{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T21:12:23Z","timestamp":1792789943632,"version":"4.5.0"},"reference-count":132,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2025,7,18]],"date-time":"2025-07-18T00:00:00Z","timestamp":1752796800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Science and Technology Project of Hami City","award":["hmskjjhxm202421"],"award-info":[{"award-number":["hmskjjhxm202421"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>Methanol Steam Reforming (MSR) is one of the most promising technologies in the hydrogen economy, and copper-based catalysts have become the core materials in this field due to their high activity and low cost. In this paper, we systematically review the design strategies of copper-based catalysts in MSR reactions in recent years, including structure control, component optimization, support effect, and surface modification. We focus on the mechanisms of active site exposure, improvement of anti-sintering ability, and the enhancement of anti-carbon deposition performance. Finally, we summarize the challenges of current research and propose the future development direction. This review aims to provide a reference for subsequent related research through the experience of this paper.<\/jats:p>","DOI":"10.3390\/nano15141118","type":"journal-article","created":{"date-parts":[[2025,7,18]],"date-time":"2025-07-18T12:09:53Z","timestamp":1752840593000},"page":"1118","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["A Review on the Design Strategies of Copper-Based Catalysts for Enhanced Activity and Stability in Methanol Reforming to Hydrogen"],"prefix":"10.3390","volume":"15","author":[{"given":"Shuang","family":"Pang","sequence":"first","affiliation":[{"name":"Hami Vocational and Technical College, Hami 839000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueying","family":"Dou","sequence":"additional","affiliation":[{"name":"Hami Vocational and Technical College, Hami 839000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Zhao","sequence":"additional","affiliation":[{"name":"Hami Vocational and Technical College, Hami 839000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suli","family":"Bai","sequence":"additional","affiliation":[{"name":"Hami Vocational and Technical College, Hami 839000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Wan","sequence":"additional","affiliation":[{"name":"Hami Vocational and Technical College, Hami 839000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tiaoxia","family":"Wang","sequence":"additional","affiliation":[{"name":"Hami Vocational and Technical College, Hami 839000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1964-3121","authenticated-orcid":false,"given":"Jing-He","family":"Yang","sequence":"additional","affiliation":[{"name":"Hami Vocational and Technical College, Hami 839000, China"},{"name":"School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,7,18]]},"reference":[{"key":"ref_1","first-page":"23","article-title":"Study on the activity of catalyst for hydrogen production by copper-based methanol water vapor reforming","volume":"44","author":"Yan","year":"2015","journal-title":"Shandong Chem. Ind."},{"key":"ref_2","first-page":"21","article-title":"Effect of Different Alumina on Catalyst Activity of Copper-based Methanol Water Vapor Reforming for Hydrogen Production","volume":"19","author":"Yan","year":"2016","journal-title":"Sichuan Chem. Ind."},{"key":"ref_3","first-page":"1536","article-title":"Research progress on hydrogen production catalyzed by methanol steam reforming with Cu-based catalysts","volume":"46","author":"Chen","year":"2017","journal-title":"Petrochem. Technol."},{"key":"ref_4","first-page":"8","article-title":"Research and application progress of methanol hydrogen production technology","volume":"48","author":"Bai","year":"2020","journal-title":"Guangzhou Chem. Ind."},{"key":"ref_5","first-page":"5975","article-title":"Research Progress on Copper-based Catalysts for Methanol Reforming to Hydrogen","volume":"72","author":"Sun","year":"2021","journal-title":"CIESC J."},{"key":"ref_6","first-page":"1","article-title":"Research progress on the intensification of methanol steam reforming process for hydrogen production","volume":"15","author":"Wang","year":"2022","journal-title":"China Sci. Technol. Pap. Online"},{"key":"ref_7","first-page":"162","article-title":"Theoretical study on CO2 hydrogenation to formic acid and design of high-efficiency iron-based catalyst","volume":"36","author":"Liu","year":"2022","journal-title":"Mol. Catal."},{"key":"ref_8","first-page":"18","article-title":"Research Progress on Cu-based Catalysts for Methanol Vapor Reforming to Hydrogen with Different Carriers","volume":"40","author":"Han","year":"2022","journal-title":"China Biogas"},{"key":"ref_9","first-page":"40","article-title":"Study on Preparation of Chalcopyrite by Copper-based Catalyst for Methanol Water Vapor Reforming for Hydrogen Production","volume":"46","author":"Zhu","year":"2023","journal-title":"J. Wuhan Univ. Sci. Technol."