{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T18:36:56Z","timestamp":1790620616370,"version":"4.1.0"},"reference-count":56,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2025,7,1]],"date-time":"2025-07-01T00:00:00Z","timestamp":1751328000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Spanish Ministry of Science and Innovation for the ECOCAT","award":["PID2022-136321OA-C22"],"award-info":[{"award-number":["PID2022-136321OA-C22"]}]},{"name":"Spanish Ministry of Science and Innovation for the ECOCAT","award":["JDC2022-048964-I"],"award-info":[{"award-number":["JDC2022-048964-I"]}]},{"name":"MICIU\/AEI\/10.13039\/501100011033","award":["PID2022-136321OA-C22"],"award-info":[{"award-number":["PID2022-136321OA-C22"]}]},{"name":"MICIU\/AEI\/10.13039\/501100011033","award":["JDC2022-048964-I"],"award-info":[{"award-number":["JDC2022-048964-I"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>A novel metal\u2013organic framework based on zinc ions, designated as Zn-URJC-12, has been synthesized and applied for the first time in the cycloaddition reaction between carbon dioxide and epoxides. This MOF is constructed from two different organic linkers: 5-aminoisophthalic acid and 4,4\u2032-biphenyldicarboxylic acid. The framework features \u2013NH2 functional groups coordinated to Zn(II) centers, as confirmed by single-crystal X-ray diffraction analysis. Zn-URJC-12 demonstrates exceptional chemical stability in polar organic solvents, such as methanol, while maintaining thermal stability up to 250 \u00b0C. The material exhibits high catalytic efficiency in the cycloaddition of CO2 with epoxides, achieving yields of 100% and 76% for propylene oxide and allyl glycidyl ether, respectively. Additionally, Zn-URJC-12 maintains its structural integrity and catalytic performance during five successive reaction cycles. These findings underscore Zn-URJC-12 as a promising heterogeneous catalyst for the valorization of CO2 into cyclic carbonates.<\/jats:p>","DOI":"10.3390\/nano15131018","type":"journal-article","created":{"date-parts":[[2025,7,1]],"date-time":"2025-07-01T06:56:54Z","timestamp":1751353014000},"page":"1018","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Zn-URJC-12 Material Constituted of Two Different Organic Ligands for CO2 Valorization into Cyclic Carbonates"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1731-6514","authenticated-orcid":false,"given":"Jes\u00fas","family":"Tapiador","sequence":"first","affiliation":[{"name":"Chemical and Environmental Engineering Group, Escuela Superior de Ciencias Experimentales y Tecnolog\u00eda (ESCET), Universidad Rey Juan Carlos, c\/Tulip\u00e1n s\/n, 28933 M\u00f3stoles, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6888-4215","authenticated-orcid":false,"given":"Pedro","family":"Leo","sequence":"additional","affiliation":[{"name":"Chemical and Environmental Engineering Group, Escuela Superior de Ciencias Experimentales y Tecnolog\u00eda (ESCET), Universidad Rey Juan Carlos, c\/Tulip\u00e1n s\/n, 28933 M\u00f3stoles, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4812-8938","authenticated-orcid":false,"given":"Pablo","family":"Salcedo-Abraira","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry, University of Granada, Avda. 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Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1016\/j.trac.2019.06.007","article-title":"A Review on Metal-Organic Frameworks: Synthesis and Applications","volume":"118","author":"Safaei","year":"2019","journal-title":"TrAC Trends Anal. Chem."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"124430","DOI":"10.1016\/j.cej.2020.124430","article-title":"A Novel Enhancement of Shape\/Thermal Stability and Energy-Storage Capacity of Phase Change Materials through the Formation of Composites with 3D Porous (3,6)-Connected Metal\u2013Organic Framework","volume":"389","author":"Atinafu","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"106354","DOI":"10.1016\/j.est.2022.106354","article-title":"A Novel Metal-Organic Framework Aerogel Based Hydrated Salt Composite Phase Change Material for Enhanced Solar Thermal Utilization","volume":"58","author":"Hu","year":"2023","journal-title":"J. Energy Storage"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"114442","DOI":"10.1016\/j.cattod.2023.114442","article-title":"Open Zn-URJC-13 Efficient Catalyst for Mild CO2 Transformation Using Bulky Epoxides","volume":"428","author":"Tapiador","year":"2024","journal-title":"Catal. Today"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"533","DOI":"10.1039\/C7CS00653E","article-title":"Magnetic Functionalities in MOFs: From the Framework to the Pore","volume":"47","author":"Coronado","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1801","DOI":"10.1039\/D0QI00167H","article-title":"Luminescent Metal\u2013Organic Frameworks (LMOFs) as Potential Probes for the Recognition of Cationic Water Pollutants","volume":"7","author":"Samanta","year":"2020","journal-title":"Inorg. Chem. Front."