","year":"2017","journal-title":"J. Colloid Interface Sci."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/j.apcatb.2017.11.057","article-title":"Confined-Interface-Directed Synthesis of Palladium Single-Atom Catalysts on Graphene\/Amorphous Carbon","volume":"225","author":"Xi","year":"2018","journal-title":"Appl. Catal. B Environ."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"806","DOI":"10.1016\/j.carbon.2018.01.038","article-title":"Magnetically Recyclable Nanocatalyst with Synergetic Catalytic Effect and Its Application for 4-Nitrophenol Reduction and Suzuki Coupling Reactions","volume":"130","author":"Duan","year":"2018","journal-title":"Carbon"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.jcis.2018.04.008","article-title":"PdCo Nanoparticles Supported on Carbon Fibers Derived from Cotton: Maximum Utilization of Pd Atoms for Efficient Reduction of Nitroarenes","volume":"524","author":"Yang","year":"2018","journal-title":"J. Colloid Interface Sci."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"2696","DOI":"10.1021\/acs.jpcc.7b10237","article-title":"Palladium Nanoparticles Anchored on Amine-Functionalized Silica Nanotubes as a Highly Effective Catalyst","volume":"122","author":"Liu","year":"2018","journal-title":"J. Phys. Chem. C"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"18242","DOI":"10.1039\/C8TA07502F","article-title":"Highly Dispersed Ultrafine Palladium Nanoparticles Encapsulated in a Triazinyl Functionalized Porous Organic Polymer as a Highly Efficient Catalyst for Transfer Hydrogenation of Aldehydes","volume":"6","author":"Yang","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1009","DOI":"10.1016\/j.apsusc.2018.06.285","article-title":"Synthesis of Amorphous PdP Nanoparticles Supported on Carbon Nanospheres for 4-Nitrophenol Reduction in Environmental Applications","volume":"457","author":"Zhao","year":"2018","journal-title":"Appl. Surf. Sci."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"13449","DOI":"10.1039\/C9TA02457C","article-title":"Ultrafine Silver Nanoparticles Supported on A Covalent Carbazole Framework as High-Efficiency Nanocatalysts for Nitrophenol Reduction","volume":"7","author":"Gong","year":"2019","journal-title":"J. Mater. Chem. A"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1016\/j.jhazmat.2019.02.027","article-title":"Palladium Nanoparticles Decorated on Amine Functionalized Graphene Nanosheets as Excellent Nanocatalyst for The Hydrogenation of Nitrophenols to Aminophenol Counterparts","volume":"369","author":"Karatas","year":"2019","journal-title":"J. Hazard. Mater."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"9618","DOI":"10.1039\/C9TA02387A","article-title":"Development of Nickel-Incorporated MCM-41-Carbon Composites and Their Application in Nitrophenol Reduction","volume":"7","author":"Ghimire","year":"2019","journal-title":"J. Mater. Chem. A"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"134013","DOI":"10.1016\/j.scitotenv.2019.134013","article-title":"N-Doped Carbon Coated Mn3O4\/PdCu Nanocomposite as a High-Performance Catalyst for 4-Nitrophenol Reduction","volume":"696","author":"Ma","year":"2019","journal-title":"Sci. Total Environ."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"117942","DOI":"10.1016\/j.apcatb.2019.117942","article-title":"Palladium Clusters Confined in Triazinyl-Functionalized COFs with Enhanced Catalytic Activity","volume":"257","author":"Fan","year":"2019","journal-title":"Appl. Catal. B Environ."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"477","DOI":"10.1016\/j.apsusc.2019.06.039","article-title":"Pd-Fe Dual-Metal Nanoparticles Confined in The Interface of Carbon Nanotubes\/N-Doped Carbon for Excellent Catalytic Performance","volume":"489","author":"Wang","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1016\/j.jcat.2020.08.027","article-title":"Pd\/Mo2N-TiO2 as Efficient Catalysts for Promoted Selective Hydrogenation of 4-Nitrophenol: A Green Bio-Reducing Preparation Method","volume":"391","author":"Tian","year":"2020","journal-title":"J. Catal."