},{"key":"ref_10","first-page":"217","article-title":"Design and analysis of methanol reforming process for hydrogen production","volume":"49","author":"Ju","year":"2022","journal-title":"Guangdong Chem. Ind."},{"key":"ref_11","first-page":"316","article-title":"Research Progress on Design and Reaction Mechanism of Copper-based Catalysts for Electrocatalytic Carbon Dioxide Reduction","volume":"51","author":"Zhang","year":"2023","journal-title":"Chin. J. Anal. Chem."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1943","DOI":"10.1038\/s41467-025-57274-y","article-title":"Optimizing selectivity via steering dominant reaction mechanisms in steam reforming of methanol for hydrogen production","volume":"16","author":"Zhang","year":"2025","journal-title":"Nat. Commun."},{"key":"ref_13","unstructured":"Purnama, H. (2003). Catalytic Study of Copper Based Catalysts for Steam Reforming of Methanol. [Ph.D. Thesis, Technische Universit\u00e4t Berlin]."},{"key":"ref_14","first-page":"54","article-title":"Synthesis, characterization, and methanol steam reforming performance of Cu\/perovskite-structured catalysts","volume":"9","author":"Safari","year":"2023","journal-title":"Heliyon"},{"key":"ref_15","first-page":"22","article-title":"Research Progress on Cu-based Catalysts for CO2 Hydrogenation to Methanol","volume":"48","author":"Huo","year":"2023","journal-title":"Low Carbon Chem. Chem. Eng."},{"key":"ref_16","first-page":"219","article-title":"Zero-carbon new energy absorption system based on hydrogen production by water electrolysis and methanol synthesis\/reforming","volume":"43","author":"Jia","year":"2023","journal-title":"Mod. Chem. Ind."},{"key":"ref_17","first-page":"96","article-title":"Effect of La Doping on Hydrogen Production Performance by Methanol Water Vapor Reforming of CuO\/CeO2 Nanorods","volume":"49","author":"Cong","year":"2023","journal-title":"Anhui Chem. Ind."},{"key":"ref_18","first-page":"287","article-title":"Research progress on the active sites of copper-based catalysts in the process of carbon dioxide hydrogenation to methanol","volume":"42","author":"Shi","year":"2023","journal-title":"Chem. Ind. Eng. Prog."},{"key":"ref_19","first-page":"24","article-title":"Study on Improvement Strategy of Copper Valence Distribution on CO2 Hydrogenation to Methanol Catalyst","volume":"43","author":"Xian","year":"2023","journal-title":"Mod. Chem. Ind."},{"key":"ref_20","first-page":"3051","article-title":"Research Progress on Electroreduction of Carbon Dioxide to Formic Acid by Copper-based Catalysts","volume":"43","author":"Chen","year":"2024","journal-title":"Chem. Ind. Eng. Prog."},{"key":"ref_21","first-page":"6","article-title":"A brief analysis on the R&D and application prospect of CO2 hydrogenation to methanol","volume":"37","author":"Chen","year":"2023","journal-title":"Dongfang Electr. Rev."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"178","DOI":"10.1016\/S1872-2067(23)64535-8","article-title":"Gallium-modified copper-based hydrophobic catalyst for selective hydrogenation of CO2 to dimethyl ether","volume":"54","author":"Li","year":"2023","journal-title":"Chin. J. Catal."},{"key":"ref_23","first-page":"44","article-title":"Research Progress on Performance Regulation of Copper-based Catalysts for Methyl Acetate Hydrogenation to Ethanol","volume":"49","author":"Liu","year":"2024","journal-title":"Low Carbon Chem. Chem. Eng."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"198","DOI":"10.1016\/j.ijhydene.2017.10.182","article-title":"The influence of the support composition and structure (MXZr1-XO2-\u03b4) of bimetallic catalysts on the activity in methanol steam reforming","volume":"43","author":"Lytkina","year":"2018","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"913","DOI":"10.1007\/s11144-024-02581-6","article-title":"Cu\u2013Mn\u2013Al based catalyst for the direct syngas to dimethyl ether conversion","volume":"137","author":"Blanco","year":"2024","journal-title":"React. Kinet. Mech. Catal."},{"key":"ref_26","first-page":"114403","article-title":"Catalytic systems for hydrogenation of CO2 to methanol","volume":"566","author":"Tedeeva","year":"2024","journal-title":"Mol. Catal."},{"key":"ref_27","first-page":"100302","article-title":"Utilization of CO2 and recycling of methanol Residue from the refining process for production of Bio-Methanol","volume":"8","author":"Jitrwung","year":"2025","journal-title":"Carbon Resour. Convers."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"27324","DOI":"10.1002\/anie.202113895","article-title":"Metal-triazolate-framework-derived FeN4Cl1 single-atom catalysts with hierarchical porosity for the oxygen reduction reaction","volume":"60","author":"Hu","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"11194","DOI":"10.1021\/acs.chemrev.0c00016","article-title":"Hierarchically structured zeolites: From design to application","volume":"120","author":"Chen","year":"2020","journal-title":"Chem. Rev."