{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,26]],"date-time":"2026-01-26T01:25:50Z","timestamp":1769390750740,"version":"3.49.0"},"reference-count":77,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2017,5,27]],"date-time":"2017-05-27T00:00:00Z","timestamp":1495843200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>In this work, we present the electrochemical deposition of manganese dioxide (MnO2) thin films on carbon-coated TiN\/Si micro-pillars. The carbon buffer layer, grown by plasma enhanced chemical vapor deposition (PECVD), is used as a protective coating for the underlying TiN current collector from oxidation, during the film deposition, while improving the electrical conductivity of the stack. A conformal electrolytic MnO2 (EMD) coating is successfully achieved on high aspect ratio C\/TiN\/Si pillar arrays by tailoring the deposition process. Lithiation\/Delithiation cycling tests have been performed. Reversible insertion and extraction of Li+ through EMD structure are observed. The fabricated stack is thus considered as a good candidate not only for 3D micorbatteries but also for other energy storage applications.<\/jats:p>","DOI":"10.3390\/nano7060126","type":"journal-article","created":{"date-parts":[[2017,5,30]],"date-time":"2017-05-30T04:35:42Z","timestamp":1496118942000},"page":"126","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Electrolytic Manganese Dioxide Coatings on High Aspect Ratio Micro-Pillar Arrays for 3D Thin Film Lithium Ion Batteries"],"prefix":"10.3390","volume":"7","author":[{"given":"Yafa","family":"Zargouni","sequence":"first","affiliation":[{"name":"KACST-Intel Consortium Centre of Excellence in Nano-Manufacturing and Applications (CENA), Riyadh 11442, Saudi Arabia"},{"name":"Imec, Kapeldreef 75, B-3001 Leuven, Belgium"},{"name":"Laboratoire de Chimie Analytique et D\u2019\u00e9lectrochimie, Facult\u00e9 des Sciences de Tunis, Universit\u00e9 de Tunis-El-Manar, Tunis 2092, Tunisie"},{"name":"KU Leuven, Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, Kasteelpark Arenberg 23 bus 2461, B-3001 Leuven, Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stella","family":"Deheryan","sequence":"additional","affiliation":[{"name":"Imec, Kapeldreef 75, B-3001 Leuven, Belgium"},{"name":"KU Leuven, Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, Kasteelpark Arenberg 23 bus 2461, B-3001 Leuven, Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alex","family":"Radisic","sequence":"additional","affiliation":[{"name":"Imec, Kapeldreef 75, B-3001 Leuven, Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Khaled","family":"Alouani","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Analytique et D\u2019\u00e9lectrochimie, Facult\u00e9 des Sciences de Tunis, Universit\u00e9 de Tunis-El-Manar, Tunis 2092, Tunisie"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Philippe","family":"Vereecken","sequence":"additional","affiliation":[{"name":"Imec, Kapeldreef 75, B-3001 Leuven, Belgium"},{"name":"KU Leuven, Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, Kasteelpark Arenberg 23 bus 2461, B-3001 Leuven, Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2017,5,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"9876","DOI":"10.1039\/c0jm04396f","article-title":"3D Lithium Ion Batteries\u2014From Fundamentals to Fabrication","volume":"21","author":"Roberts","year":"2011","journal-title":"J. Mater. Chem."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"2419","DOI":"10.1016\/j.jpowsour.2009.11.048","article-title":"Lithium Batteries: Status, Prospects and Future","volume":"195","author":"Scrosati","year":"2010","journal-title":"J. Power Sources"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"366","DOI":"10.1038\/nmat1368","article-title":"Nanostructured Materials for Advanced Energy Conversion and Storage Devices","volume":"4","author":"Bruce","year":"2005","journal-title":"Nat. Mater."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"330","DOI":"10.1016\/j.jpowsour.2015.03.164","article-title":"Lithium and Lithium Ion Batteries for Applications in Microelectronic Devices: A Review","volume":"286","author":"Wang","year":"2015","journal-title":"J. Power Sources"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1149\/05810.0111ecst","article-title":"Conformal Deposition For 3D Thin-Film Batteries","volume":"58","author":"Vereecken","year":"2013","journal-title":"ECS Trans."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"652","DOI":"10.1038\/451652a","article-title":"Building Better Batteries","volume":"451","author":"Armand","year":"2008","journal-title":"Nature"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1557\/mrs.2011.156","article-title":"Three-Dimensional Electrodes and Battery Architectures","volume":"36","author":"Arthur","year":"2011","journal-title":"MRS Bull."