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"5208","DOI":"10.1021\/acs.langmuir.0c00526","article-title":"Controlled Synthesis of Palladium Nanocubes as an Efficient Nanocatalyst for Suzuki-Miyaura Cross-Coupling and Reduction of p-Nitrophenol","volume":"36","author":"Swain","year":"2020","journal-title":"Langmuir"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"2998","DOI":"10.1021\/acs.iecr.9b06367","article-title":"Preparation of Highly Uniform Polyurethane Microspheres by Precipitation Polymerization and Pd Immobilization on Their Surface and Their Catalytic Activity in 4-Nitrophenol Reduction and Dye Degradation","volume":"59","author":"Yang","year":"2020","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"1191","DOI":"10.1039\/C9DT04051J","article-title":"A New Cobalt Metal-Organic Framework as a Substrate for Pd Nanoparticles Applied in High-Efficiency Nitro Phenol Degradation and Cinnamaldehyde Hydrogenation","volume":"49","author":"Liu","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"5854","DOI":"10.1021\/acsanm.1c00777","article-title":"Substrate-Assisted Encapsulation of Pd-Fe Bimetal Nanoparticles on Functionalized Silica Nanotubes for Catalytic Hydrogenation of Nitroarenes and Azo Dyes","volume":"4","author":"Zhang","year":"2021","journal-title":"ACS Appl. Nano Mater."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"3443","DOI":"10.1021\/acs.jpclett.1c00373","article-title":"Probing Activity Enhancement of Photothermal Catalyst under Near-Infrared Irradiation","volume":"12","author":"Xi","year":"2021","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"119775","DOI":"10.1016\/j.apcatb.2020.119775","article-title":"Black Phosphorus Hybridizing Produces Electron-Deficient Active Sites on Palladium Nanoparticles for Catalysis","volume":"285","author":"He","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"2446","DOI":"10.1021\/acs.jpcc.0c10441","article-title":"Interfacial Hydroxyl Promotes the Reduction of 4-Nitrophenol by Ag-Based Catalysts Confined in Dendritic Mesoporous Silica Nanospheres","volume":"125","author":"Hu","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"701","DOI":"10.1016\/j.jcis.2020.08.062","article-title":"Simple Fabrication of Bimetallic Platinum-Rhodium Alloyed Nano-Multipods: A Highly Effective and Recyclable Catalyst for Reduction of 4-Nitrophenol and Rhodamine B","volume":"582","author":"Yan","year":"2021","journal-title":"J. Colloid Interface Sci."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"116303","DOI":"10.1016\/j.ces.2020.116303","article-title":"Continuous Flow Reduction of Organic Dyes over Pd-Fe Alloy Based Fibrous Catalyst in a Fixed-Bed System","volume":"231","author":"Xi","year":"2021","journal-title":"Chem. Eng. Sci."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1007\/s42823-022-00404-z","article-title":"Pd-Fe Bimetallic Nanoparticles Anchored on N-Doped Carbon-Modified Graphene for Efficient Catalytic Organic Reactions","volume":"33","author":"Zhang","year":"2023","journal-title":"Carbon Lett."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"1643","DOI":"10.1021\/acssuschemeng.2c04955","article-title":"Pd\/Chitosan Nanoparticle Catalysts Prepared by Solid Mortar Grinding for Hydrogenation of Nitroarenes","volume":"11","author":"Kalvakunta","year":"2023","journal-title":"ACS Substain. Chem. Eng."},{"key":"ref_72","doi-asserted-by":"crossref","unstructured":"Zhao, Y., Wang, P., Hong, X., and Tang, K. (2023). Ni@Pd Core-Shell Nanoparticles with Tunable Comosition Supported on Glycine-Functionalized Hollow Fe3O4@PPy for Tandem Degradation Reduction of 4-Nitrophenol and Toxic Organic Dyes by Hydrogen Generation via Hydrolysis of NaBH4 and NH3BH3. Catal. Lett.","DOI":"10.1007\/s10562-022-04242-6"},{"key":"ref_73","doi-asserted-by":"crossref","unstructured":"Wang, D., Li, Y., Wen, L.S., Xi, J.B., Liu, P., Hanse, T.W., and Li, P. (2023). Ni-Pd-incorporated Fe3O4 Yolk-Shelled Nanospheres as Efficient Magnetically Recyclable Catalysts for Reduction of N-Containing Unsaturated Compounds. Catalysts, 13.","DOI":"10.3390\/catal13010190"},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"156344","DOI":"10.1016\/j.apsusc.2023.156344","article-title":"Defect Anchoring of Atomically Dispersed Pd on Nitrogen-Doped Holey Carbon Nanotube for Catalytic Hydrogenation of Nitroarenes","volume":"615","author":"Huang","year":"2023","journal-title":"Appl. Surf. Sci."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"5634","DOI":"10.1038\/ncomms6634","article-title":"FeOx-Supported Platinum Single-Atom and Pseudo-Single-Atom Catalysts for Chemoselective Hydrogenation of Functionalized Nitroarenes","volume":"5","author":"Wei","year":"2014","journal-title":"Nat. Commun."}],"container-title":["Nanomaterials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2079-4991\/13\/17\/2434\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:40:26Z","timestamp":1760128826000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2079-4991\/13\/17\/2434"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,8,27]]},"references-count":75,"journal-issue":{"issue":"17","published-online":{"date-parts":[[2023,9]]}},"alternative-id":["nano13172434"],"URL":"https:\/\/doi.org\/10.3390\/nano13172434","relation":{},"ISSN":["2079-4991"],"issn-type":[{"value":"2079-4991","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,8,27]]}}}