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1016\/j.ijhydene.2024.12.352","article-title":"Synthesis and evaluation of Cu-based catalysts employed in the medium temperature water gas shift reaction","volume":"101","author":"Tonekaboni","year":"2025","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"115316","DOI":"10.1016\/j.jcat.2024.115316","article-title":"High density ultra-small Cu nanoparticles with abundant oxygen vacancies for efficient hydrogen evolution from MeOH\/H2O","volume":"430","author":"Li","year":"2024","journal-title":"J. Catal."},{"key":"ref_32","first-page":"12","article-title":"Current status and development trend of methanol synthesis technology","volume":"45","author":"Yu","year":"2024","journal-title":"Energy Chem. Ind."},{"key":"ref_33","first-page":"121","article-title":"Research Progress on Methanol Water Steam Reforming for Hydrogen Production","volume":"43","author":"Guo","year":"2024","journal-title":"Energy Conserv."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1443","DOI":"10.1016\/S1872-5813(24)60459-7","article-title":"Effect of Al2O3 Precursor on the Performance of Cu\/ZnO\/Al2O3 in Catalyzing Methanol Reforming for Hydrogen Production","volume":"52","author":"Huang","year":"2024","journal-title":"J. Fuel Chem. Technol."},{"key":"ref_35","first-page":"1","article-title":"Research Progress on Copper-based Catalysts for Reverse Water Vapor Shift Reaction","volume":"32","author":"Lv","year":"2024","journal-title":"Ind. Catal."},{"key":"ref_36","first-page":"373","article-title":"Comprehensive Experiment on Nitrate Synthesis of Ammonia Based on Electrocatalytic Reduction: Preparation Characterization, Performance Exploration and Application Design of Copper-based Catalyst","volume":"39","author":"Zou","year":"2024","journal-title":"Univ. Chem."},{"key":"ref_37","first-page":"1338","article-title":"Durability evaluation and life prediction method of methanol reforming catalyst for hydrogen production","volume":"44","author":"Zhu","year":"2025","journal-title":"Chem. Ind. Eng. Prog."},{"key":"ref_38","first-page":"67","article-title":"CuO\/ZnO catalysts for methanol steam reforming: The role of the support polarity ratio and surface area","volume":"174","author":"Silva","year":"2015","journal-title":"Appl. Catal. B Environ."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"4397","DOI":"10.1016\/j.ijhydene.2013.01.053","article-title":"CeO2\u2013ZrO2-promoted CuO\/ZnO catalyst for methanol steam reforming","volume":"38","author":"Zhang","year":"2013","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1007\/s43153-021-00136-z","article-title":"Statistical optimization of the composition of CuO\u2013ZnO\/Al2O3 catalysts for methanol steam reforming","volume":"38","author":"Fornari","year":"2021","journal-title":"Braz. J. Chem. Eng."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"030701","DOI":"10.1063\/5.0137706","article-title":"A review study on methanol steam reforming catalysts: Evaluation of the catalytic performance, characterizations, and operational parameters","volume":"13","author":"Rostami","year":"2023","journal-title":"AIP Adv."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"102934","DOI":"10.1016\/j.jcou.2024.102934","article-title":"Optimizing bimetallic and multimetallic Cu-based catalysts by promoters for enhanced reverse Water-Gas Shift reaction: Insights and stability assessments","volume":"88","author":"Bazyari","year":"2024","journal-title":"J. CO2 Util."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"6169","DOI":"10.1007\/s10853-024-09546-z","article-title":"A review on copper-based nanoparticles as a catalyst: Synthesis and applications in coupling reactions","volume":"59","author":"Pathak","year":"2024","journal-title":"J. Mater. Sci."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"2300549","DOI":"10.1002\/adsu.202300549","article-title":"Recent Developments in Copper-Based Catalysts for Enhanced Electrochemical CO2 Reduction","volume":"8","author":"Yesupatham","year":"2024","journal-title":"Adv. Sustain. Syst."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"2307913","DOI":"10.1002\/adma.202307913","article-title":"Recent advances in electrocatalytic hydrogenation reactions on copper-based catalysts","volume":"36","author":"Zheng","year":"2024","journal-title":"Adv. Mater."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"e202301108","DOI":"10.1002\/cctc.202301108","article-title":"Progress of Copper-based Nanocatalysts in Advanced Oxidation Degraded Organic Pollutants","volume":"16","author":"Li","year":"2024","journal-title":"ChemCatChem"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/01614940.2023.2267286","article-title":"State-of-the-art for the development of Cu-based heterogeneous catalysts for efficient utilization of furfural to value chemicals via liquid-phase and gas-phase reactions","volume":"67","author":"Nikam","year":"2025","journal-title":"Catal. Rev."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"215936","DOI":"10.1016\/j.ccr.2024.215936","article-title":"Coordination structure engineering of Cu-based electrocatalysts for electrocatalytic water splitting","volume":"516","author":"Luo","year":"2024","journal-title":"Coord. Chem. Rev."