{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T18:56:46Z","timestamp":1791226606482,"version":"4.1.0"},"reference-count":72,"publisher":"MDPI AG","issue":"17","license":[{"start":{"date-parts":[[2024,9,2]],"date-time":"2024-09-02T00:00:00Z","timestamp":1725235200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Bolyai Janos Research Fellowship","award":["BO\/00246\/21\/7"],"award-info":[{"award-number":["BO\/00246\/21\/7"]}]},{"name":"Bolyai Janos Research Fellowship","award":["\u00daNKP-23-5-SZTE-714"],"award-info":[{"award-number":["\u00daNKP-23-5-SZTE-714"]}]},{"name":"New National Excellence Program of the Ministry for the Innovation and Technology from the Source of the National Research, Development and Innovation Office","award":["BO\/00246\/21\/7"],"award-info":[{"award-number":["BO\/00246\/21\/7"]}]},{"name":"New National Excellence Program of the Ministry for the Innovation and Technology from the Source of the National Research, Development and Innovation Office","award":["\u00daNKP-23-5-SZTE-714"],"award-info":[{"award-number":["\u00daNKP-23-5-SZTE-714"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>Using a co-precipitation technique, the anionic form of sulisobenzone (benzophenone-4) sunscreen ingredient was incorporated into the interlayer space of CaFe-hydrocalumite for the first time. Using detailed post-synthetic millings of the photoprotective nanocomposite obtained, we aimed to study the mechanochemical effects on complex, hybridized layered double hydroxides (LDHs). Various physicochemical properties of the ground and the intact LDHs were compared by powder X-ray diffractometry, N2 adsorption-desorption, UV\u2013Vis diffuse reflectance, infrared and Raman spectroscopy, scanning electron microscopy and thermogravimetric measurements. The data showed significant structural and morphological deformations, surface and textural changes and multifarious thermal behavior. The most interesting development was the change in the optical properties of organic LDHs; the milling significantly improved the UV light blocking ability, especially around 320 nm. Spectroscopic results verified that this could be explained by a modification in interaction between the LDH layers and the sulisobenzone anions, through modulated \u03c0\u2013\u03c0 conjugation and light absorption of benzene rings. In addition to the vibrating mill often used in the laboratory, the photoprotection reinforcement can also be induced by the drum mill grinding system commonly applied in industry.<\/jats:p>","DOI":"10.3390\/nano14171436","type":"journal-article","created":{"date-parts":[[2024,9,2]],"date-time":"2024-09-02T12:54:42Z","timestamp":1725281682000},"page":"1436","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Ball-Milling Enhanced UV Protection Performance of Ca2Fe-Sulisobenzone Layered Double Hydroxide Organic Clay"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7588-335X","authenticated-orcid":false,"given":"M\u00e1rton","family":"Szabados","sequence":"first","affiliation":[{"name":"Materials and Solution Structure Research Group, Interdisciplinary Excellence Centre, Institute of Chemistry, University of Szeged, Aradi V\u00e9rtan\u00fak Tere 1, H-6720 Szeged, Hungary"},{"name":"Department of Molecular and Analytical Chemistry, University of Szeged, D\u00f3m T\u00e9r 7\u20138, H-6720 Szeged, Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rebeka","family":"M\u00e9sz\u00e1ros","sequence":"additional","affiliation":[{"name":"Institute of Pharmaceutical Chemistry, University of Szeged, E\u00f6tv\u00f6s Utca 6, H-6720 Szeged, Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9528-9983","authenticated-orcid":false,"given":"Dorina Gabriella","family":"Dob\u00f3","sequence":"additional","affiliation":[{"name":"Institute of Pharmaceutical Technology and Regulatory Affairs, University of Szeged, E\u00f6tv\u00f6s Utca 6, H-6720 Szeged, Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9406-8596","authenticated-orcid":false,"given":"Zolt\u00e1n","family":"K\u00f3nya","sequence":"additional","affiliation":[{"name":"Department of Applied and Environmental Chemistry, University of Szeged, Rerrich B. T\u00e9r 1, H-6720 Szeged, Hungary"},{"name":"HUN-REN-SZTE Reaction Kinetics and Surface Chemistry Research Group, Rerrich B. T\u00e9r 1, H-6720 Szeged, Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"\u00c1kos","family":"Kukovecz","sequence":"additional","affiliation":[{"name":"Department of Applied and Environmental Chemistry, University of Szeged, Rerrich B. 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