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"7004","DOI":"10.1021\/acsami.1c01089","article-title":"Metal\u2013Organic Frameworks for Drug Delivery: A Design Perspective","volume":"13","author":"Lawson","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"6804","DOI":"10.1039\/C4CS00395K","article-title":"Metal-Organic Frameworks: Versatile Heterogeneous Catalysts for Efficient Catalytic Organic Transformations","volume":"44","author":"Chughtai","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"101715","DOI":"10.1016\/j.jcou.2021.101715","article-title":"A Review for Metal-Organic Frameworks (MOFs) Utilization in Capture and Conversion of Carbon Dioxide into Valuable Products","volume":"53","author":"Zahid","year":"2021","journal-title":"J. CO2 Util."},{"key":"ref_12","doi-asserted-by":"crossref","unstructured":"Rollin, P., Soares, L.K., Barcellos, A.M., Araujo, D.R., Lenard\u00e3o, E.J., Jacob, R.G., and Perin, G. (2021). Five-Membered Cyclic Carbonates: Versatility for Applications in Organic Synthesis, Pharmaceutical, and Materials Sciences. Appl. Sci., 11.","DOI":"10.3390\/app11115024"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"1514","DOI":"10.1039\/c0gc00065e","article-title":"Synthesis of Cyclic Carbonates from Epoxides and CO2","volume":"12","author":"North","year":"2010","journal-title":"Green Chem."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"138715","DOI":"10.1016\/j.cej.2022.138715","article-title":"Rational Design of Lewis Acid-Base Bifunctional Nanopolymers with High Performance on CO2\/Epoxide Cycloaddition without a Cocatalyst","volume":"451","author":"Zhang","year":"2023","journal-title":"Chem. Eng. J."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"160","DOI":"10.1016\/j.molcata.2006.08.002","article-title":"Homogeneous and Heterogeneous 4-(N,N-Dialkylamino)Pyridines as Effective Single Component Catalysts in the Synthesis of Propylene Carbonate","volume":"261","author":"Shiels","year":"2007","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"102","DOI":"10.1016\/j.cattod.2006.02.028","article-title":"Chemical Fixation of Carbon Dioxide to Propylene Carbonate over Amine-Functionalized Silica Catalysts","volume":"115","author":"Zhang","year":"2006","journal-title":"Catal. Today"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"32","DOI":"10.1016\/j.molcata.2005.08.004","article-title":"Solventless Synthesis of Propylene Carbonate Catalysed by Chromium-Salen Complexes: Bridging Homogeneous and Heterogeneous Catalysis","volume":"242","author":"Ramin","year":"2005","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"102166","DOI":"10.1016\/j.jcou.2022.102166","article-title":"Robust Cu-URJC-8 with Mixed Ligands for Mild CO2 Cycloaddition Reaction","volume":"64","author":"Tapiador","year":"2022","journal-title":"J. CO2 Util."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"112741","DOI":"10.1016\/j.micromeso.2023.112741","article-title":"Copper MOFs Performance in the Cycloaddition Reaction of CO2 and Epoxides","volume":"361","author":"Tapiador","year":"2023","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1016\/j.cattod.2021.11.025","article-title":"A Novel Zn-Based-MOF for Efficient CO2 Adsorption and Conversion under Mild Conditions","volume":"390\u2013391","author":"Tapiador","year":"2022","journal-title":"Catal. Today"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"109497","DOI":"10.1016\/j.jece.2023.109497","article-title":"Influence of Divalent Metal Ions on CO2 Valorization at Room Temperature by Isostructural MOF-74 Materials","volume":"11","author":"Tapiador","year":"2023","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"213173","DOI":"10.1016\/j.ccr.2019.213173","article-title":"Metal\u2013Organic Frameworks for the Chemical Fixation of CO2 into Cyclic Carbonates","volume":"408","author":"Pal","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"16747","DOI":"10.1021\/acs.inorgchem.0c02807","article-title":"Series of M-MOF-184 (M = Mg, Co, Ni, Zn, Cu, Fe) Metal-Organic Frameworks for Catalysis Cycloaddition of CO2","volume":"59","author":"Tran","year":"2020","journal-title":"Inorg. Chem."