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"e202500770","DOI":"10.1002\/chem.202500770","article-title":"Structural Reconstruction of Copper-Based Catalysts in CO2 Electroreduction Reaction: A Comprehensive Review","volume":"31","author":"Zhong","year":"2025","journal-title":"Chem. A Eur. J."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"246","DOI":"10.3390\/suschem4030019","article-title":"Recent advances in copper-based materials for sustainable environmental applications","volume":"4","author":"Bonthula","year":"2023","journal-title":"Sustain. Chem."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"155394","DOI":"10.1016\/j.apsusc.2022.155394","article-title":"Insight into the effect of surface coverage of carbon support on selective CO2 electroreduction to C2H4 over copper-based catalyst","volume":"609","author":"Han","year":"2023","journal-title":"Appl. Surf. Sci."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"181","DOI":"10.1007\/s10563-022-09384-6","article-title":"The challenges and comprehensive evolution of Cu-based zeolite catalysts for SCR systems in diesel vehicles: A review","volume":"27","author":"Qi","year":"2023","journal-title":"Catal. Surv. Asia"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"320","DOI":"10.1016\/j.mattod.2023.05.028","article-title":"How to enhance the C2 products selectivity of copper-based catalysts towards electrochemical CO2 reduction?\u2014A review","volume":"67","author":"Li","year":"2023","journal-title":"Mater. Today"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"130291","DOI":"10.1016\/j.seppur.2024.130291","article-title":"Peracetic acid activation by chitosan-derived nitrogen-doped carbon spheres loaded with zero-valent copper for efficient sulfamethazine degradation in groundwater","volume":"358","author":"Zhao","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"131167","DOI":"10.1016\/j.fuel.2024.131167","article-title":"Copper-based catalysts supported on novel Metal-Organic Framework MIL-125 (Ti) for selective catalytic reduction of NO with CO","volume":"364","author":"Huang","year":"2024","journal-title":"Fuel"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"215962","DOI":"10.1016\/j.ccr.2024.215962","article-title":"Copper-based catalysts for CO2 electroreduction to C2\/2+ products: Advance and perspective","volume":"515","author":"Wang","year":"2024","journal-title":"Coord. Chem. Rev."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"3502","DOI":"10.1039\/D1GC04400A","article-title":"A review on the synthesis and applications of sustainable copper-based nanomaterials","volume":"24","author":"Kute","year":"2022","journal-title":"Green Chem."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"361","DOI":"10.2174\/1570193X15666180430151658","article-title":"Copper-based bulk and nano-catalysts for the one-pot propargylamine synthesis","volume":"16","author":"Sayyahi","year":"2019","journal-title":"Mini-Rev. Org. Chem."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"115940","DOI":"10.1016\/j.ces.2020.115940","article-title":"Copper-based nanocatalysts produced via laser-induced ex situ generation for homo-and cross-coupling reactions","volume":"227","author":"Gordeychuk","year":"2020","journal-title":"Chem. Eng. Sci."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"82","DOI":"10.1016\/j.ijhydene.2024.02.048","article-title":"Numerical simulation of catalytic reaction kinetics in a sine wave tubular methanol steam reforming reactor","volume":"60","author":"Wang","year":"2024","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"1284","DOI":"10.1021\/acsenergylett.2c00035","article-title":"Well-defined copper-based nanocatalysts for selective electrochemical reduction of CO2 to C2 products","volume":"7","author":"Zaza","year":"2022","journal-title":"ACS Energy Lett."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"258","DOI":"10.1016\/j.actbio.2022.05.030","article-title":"Copper-based theranostic nanocatalysts for synergetic photothermal-chemodynamic therapy","volume":"147","author":"Zuo","year":"2022","journal-title":"Acta Biomater."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1002\/tcr.201800069","article-title":"Recent developments in the biosynthesis of Cu-based recyclable nanocatalysts using plant extracts and their application in the chemical reactions","volume":"19","author":"Nasrollahzadeh","year":"2019","journal-title":"Chem. Rec."},{"key":"ref_64","first-page":"1","article-title":"Current status and development trend of CO2 hydrogenation to methanol","volume":"45","author":"Jiang","year":"2024","journal-title":"Energy Chem. Ind."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1039\/D4CC04025B","article-title":"Catalyst to cure: Applications of a new copper-based nanocatalyst in organic synthesis and cancer treatment","volume":"61","author":"Sampatkumar","year":"2025","journal-title":"Chem. Commun."