{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T22:55:13Z","timestamp":1791500113189,"version":"4.3.4"},"reference-count":181,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2025,1,28]],"date-time":"2025-01-28T00:00:00Z","timestamp":1738022400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"MICIU\/AEI\/","award":["PID2023-146481OB-I00"],"award-info":[{"award-number":["PID2023-146481OB-I00"]}]},{"name":"FEDER, UE","award":["PID2023-146481OB-I00"],"award-info":[{"award-number":["PID2023-146481OB-I00"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>This review explores the recent advancements in the application of boron nitride (BN) as a support material for metallic nanoparticles, highlighting its potential in fostering sustainable chemical reactions when employed as a heterogeneous catalyst. Two key processes, both critical to hydrogen storage and transport, are examined in detail. First, the reversible synthesis and decomposition of ammonia using BN-supported metallic catalysts has emerged as a promising technology. This approach facilitates the preparation of Ru nanoparticles with precisely structured surface atomic ensembles, such as B5 sites, which are critical for maximizing catalytic efficiency. Second, the review emphasizes the role of BN-supported catalysts in the production of formic acid (FA), a process intrinsically linked to the reuse of carbon dioxide. In this context, hydrogen and carbon dioxide\u2014potentially sourced from atmospheric capture\u2014serve as reactants. BN\u2019s high CO2 adsorption capacity makes it an ideal support material for such applications. Moreover, FA can serve as a source of hydrogen through decomposition or as a precursor to alternative chemicals like carbon monoxide (CO) via dehydration, further underscoring its versatility in sustainable catalysis.<\/jats:p>","DOI":"10.3390\/nano15030212","type":"journal-article","created":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T03:26:10Z","timestamp":1738121170000},"page":"212","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Boron Nitride-Supported Metal Catalysts for the Synthesis and Decomposition of Ammonia and Formic Acid"],"prefix":"10.3390","volume":"15","author":[{"given":"Marta","family":"Yruela-Garrido","sequence":"first","affiliation":[{"name":"Instituto de Cat\u00e1lisis y Petroleoqu\u00edmica, CSIC, 28049 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eduardo","family":"Campos-Castellanos","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica y Qu\u00edmica T\u00e9cnica, UNED, Las Rozas, 28232 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2834-0296","authenticated-orcid":false,"given":"Mar\u00eda V.","family":"Morales","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica y Qu\u00edmica T\u00e9cnica, UNED, Las Rozas, 28232 Madrid, Spain"},{"name":"Grupo de Dise\u00f1o y Aplicaci\u00f3n de Catalizadores Heterog\u00e9neos, Unidad Asociada UNED-CSIC (ICP), UNED, 28049 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4622-6008","authenticated-orcid":false,"given":"Inmaculada","family":"Rodr\u00edguez-Ramos","sequence":"additional","affiliation":[{"name":"Instituto de Cat\u00e1lisis y Petroleoqu\u00edmica, CSIC, 28049 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1848-5985","authenticated-orcid":false,"given":"Antonio","family":"Guerrero-Ruiz","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica y Qu\u00edmica T\u00e9cnica, UNED, Las Rozas, 28232 Madrid, Spain"},{"name":"Grupo de Dise\u00f1o y Aplicaci\u00f3n de Catalizadores Heterog\u00e9neos, Unidad Asociada UNED-CSIC (ICP), UNED, 28049 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,1,28]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"230081","DOI":"10.1016\/j.jpowsour.2021.230081","article-title":"Autothermal Recirculating Reactor (ARR) with Cu-BN Composite as a Stable Reactor Material for Sustainable Hydrogen Release from Ammonia","volume":"506","author":"Badakhsh","year":"2021","journal-title":"J. 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