},{"key":"ref_24","first-page":"1029","article-title":"Predicting Metal-Organic Frameworks as Catalysts to Fix Carbon Dioxide to Cyclic Carbonate by Machine Learning","volume":"7","author":"Li","year":"2021","journal-title":"J. Mater."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"102298","DOI":"10.1016\/j.jcou.2022.102298","article-title":"Nitrogen-Rich Cobalt (II) MOFs as Efficient Bifunctional Catalysts for Single or Tandem Oxidation and CO2 Conversion Reactions","volume":"67","author":"Maya","year":"2023","journal-title":"J. CO2 Util."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"102235","DOI":"10.1016\/j.jcou.2022.102235","article-title":"Catalytic Performance of MOFs Containing Trinuclear Lanthanides Clusters in the Cycladdition Reaction of CO2 and Epoxide","volume":"65","author":"Shang","year":"2022","journal-title":"J. CO2 Util."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"557","DOI":"10.1016\/j.molstruc.2019.02.076","article-title":"A Novel 2D Cu(II)-MOF as a Heterogeneous Catalyst for the Cycloaddition Reaction of Epoxides and CO2 into Cyclic Carbonates","volume":"1184","author":"Guo","year":"2019","journal-title":"J. Mol. Struct."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"214645","DOI":"10.1016\/j.ccr.2022.214645","article-title":"Multi-Dimensional Metal-Organic Frameworks Based on Mixed Linkers: Interplay between Structural Flexibility and Functionality","volume":"469","author":"Bhattacharyya","year":"2022","journal-title":"Coord. Chem. Rev."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"9276","DOI":"10.1039\/c3ce41438h","article-title":"Metal\u2013Organic Frameworks (MOFs) Based on Mixed Linker Systems: Structural Diversities towards Functional Materials","volume":"15","author":"Haldar","year":"2013","journal-title":"CrystEngComm"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"5238","DOI":"10.1039\/C6CY00695G","article-title":"Mixed-Metal or Mixed-Linker Metal Organic Frameworks as Heterogeneous Catalysts","volume":"6","author":"Dhakshinamoorthy","year":"2016","journal-title":"Catal. Sci. Technol."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"3552","DOI":"10.1002\/ejic.200900509","article-title":"Mixed-Linker Metal-Organic Frameworks as Catalysts for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2","volume":"2009","author":"Kleist","year":"2009","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2665","DOI":"10.1021\/ja512478y","article-title":"Bipyridine- and Phenanthroline-Based Metal\u2013Organic Frameworks for Highly Efficient and Tandem Catalytic Organic Transformations via Directed C\u2013H Activation","volume":"137","author":"Manna","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"17951","DOI":"10.1021\/acs.inorgchem.2c01855","article-title":"Coordination Polymers Constructed from an Adaptable Pyridine-Dicarboxylic Acid Linker: Assembly, Diversity of Structures, and Catalysis","volume":"61","author":"Cheng","year":"2022","journal-title":"Inorg. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"851","DOI":"10.1039\/C4CY01074D","article-title":"Efficient and Recyclable Cu2(BDC)2(BPY)-Catalyzed Oxidative Amidation of Terminal Alkynes: Role of Bipyridine Ligand","volume":"5","author":"Le","year":"2015","journal-title":"Catal. Sci. Technol."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"11269","DOI":"10.1021\/acs.inorgchem.5b01850","article-title":"Application of Two Cobalt-Based Metal\u2013Organic Frameworks as Oxidative Desulfurization Catalysts","volume":"54","author":"Masoomi","year":"2015","journal-title":"Inorg. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1309","DOI":"10.1557\/s43579-023-00456-w","article-title":"CO2 Cycloaddition Reaction at Ambient Temperature and Pressure over Metal Organic Framework Catalysts","volume":"13","author":"Payra","year":"2023","journal-title":"MRS Commun."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"1408","DOI":"10.1007\/s10562-019-03053-6","article-title":"A Stable Zn-Based Metal\u2013Organic Framework as an Efficient Catalyst for Carbon Dioxide Cycloaddition and Alcoholysis at Mild Conditions","volume":"150","author":"Luo","year":"2020","journal-title":"Catal. Lett."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","article-title":"SHELXT\u2014Integrated Space-Group and Crystal-Structure Determination","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. A Found. Adv."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal Structure Refinement with SHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. C Struct. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","article-title":"OLEX2: A Complete Structure Solution, Refinement and Analysis Program","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Crystallogr."