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"120189","DOI":"10.1016\/j.molliq.2022.120189","article-title":"Facile synthesis of green and efficient copper-based magnetically recoverable nanocatalyst for the reduction of nitrophenol derivatives","volume":"365","author":"Maleki","year":"2022","journal-title":"J. Mol. Liq."},{"key":"ref_67","first-page":"41","article-title":"Design strategy of copper-based catalyst for electrocatalytic carbon dioxide reduction","volume":"30","author":"Zheng","year":"2024","journal-title":"Clean Coal Technol."},{"key":"ref_68","first-page":"277","article-title":"Au-CuO\/Cu2O tandem catalytic enhanced electrocatalytic reduction of CO2 to ethanol","volume":"44","author":"Dong","year":"2025","journal-title":"Chem. Ind. Eng. Prog."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"e7487","DOI":"10.1002\/aoc.7487","article-title":"Synthesis and catalytic applications of highly stable copper-based metal\u2013organic framework as an efficient heterogeneous nanocatalyst for solvent-free Suzuki\u2013Miyaura cross-coupling reaction","volume":"38","author":"Eshghi","year":"2024","journal-title":"Appl. Organomet. Chem."},{"key":"ref_70","first-page":"149","article-title":"Research Progress on Hydrophobic Modification of Cu-based Catalysts for Carbon Dioxide Hydrogenation to Methanol","volume":"42","author":"He","year":"2024","journal-title":"Petrochem. Technol. Appl."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"3075","DOI":"10.1016\/j.matpr.2021.07.169","article-title":"A critical review on efficient photocatalytic degradation of organic compounds using copper-based nanoparticles","volume":"80","author":"Priya","year":"2023","journal-title":"Mater. Today Proc."},{"key":"ref_72","first-page":"35","article-title":"Hydrogen production performance of Methanol water vapor reforming monolithic catalyst with CuO\/ZnO\/Al2O3 stainless steel fiber felt structure","volume":"40","author":"Li","year":"2024","journal-title":"Chem. React. Eng. Technol."},{"key":"ref_73","first-page":"46","article-title":"Dehydrogenation of propylene glycol methyl ether to methoxyacetone on copper-based catalyst","volume":"32","author":"Lin","year":"2024","journal-title":"Ind. Catal."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"69","DOI":"10.5562\/cca4001","article-title":"Ecofriendly Synthesis of DHPMs using Copper-based Nano catalysts and Evaluation of Antibacterial Activity","volume":"96","author":"Sharma","year":"2023","journal-title":"Croat. Chem. Acta"},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"24310","DOI":"10.1021\/acsami.4c22163","article-title":"Preparation of Hierarchical Porous Zeolite Particles with Multiscale Pore Architectures through a Template-Assisted Spray Process for Enhanced Toluene Adsorption Rate","volume":"17","author":"Cao","year":"2025","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"117402","DOI":"10.1016\/j.apcata.2019.117402","article-title":"Texture-evolution of copper-based nanocatalyst via hybrid glow discharge plasma-oxalate-precipitation method for hydrogen production from CH3OH\/H2O mixture","volume":"591","author":"Bagherzadeh","year":"2020","journal-title":"Appl. Catal. A Gen."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"466","DOI":"10.3390\/methane3030027","article-title":"Copper-Based Metal\u2013Organic Frameworks Applied as Electrocatalysts for the Electroreduction of Carbon Dioxide (CO2ER) to Methane: A Review","volume":"3","year":"2024","journal-title":"Methane"},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"20222","DOI":"10.1039\/D3NJ03074A","article-title":"A review of catalytic oxidation of carbon monoxide over different catalysts with an emphasis on hopcalite catalysts","volume":"47","author":"Kembo","year":"2023","journal-title":"New J. Chem."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1007\/s11030-022-10408-6","article-title":"Mesoporous epoxidized soybean oil-supported copper-based magnetic nanocatalyst and amberlite-supported azide as a green and efficient catalytic system for 1, 2, 3-triazole synthesis","volume":"27","author":"Dehkordi","year":"2023","journal-title":"Mol. Divers."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"3740","DOI":"10.1039\/D3CY00408B","article-title":"Copper-based metal\u2013organic frameworks for CO2 reduction: Selectivity trends, design paradigms, and perspectives","volume":"13","author":"Nwosu","year":"2023","journal-title":"Catal. Sci. Technol."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"15821","DOI":"10.1039\/D4RA01241K","article-title":"Antibacterial efficacy of copper-based metal\u2013organic frameworks against Escherichia coli and Lactobacillus","volume":"14","author":"Elmehrath","year":"2024","journal-title":"RSC Adv."},{"key":"ref_82","first-page":"332","article-title":"Copper-based catalyst for CO2 electrocatalysis to ethylene production","volume":"37","author":"Hu","year":"2025","journal-title":"Prog. Chem."},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"e5359","DOI":"10.1002\/aoc.5359","article-title":"Copper-based Schiff Base Complex Immobilized on Core-shell Fe3O4@ SiO2 as a magnetically recyclable and highly efficient nanocatalyst for green synthesis of 2-amino-4H-chromene derivatives","volume":"34","author":"Ebrahimiasl","year":"2020","journal-title":"Appl. Organomet. Chem."