{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T02:20:35Z","timestamp":1791685235875,"version":"4.3.4"},"reference-count":86,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2024,6,28]],"date-time":"2024-06-28T00:00:00Z","timestamp":1719532800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"the State Key Laboratory of NBC Protection for Civilian","award":["SKLNBC2021-19"],"award-info":[{"award-number":["SKLNBC2021-19"]}]},{"name":"the State Key Laboratory of NBC Protection for Civilian","award":["2022AH010023"],"award-info":[{"award-number":["2022AH010023"]}]},{"name":"Foundation of Education Department of Anhui Province","award":["SKLNBC2021-19"],"award-info":[{"award-number":["SKLNBC2021-19"]}]},{"name":"Foundation of Education Department of Anhui Province","award":["2022AH010023"],"award-info":[{"award-number":["2022AH010023"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>Chemical warfare agents primarily comprise organophosphorus nerve agents, saliva alkaloids, cyanides, and mustard gas. Exposure to these agents can result in severe respiratory effects, including spasms, edema, and increased secretions leading to breathing difficulties and suffocation. Protecting public safety and national security from such threats has become an urgent priority. Porous metal\u2013organic framework (MOF) materials have emerged as promising candidates for the degradation of chemical warfare agents due to their large surface area, tunable pore size distribution, and excellent catalytic performance. Furthermore, combining MOFs with polymers can enhance their elasticity and processability and improve their degradation performance. In this review, we summarize the literature of the past five years on MOF-based composite materials and their effectiveness in degrading chemical warfare agents. Moreover, we discuss key factors influencing their degradation efficiency, such as MOF structure, pore size, and functionalization strategies. Furthermore, we highlight recent developments in the design of MOF\u2013polymer composites, which offer enhanced degradation performance and stability for practical applications in CWA degradation. These composite materials exhibit good performance in degrading chemical warfare agents, playing a crucial role in protecting public safety and maintaining national security. We can expect to see more breakthroughs in the application of metal\u2013organic framework porous materials for degrading chemical warfare agents. It is hoped that these innovative materials will play a positive role in achieving social stability and security.<\/jats:p>","DOI":"10.3390\/nano14131108","type":"journal-article","created":{"date-parts":[[2024,6,28]],"date-time":"2024-06-28T03:42:30Z","timestamp":1719546150000},"page":"1108","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Research Progress in the Degradation of Chemical Warfare Agent Simulants Using Metal\u2013Organic Frameworks"],"prefix":"10.3390","volume":"14","author":[{"given":"Taotao","family":"Huang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma\u2019anshan 243032, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma\u2019anshan 243032, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of NBC Protection for Civilian, Beijing 102205, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5634-9952","authenticated-orcid":false,"given":"Kui","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma\u2019anshan 243032, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,6,28]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/j.toxlet.2017.11.040","article-title":"Chemical warfare agents. classes and targets","volume":"293","author":"Schwenk","year":"2018","journal-title":"Toxicol. 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