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"9281","DOI":"10.1039\/c3ta11921a","article-title":"Electrochemical Elaboration of Electrodes and Electrolytes for 3D Structured Batteries","volume":"1","author":"Valvo","year":"2013","journal-title":"J. Mater. Chem. A"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1016\/j.tsf.2014.03.069","article-title":"On the Electrophoretic and Sol-Gel Deposition of Active Materials on Aluminium Rod Current Collectors for Three-Dimensional Li-Ion Micro-Batteries","volume":"562","author":"Oltean","year":"2014","journal-title":"Thin Solid Films"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1149\/06109.0029ecst","article-title":"Electrodeposition and Characterization of Manganese Dioxide Thin Films on Silicon Pillar Arrays for 3D Thin-Film Lithium-Ion Batteries","volume":"61","author":"Zargouni","year":"2014","journal-title":"ECS Trans."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"A54","DOI":"10.1149\/2.003406eel","article-title":"A Li-Ion Microbattery with 3D Electrodes of Different Geometries","volume":"3","author":"Oltean","year":"2014","journal-title":"ECS Electrochem. Lett."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"D515","DOI":"10.1149\/2.0511410jes","article-title":"Electrodeposition of Vanadium Oxide\/Manganese Oxide Hybrid Thin Films on Nanostructured Aluminum Substrates","volume":"161","author":"Rehnlund","year":"2014","journal-title":"J. Electrochem. Soc."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/aenm.201300882","article-title":"Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review","volume":"4","author":"Su","year":"2014","journal-title":"Adv. Energy Mater."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1016\/j.mee.2014.10.019","article-title":"An Overview of Through-Silicon-via Technology and Manufacturing Challenges","volume":"135","author":"Gambino","year":"2015","journal-title":"Microelectron. Eng."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"844","DOI":"10.1109\/JMEMS.2007.901638","article-title":"Fabrication of High-Aspect-Ratio Electrode Arrays for Three-Dimensional Microbatteries","volume":"16","author":"Chamran","year":"2007","journal-title":"J. Microelectromechanical Syst."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"295","DOI":"10.1117\/12.548755","article-title":"Carbon-MEMS Architectures for 3D Microbatteries","volume":"5455","author":"Wang","year":"2004","journal-title":"Proc. SPIE"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"4564","DOI":"10.1002\/adma.200702398","article-title":"3-D Integrated All-Solid-State Rechargeable Batteries","volume":"19","author":"Notten","year":"2007","journal-title":"Adv. Mater."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"A2105","DOI":"10.1149\/1.2039587","article-title":"Current Collectors for Positive Electrodes of Lithium-Based Batteries","volume":"152","author":"Whitehead","year":"2005","journal-title":"J. Electrochem. Soc."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1","DOI":"10.33961\/JECST.2015.6.1.1","article-title":"Current Collectors for Flexible Lithium Ion Batteries: A Review of Materials","volume":"6","author":"Kim","year":"2015","journal-title":"J. Electrochem. Sci. Technol."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"493","DOI":"10.1149\/2.0051504jes","article-title":"Sputtered Titanium Nitride: A Bifunctional Material for Li-Ion Microbatteries","volume":"162","author":"Freixas","year":"2015","journal-title":"J. Electrochem. Soc."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1002\/aenm.201000002","article-title":"All-Solid-State Lithium-Ion Microbatteries: A Review of Various Three-Dimensional Concepts","volume":"1","author":"Oudenhoven","year":"2011","journal-title":"Adv. Energy Mater."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1038\/ncomms12647","article-title":"Architectures for Future Hybrid Energy Storage","volume":"7","author":"Lukatskaya","year":"2016","journal-title":"Nat. Commun."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"2811","DOI":"10.1016\/j.ssi.2006.02.048","article-title":"Progress in Three-Dimensional (3D) Li-Ion Microbatteries","volume":"177","author":"Golodnitsky","year":"2006","journal-title":"Solid State Ionics"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"567","DOI":"10.1038\/nmat1672","article-title":"High Rate Capabilities Fe3O4-Based Cu Nano-Architectured Electrodes for Lithium-Ion Battery Applications","volume":"5","author":"Taberna","year":"2006","journal-title":"Nat. Mater."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"3329","DOI":"10.1021\/nl2017042","article-title":"Building Energy Storage Device on a Single Nanowire","volume":"11","author":"Gowda","year":"2011","journal-title":"Nano Lett."