},{"key":"ref_84","first-page":"69","article-title":"Study on the catalytic properties of copper-based composite oxides for CO oxidation","volume":"53","author":"Zhang","year":"2025","journal-title":"Rare Met. Cem. Carbide"},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"881","DOI":"10.1007\/s42247-020-00116-y","article-title":"A review of recent advances in water-gas shift catalysis for hydrogen production","volume":"3","author":"Ebrahimi","year":"2020","journal-title":"Emergent Mater."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"100513","DOI":"10.1016\/j.rechem.2022.100513","article-title":"Recent advances in copper oxide nanocatalyzed CC cross-coupling transformations","volume":"4","author":"Soni","year":"2022","journal-title":"Results Chem."},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"216230","DOI":"10.1016\/j.ccr.2024.216230","article-title":"Unveiling the potential of ingenious copper-based metal-organic frameworks in gas storage and separation","volume":"522","author":"Kumar","year":"2025","journal-title":"Coord. Chem. Rev."},{"key":"ref_88","doi-asserted-by":"crossref","unstructured":"Haso, H.W., Dubale, A.A., Chimdesa, M.A., and Atlabachew, M. (2022). High performance copper based metal organic framework for removal of heavy metals from wastewater. Front. Mater., 9.","DOI":"10.3389\/fmats.2022.840806"},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"e6361","DOI":"10.1002\/aoc.6361","article-title":"Synthesis of 1-aminoalkyl-2-naphthols derivatives using an engineered copper-based nanomagnetic catalyst (Fe3O4@CQD@Si (OEt)(CH2) 3NH@CC@N3@phenylacetylene@Cu)","volume":"35","author":"Akbarpour","year":"2021","journal-title":"Appl. Organomet. Chem."},{"key":"ref_90","doi-asserted-by":"crossref","unstructured":"Abouri, M., Elouardi, M., Mabrouki, J., El Belghiti, M.A., and El Hamidi, A. (2025). Copper and Copper-Based Nanoparticles for Water Treatment. Technical Innovation and Modeling in the Biological Sciences, IGI Global Scientific Publishing.","DOI":"10.4018\/979-8-3693-9450-2.ch005"},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"162566","DOI":"10.1016\/j.apsusc.2025.162566","article-title":"Copper-based magnetic nanocatalysts for the catalytic transfer hydrogenation of biomass-derived furfural","volume":"689","author":"Gaete","year":"2025","journal-title":"Appl. Surf. Sci."},{"key":"ref_92","first-page":"30","article-title":"Research Progress on Failure Mechanism of Copper-based Catalysts in Electrocatalytic CO2 Reduction","volume":"4","author":"Zhang","year":"2024","journal-title":"Copp. Eng."},{"key":"ref_93","first-page":"1979","article-title":"Research Progress on Integral Catalysts Based on Reforming Hydrogen Production Technology","volume":"53","author":"Qiu","year":"2024","journal-title":"Contemp. Chem. Ind."},{"key":"ref_94","first-page":"36","article-title":"Application of SiO2@TiO2 catalyst support in hydrogen production by methanol reforming","volume":"39","author":"Duan","year":"2024","journal-title":"J. Southwest Univ. Sci. Technol."},{"key":"ref_95","doi-asserted-by":"crossref","unstructured":"Bouzayani, B., Lomba-Fern\u00e1ndez, B., Fdez-Sanrom\u00e1n, A., Elaoud, S.C., and Sanrom\u00e1n, M.\u00c1. (2024). Advancements in Copper-Based Catalysts for Efficient Generation of Reactive Oxygen Species from Peroxymonosulfate. Appl. Sci., 14.","DOI":"10.3390\/app14178075"},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"193","DOI":"10.9767\/bcrec.20341","article-title":"Harnessing Copper\u2019s Potential: A Review of Cu-Based Catalysts for Glycerol Conversion","volume":"20","author":"Ahmed","year":"2025","journal-title":"Bull. Chem. React. Eng. Catal."},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"756","DOI":"10.1016\/j.ijhydene.2024.02.176","article-title":"A robust kinetic modeling of CO2 hydrogenation to methanol over an industrial copper\u2013zinc oxide catalyst based on a single-active site mechanism","volume":"60","author":"Kouzehli","year":"2024","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_98","first-page":"9087","article-title":"Performance of CO2 Hydrogenation to Methanol from La-Cu\/ZnO\/ZrO2 Catalyst","volume":"55","author":"Huang","year":"2024","journal-title":"J. Funct. Mater."},{"key":"ref_99","first-page":"2499","article-title":"Research Progress on CO2-Catalyzed Hydrogenation of Metal-Organic Framework-Supported Metal Catalysts","volume":"54","author":"Yan","year":"2024","journal-title":"Sci. China Chem."},{"key":"ref_100","first-page":"15","article-title":"Research progress on electrocatalytic carbon dioxide reduction by copper-based catalysts","volume":"42","author":"Sun","year":"2024","journal-title":"J. Fujian Norm. Univ. Technol."},{"key":"ref_101","first-page":"48","article-title":"Research Progress on Electrocatalytic CO2 Reduction to Produce C+2 Products","volume":"44","author":"Liu","year":"2024","journal-title":"Mod. Chem. Ind."