{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T09:41:36Z","timestamp":1786527696075,"version":"build-2736575974"},"reference-count":61,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T00:00:00Z","timestamp":1786492800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22509020"],"award-info":[{"award-number":["22509020"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"award":["22509020"],"award-info":[{"award-number":["22509020"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Sichuan Science and Technology Project","award":["2025ZDZX0085"],"award-info":[{"award-number":["2025ZDZX0085"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>The practical deployment of aqueous zinc-ion batteries (AZIBs) is critically limited by uneven Zn2+ flux, uncontrolled dendrite growth, and concurrent parasitic reactions\u2014notably the hydrogen evolution reaction (HER) and anode corrosion\u2014arising from interfacial and kinetic instability during repeated plating\/stripping cycles. These issues originate at the zinc anode\u2013electrolyte interface, underscoring the necessity of advanced interfacial engineering. Here, we report a surface-confined polyphenol-derived interphase formed on zinc foil through a 1 min dip treatment in a dilute aqueous solution of a commercial tea polyphenol (TP) mixture (0.02 M); after rinsing and drying, the modified electrode is cycled in a conventional electrolyte to which no TP is deliberately added. This interphase promotes more homogeneous nucleation behaviour through coordination between phenolic oxygen-containing moieties and Zn2+, improves electrolyte contact homogeneity and perturbs the local water structure to mitigate water-mediated parasitic reactions. The TP-derived surface modification creates a substantially altered interfacial charging environment (Cdl = 47.25 vs. 16.83 \u00b5F cm\u22122 for bare Zn) that facilitates more uniform zinc deposition. Symmetric cells with TP@Zn anodes demonstrated exceptional cycling stability exceeding 4000 h at 1 mA cm\u22122 and 1 mAh cm\u22122 (bare Zn fails within ~240 h under identical conditions), while TP@Zn\/\/V2O5 full cells retained 56.2% capacity after 300 cycles at 0.5 A g\u22121 with a higher median discharge voltage than bare Zn cells, substantially outperforming the latter (31.1% retention). Density functional theory calculations using the selected cluster models yield a markedly more negative electronic interaction energy for Zn2+ with an EGCG model ligand (\u221210.97 eV) than with H2O (\u22124.49 eV), qualitatively supporting preferential coordination of Zn2+ by phenolic oxygen sites. This work presents a green, facile and potentially scalable interfacial regulation strategy and advances the understanding of natural polyphenols as pre-formed surface conditioners for highly reversible metal anodes.<\/jats:p>","DOI":"10.3390\/nano16160992","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T09:11:36Z","timestamp":1786525896000},"page":"992","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ultrafast Tea Polyphenol Surface Conditioning Creates a Zincophilic Interphase for Durable Zinc Anodes"],"prefix":"10.3390","volume":"16","author":[{"given":"Yimin","family":"Jiang","sequence":"first","affiliation":[{"name":"Information Materials and Device Applications Key Laboratory of Sichuan Provincial Universities, Chengdu University of Information Technology, Chengdu 610225, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenxia","family":"Zhao","sequence":"additional","affiliation":[{"name":"Information Materials and Device Applications Key Laboratory of Sichuan Provincial Universities, Chengdu University of Information Technology, Chengdu 610225, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-1376-2605","authenticated-orcid":false,"given":"Luo","family":"Zhang","sequence":"additional","affiliation":[{"name":"Information Materials and Device Applications Key Laboratory of Sichuan Provincial Universities, Chengdu University of Information Technology, Chengdu 610225, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Guo","sequence":"additional","affiliation":[{"name":"Optoelectronic Sensor Devices and Systems Key Laboratory of Sichuan Provincial Universities, College of Optoelectronic Engineering (Chengdu IC Valley Industrial College), Chengdu University of Information Technology, Chengdu 610225, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Jiang","sequence":"additional","affiliation":[{"name":"Chengdu Product Quality Inspection and Research Institute Co., Ltd., Chengdu 610100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dingyu","family":"Yang","sequence":"additional","affiliation":[{"name":"Sichuan Meteorological Optoelectronic Sensor Technology and Application Engineering Research Center, Chengdu University of Information Technology, Chengdu 610225, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,8,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"13180","DOI":"10.1002\/anie.202000162","article-title":"Interfacial Design of Dendrite-Free Zinc Anodes for Aqueous Zinc-Ion Batteries","volume":"59","author":"Zhang","year":"2020","journal-title":"Angew. 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