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"309","DOI":"10.1021\/ja01269a023","article-title":"Adsorption of Gases in Multimolecular Layers","volume":"60","author":"Brunauer","year":"1938","journal-title":"J. Am. Chem. Soc."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.ica.2013.03.042","article-title":"Influential Factors on Assembly of First-Row Transition Metal Coordination Polymers","volume":"403","author":"Yang","year":"2013","journal-title":"Inorg. Chim. Acta"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"2424","DOI":"10.1021\/ic050662v","article-title":"Design of Novel Bilayer Compounds of the CPO-8 Type Containing 1D Channels","volume":"45","author":"Kongshaug","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"14201","DOI":"10.1039\/D0DT02606A","article-title":"From Lamellar Net to Bilayered-Lamella and to Porous Pillared-Bilayer: Reversible Crystal-to-Crystal Transformation, CO2 Adsorption, and Fluorescence Detection of Fe3+, Al3+, Cr3+, MnO4\u2212, and Cr2O72\u2212 in Water","volume":"49","author":"Zhang","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"61334","DOI":"10.1021\/acsami.1c20878","article-title":"Facile One-Pot Synthesis of Zn\/Mg-MOF-74 with Unsaturated Coordination Metal Centers for Efficient CO2 Adsorption and Conversion to Cyclic Carbonates","volume":"13","author":"Gao","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"6289","DOI":"10.1002\/chem.201203985","article-title":"A DFT Study on the Mechanism of the Cycloaddition Reaction of CO2 to Epoxides Catalyzed by Zn(Salphen) Complexes","volume":"19","author":"Salassa","year":"2013","journal-title":"Chem. A Eur. J."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"9256","DOI":"10.1021\/acs.chemmater.7b03183","article-title":"Highly Effective Carbon Fixation via Catalytic Conversion of CO2 by an Acylamide-Containing Metal\u2013Organic Framework","volume":"29","author":"Li","year":"2017","journal-title":"Chem. Mater."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"2584","DOI":"10.1021\/acs.inorgchem.7b02983","article-title":"Zinc Porphyrin\/Imidazolium Integrated Multivariate Zirconium Metal\u2013Organic Frameworks for Transformation of CO2 into Cyclic Carbonates","volume":"57","author":"Liang","year":"2018","journal-title":"Inorg. Chem."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"180","DOI":"10.1021\/cs200638h","article-title":"Zeolitic Imidazole Framework-8 Catalysts in the Conversion of CO2 to Chloropropene Carbonate","volume":"2","author":"Miralda","year":"2012","journal-title":"ACS Catal."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"2167","DOI":"10.1039\/c2ra22550f","article-title":"Ni(Salphen)-Based Metal-Organic Framework for the Synthesis of Cyclic Carbonates by Cycloaddition of CO2 to Epoxides","volume":"3","author":"Ren","year":"2013","journal-title":"RSC Adv."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.molcata.2012.04.008","article-title":"Functionalized IRMOF-3 as Efficient Heterogeneous Catalyst for the Synthesis of Cyclic Carbonates","volume":"361\u2013362","author":"Zhou","year":"2012","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1016\/j.cattod.2012.03.034","article-title":"Catalytic Activity of Metal Organic Framework Cu3(BTC)2 in the Cycloaddition of CO2 to Epichlorohydrin Reaction","volume":"198","author":"Macias","year":"2012","journal-title":"Catal. Today"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"3757","DOI":"10.1021\/acs.inorgchem.3c03901","article-title":"Zn-MOF as a Single Catalyst with Dual Lewis Acidic and Basic Reaction Sites for CO2 Fixation","volume":"63","author":"Eskemech","year":"2024","journal-title":"Inorg. Chem."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"1888","DOI":"10.1039\/D3CY01709E","article-title":"Ambient Conversion of CO2 and Epoxides to Cyclic Carbonates Using 3D Amide-Functionalized MOFs","volume":"14","author":"Khattak","year":"2024","journal-title":"Catal. Sci. Technol."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"4375","DOI":"10.1002\/asia.201901246","article-title":"Hollow Zn\u2212Co Based Zeolitic Imidazole Framework as a Robust Heterogeneous Catalyst for Enhanced CO2 Chemical Fixation","volume":"14","author":"Tang","year":"2019","journal-title":"Chem. Asian J."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"5018","DOI":"10.1002\/anie.201900787","article-title":"Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation","volume":"58","author":"Xu","year":"2019","journal-title":"Angew. Chem. Int. 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