},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"9","DOI":"10.3866\/PKU.WHXB202406029","article-title":"Research progress on carbon dioxide conversion of copper-based photocatalysts","volume":"40","author":"Zhang","year":"2024","journal-title":"Acta Phys.-Chim. Sin."},{"key":"ref_103","first-page":"54","article-title":"Thermodynamic analysis of hydrogen production by methanol water vapor reforming under induction heating","volume":"24","author":"Wang","year":"2024","journal-title":"J. Contemp. Chem. Ind. Eng. Res."},{"key":"ref_104","first-page":"64","article-title":"Research Progress on Methanol Liquid Phase Reform Catalysts for Hydrogen Production","volume":"88","author":"Wu","year":"2025","journal-title":"Chin. Chem. Bull."},{"key":"ref_105","first-page":"238","article-title":"Study on the performance of chemical chain methanol oxidation steam reforming process","volume":"41","author":"Liu","year":"2025","journal-title":"Chem. React. Eng. Technol."},{"key":"ref_106","first-page":"15","article-title":"Catalytic performance of Cu\/SiO2 catalyst for hydrogen production by methanol steam reforming","volume":"46","author":"Du","year":"2025","journal-title":"Energy Chem. Ind."},{"key":"ref_107","first-page":"64","article-title":"Application of copper-based catalysts in electrocatalytic CO2 to C2+ products","volume":"45","author":"Jiang","year":"2025","journal-title":"Mod. Chem. Ind."},{"key":"ref_108","first-page":"104","article-title":"Research status and prospect of CO2 hydrogenation to methanol on copper-based catalysts","volume":"31","author":"Zhao","year":"2025","journal-title":"Clean Coal Technol."},{"key":"ref_109","doi-asserted-by":"crossref","first-page":"12983","DOI":"10.1016\/j.ijhydene.2019.03.136","article-title":"Catalyst modification strategies to enhance the catalyst activity and stability during steam reforming of acetic acid for hydrogen production","volume":"44","author":"Kumar","year":"2019","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_110","doi-asserted-by":"crossref","unstructured":"Tommasi, M., Ceriotti, D., Gramegna, A., Degerli, S.N., Ramis, G., and Rossetti, I. (2024). Oxidative Steam Reforming of Methanol over Cu-Based Catalysts. Catalysts, 14.","DOI":"10.3390\/catal14110759"},{"key":"ref_111","doi-asserted-by":"crossref","unstructured":"Nippes, R.P., Macruz, P.D., Domingues Gomes, A., de Souza, M., Ferreira, B.R., Rizzo-Domingues, R.C.P., and Ramos, L.P. (2024). Effect of Support on Steam Reforming of Ethanol for H2 Production with Copper-Based Catalysts. Processes, 12.","DOI":"10.20944\/preprints202405.2026.v1"},{"key":"ref_112","doi-asserted-by":"crossref","unstructured":"S\u0142owik, G., Rotko, M., Ryczkowski, J., and Greluk, M. (2024). Hydrogen production from methanol steam reforming over Fe-modified Cu\/CeO2 catalysts. Molecules, 29.","DOI":"10.3390\/molecules29163963"},{"key":"ref_113","doi-asserted-by":"crossref","first-page":"9188","DOI":"10.1021\/acscatal.4c02293","article-title":"K and Na promotion enables high-pressure low-temperature reverse water gas shift over copper-based catalysts","volume":"14","author":"Barberis","year":"2024","journal-title":"ACS Catal."},{"key":"ref_114","doi-asserted-by":"crossref","first-page":"822","DOI":"10.1016\/j.ijhydene.2024.09.030","article-title":"A comprehensive analysis of a compact-sized methanol cracking unit for hydrogen production","volume":"87","author":"Farooq","year":"2024","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_115","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.ijhydene.2024.01.188","article-title":"Experimental studies on hydrogen production from steam reforming of methanol integrated with metal hydride-based hydrogen purification system","volume":"76","author":"Achomo","year":"2024","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_116","doi-asserted-by":"crossref","first-page":"829","DOI":"10.1016\/j.ijhydene.2023.11.232","article-title":"GBL\/BDO pair as a bio-based liquid organic carrier: Kinetic modeling of liquid phase hydrogenation and dehydrogenation over copper-based catalyst","volume":"67","author":"Qasmi","year":"2024","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_117","doi-asserted-by":"crossref","first-page":"101949","DOI":"10.1016\/j.joei.2024.101949","article-title":"Autothermal reforming of methanol in a microreactor using porous alumina supported CuO\/ZnO with CeO2 sol catalysts washcoat","volume":"119","author":"Mdlovu","year":"2025","journal-title":"J. Energy Inst."},{"key":"ref_118","doi-asserted-by":"crossref","first-page":"132882","DOI":"10.1016\/j.fuel.2024.132882","article-title":"Development of CuO\/ZnO\/Al2O3-hydrotalcite\u2212 based catalysts for middle temperature water gas shift reaction: Impact of calcination temperature and residual carbonates","volume":"378","author":"Zonouz","year":"2024","journal-title":"Fuel"},{"key":"ref_119","doi-asserted-by":"crossref","first-page":"177879","DOI":"10.1016\/j.scitotenv.2024.177879","article-title":"Life cycle assessment on the role of H2S-based hydrogen via H2S-methane reforming for the production of sustainable fuels","volume":"958","author":"Chelvam","year":"2025","journal-title":"Sci. Total Environ."