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"4779","DOI":"10.1016\/j.jpowsour.2011.01.029","article-title":"Synthesis and Rate Performance of Fe3O4-Based Cu Nanostructured Electrodes for Li-Ion Batteries","volume":"196","author":"Duan","year":"2011","journal-title":"J. Power Sources"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"504008","DOI":"10.1088\/0957-4484\/25\/50\/504008","article-title":"Nanostructured TiO2\/carbon Nanosheet Hybrid Electrode for High-Rate Thin-Film Lithium-Ion Batteries","volume":"25","author":"Moitzheim","year":"2014","journal-title":"Nanotechnology"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1149\/2.F05112if","article-title":"Electrodeposition as a Tool for 3D Microbattery Fabrication","volume":"20","author":"Brandell","year":"2011","journal-title":"Electrochem. Soc. Interface"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"10801","DOI":"10.1116\/1.3660699","article-title":"Atomic Layer Deposition for Nanostructured Li-Ion Batteries","volume":"30","author":"Knoops","year":"2012","journal-title":"J. Vac. Sci. Technol. A Vac. Surf. Film."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"24001","DOI":"10.1088\/0957-4484\/26\/2\/024001","article-title":"Elegant Design of Electrode and Electrode\/electrolyte Interface in Lithium-Ion Batteries by Atomic Layer Deposition","volume":"26","author":"Liu","year":"2015","journal-title":"Nanotechnology"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1889","DOI":"10.1039\/C5EE01254F","article-title":"Chemical Vapor Deposition and Atomic Layer Deposition for Advanced Lithium Ion Batteries and Supercapacitors","volume":"8","author":"Wang","year":"2015","journal-title":"Energy Environ. Sci."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1016\/j.jpowsour.2013.08.042","article-title":"Significant Impact on Cathode Performance of Lithium-Ion Batteries by Precisely Controlled Metal Oxide Nanocoatings via Atomic Layer Deposition","volume":"247","author":"Li","year":"2014","journal-title":"J. Power Sources"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"4669","DOI":"10.1021\/cm200899k","article-title":"Atomic Layer Deposition of Li2O\u2013Al2O3 Thin Films","volume":"23","author":"Aaltonen","year":"2011","journal-title":"Chem. Mater."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0079-6786(97)81003-5","article-title":"Manganese Oxides for Lithium Batteries","volume":"25","author":"Thackeray","year":"1997","journal-title":"Prog. Solid State Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"1002","DOI":"10.1021\/nl803081j","article-title":"Coaxial MnO2\/carbon Nanotube Array Electrodes for High-Performance Lithium Batteries","volume":"9","author":"Reddy","year":"2009","journal-title":"Nano Lett."},{"key":"ref_36","unstructured":"Garcia, E., Lins, V., and Matencio, T. (2013). Metallic and Oxide Electrodeposition. Mod. Surf. Eng. Treat., 101\u2013122."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/S1452-3981(23)17131-8","article-title":"Synthesis of Spinel LiMn2O4 for Li-Ion Batteries via Sol\u2013Gel Process","volume":"1","author":"He","year":"2006","journal-title":"Int. J. Electrochem. Soc."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"58255","DOI":"10.1039\/C5RA05892A","article-title":"Electrolytic Manganese Dioxide (EMD): A Perspective on Worldwide Production, Reserves and Its Role in Electrochemistry","volume":"5","author":"Biswal","year":"2015","journal-title":"RSC Adv."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1007\/BF02354981","article-title":"Recent Advances in Lithium Solid State Batteries","volume":"2","author":"Scrosati","year":"1972","journal-title":"J. Appl. Electrochem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0079-6786(94)00005-2","article-title":"Structural and Electrochemical Properties of the Proton\/\u03b3-MnO2 System","volume":"23","author":"Chabre","year":"1995","journal-title":"Prog. Solid State Chem."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"943","DOI":"10.1002\/1521-4095(200107)13:12\/13<943::AID-ADMA943>3.0.CO;2-J","article-title":"Novel Lithium-Ion Cathode Materials Based on Layered Manganese Oxides","volume":"13","author":"Ammundsen","year":"2001","journal-title":"Adv. Mater."