},{"key":"ref_120","doi-asserted-by":"crossref","unstructured":"Gwon, K., Lee, S., Kim, Y., Choi, J., Kim, S., Kim, S.-J., Hong, H.J., Hwang, Y., Mori, M., and Lee, D.N. (2023). Construction of a bioactive copper-based metal organic framework-embedded dual-crosslinked alginate hydrogel for antimicrobial applications. Int. J. Biol. Macromol., 242.","DOI":"10.1016\/j.ijbiomac.2023.124840"},{"key":"ref_121","doi-asserted-by":"crossref","unstructured":"Abdelhameed, R.M., El-Shahat, M., Abdel-Gawad, H., and Hegazi, B. (2023). Efficient phenolic compounds adsorption by immobilization of copper-based metal-organic framework anchored polyacrylonitrile\/chitosan beads. Int. J. Biol. Macromol., 240.","DOI":"10.1016\/j.ijbiomac.2023.124498"},{"key":"ref_122","doi-asserted-by":"crossref","unstructured":"Qian, Y., Wang, C., Xu, R., Wang, J., Chen, Q., Zhu, Z., Hu, Q., Shen, Q., and Shen, J.-W. (2025). Copper-based metal\u2013organic frameworks for antitumor application. J. Nanobiotechnol., 23.","DOI":"10.1186\/s12951-025-03220-5"},{"key":"ref_123","doi-asserted-by":"crossref","first-page":"111819","DOI":"10.1016\/j.inoche.2023.111819","article-title":"Effect and mechanism of inorganic anions on the adsorption of Cd2+ on two-dimensional copper-based metal\u2013organic framework","volume":"159","author":"Li","year":"2024","journal-title":"Inorg. Chem. Commun."},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"7784","DOI":"10.1039\/D4TC00558A","article-title":"Simple fabrication of laser-induced graphene functionalized with a copper-based metal\u2013organic framework and its application in solid-state supercapacitors","volume":"12","author":"Toral","year":"2024","journal-title":"J. Mater. Chem. C"},{"key":"ref_125","doi-asserted-by":"crossref","first-page":"144299","DOI":"10.1016\/j.electacta.2024.144299","article-title":"Enhanced oxygen evolution of a new copper-based metal-organic framework through the construction of a heterogeneous structure with bismuth oxyiodide","volume":"491","author":"Sajjadizadeh","year":"2024","journal-title":"Electrochim. Acta"},{"key":"ref_126","doi-asserted-by":"crossref","first-page":"123563","DOI":"10.1016\/j.seppur.2023.123563","article-title":"Ambient temperature NO2 removal by reversible NO2 adsorption on copper-based metal-organic frameworks (MOFs)-derived nanoporous adsorbents","volume":"314","author":"Sun","year":"2023","journal-title":"Sep. Purif. Technol."},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"704","DOI":"10.1039\/D4TA06757F","article-title":"Highly dispersed copper-based nanocomposite synthesis via spray pyrolysis: Towards waste-to-hydrogen production through the water-gas shift reaction","volume":"13","author":"Jeon","year":"2025","journal-title":"J. Mater. Chem. A"},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"8664","DOI":"10.1021\/acs.inorgchem.4c00188","article-title":"A Copper-Based Metal\u2013Organic Framework for Selective Separation of C2 Hydrocarbons from Methane at Ambient Conditions: Experiment and Simulation","volume":"63","author":"Islam","year":"2024","journal-title":"Inorg. Chem."},{"key":"ref_129","doi-asserted-by":"crossref","first-page":"109714","DOI":"10.1016\/j.cep.2024.109714","article-title":"Methanol compared to other fuels for on-board hydrogen production in thermally balanced membrane reactors with internal recycle","volume":"198","author":"Dawidowicz","year":"2024","journal-title":"Chem. Eng. Process.-Process Intensif."},{"key":"ref_130","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1016\/j.ijhydene.2025.01.053","article-title":"Hydrogen generation from coupled methanol steam reforming with metal hydride hydrolysis: Effects of metal catalysts and hydrides","volume":"102","author":"Kadeer","year":"2025","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_131","doi-asserted-by":"crossref","first-page":"114971","DOI":"10.1016\/j.cattod.2024.114971","article-title":"Influence of water steam and copper oxidation state on the CO2 hydrogenation to ethanol over copper catalysts","volume":"443","author":"Caldeira","year":"2024","journal-title":"Catal. Today"},{"key":"ref_132","doi-asserted-by":"crossref","first-page":"112325","DOI":"10.1016\/j.jece.2024.112325","article-title":"Synthesis and evaluation of novel Cu-based adsorbent-containing catalysts for CO2 hydrogenation to methanol and value-added products","volume":"12","author":"Ismail","year":"2024","journal-title":"J. Environ. Chem. Eng."}],"container-title":["Nanomaterials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2079-4991\/15\/14\/1118\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T18:12:07Z","timestamp":1760033527000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2079-4991\/15\/14\/1118"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,18]]},"references-count":132,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2025,7]]}},"alternative-id":["nano15141118"],"URL":"https:\/\/doi.org\/10.3390\/nano15141118","relation":{},"ISSN":["2079-4991"],"issn-type":[{"value":"2079-4991","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,18]]}}}