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/j.electacta.2013.12.014","article-title":"Nucleation and Growth of Electrodeposited Manganese Dioxide for Electrochemical Capacitors","volume":"120","author":"Dupont","year":"2014","journal-title":"Electrochim. Acta"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"4711","DOI":"10.1039\/C5CP07141K","article-title":"Correlation among Physical and Electrochemical Behaviour of Nanostructured Electrolytic Manganese Dioxide from Leach Liquor and Synthetic for Aqueous Asymmetric Capacitor","volume":"18","author":"Biswal","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"9771","DOI":"10.1038\/srep09771","article-title":"3D Hierarchical Assembly of Ultrathin MnO2 Nanoflakes on Silicon Nanowires for High Performance Micro-Supercapacitors in Li-Doped Ionic Liquid","volume":"5","author":"Dubal","year":"2015","journal-title":"Sci. Rep."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"14073","DOI":"10.1021\/jp500939d","article-title":"Evaluation of MnOX, Mn2O3, and Mn3O4 Electrodeposited Films for the Oxygen Evolution Reaction of Water","volume":"118","author":"Hillebrand","year":"2014","journal-title":"J. Phys. Chem. C"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1195","DOI":"10.1007\/s10800-008-9537-z","article-title":"Durability of Carbon-Supported Manganese Oxide Nanoparticles for the Oxygen Reduction Reaction (ORR) in Alkaline Medium","volume":"38","author":"Roche","year":"2008","journal-title":"J. Appl. Electrochem."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"289","DOI":"10.1016\/0378-7753(93)80126-A","article-title":"The Versatility of MnO2 for Lithium Battery Applications","volume":"43","author":"Thackeray","year":"1993","journal-title":"J. Power Sources"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"A905","DOI":"10.1149\/1.3597640","article-title":"Thermal Treatment Effects on Manganese Dioxide Structure, Morphology and Electrochemical Performance","volume":"158","author":"Dose","year":"2011","journal-title":"J. Electrochem. Soc."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1007\/s10973-011-1445-5","article-title":"Kinetic Analysis of \u03b3-MnO2 Thermal Treatment","volume":"105","author":"Dose","year":"2011","journal-title":"J. Therm. Anal. Calorim."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"A1539","DOI":"10.1149\/1.1943607","article-title":"The Effect of Heat-Treatment on Electrolytic Manganese Dioxide: A 2H and 6Li Magic Angle Spinning NMR Study","volume":"152","author":"Paik","year":"2005","journal-title":"J. Electrochem. Soc."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"9889","DOI":"10.1021\/jp4105008","article-title":"Effect of Film Morphology on the Li-Ion Intercalation Kinetics in Anodic Porous Manganese Dioxide Thin Films","volume":"118","author":"Etman","year":"2014","journal-title":"J. Phys. Chem. C"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"A538","DOI":"10.1149\/2.1431702jes","article-title":"Nanometer-Thin Graphitic Carbon Buffer Layers for Electrolytic MnO2 for Thin-Film Energy Storage Devices","volume":"164","author":"Deheryan","year":"2017","journal-title":"J. Electrochem. Soc."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"976","DOI":"10.1002\/celc.201600071","article-title":"Electrodeposition of Sea Urchin and Cauliflower-like Nickel-\/Cobalt-Doped Manganese Dioxide Hierarchical Nanostructures with Improved Energy-Storage Behavior","volume":"3","author":"Biswal","year":"2016","journal-title":"ChemElectroChem"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"1600","DOI":"10.1016\/j.physe.2009.05.009","article-title":"Fabrication of Highly Ordered Metallic Arrays and Silicon Pillars with Controllable Size Using Nanosphere Lithography","volume":"41","author":"Li","year":"2009","journal-title":"Phys. E-Low-Dimensional Syst. Nanostruct."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"4564","DOI":"10.1002\/aenm.201500680","article-title":"MnO2 Thin Films on 3D Scaffold: Microsupercapacitor Electrodes Competing with \u201cBulk\u201d Carbon Electrodes","volume":"5","author":"Eustache","year":"2015","journal-title":"Adv. Energy Mater."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"574","DOI":"10.1016\/j.electacta.2014.03.148","article-title":"Direct Correlation between the Measured Electrochemical Capacitance, Wettability and Surface Functional Groups of CarbonNanosheets","volume":"132","author":"Deheryan","year":"2014","journal-title":"Electrochim. Acta"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1016\/j.carbon.2013.02.030","article-title":"Synthesis of Large Area Carbon Nanosheets for Energy Storage Applications","volume":"58","author":"Cott","year":"2013","journal-title":"Carbon"},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"N8","DOI":"10.1149\/2.008403ssl","article-title":"Large Area Carbon Nanosheet Capacitors","volume":"3","author":"Qaid","year":"2014","journal-title":"ECS Solid State Lett."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"1278","DOI":"10.1021\/cr800344k","article-title":"Raman Microspectrometry Applied to the Study of Electrode Materials for Lithium Batteries","volume":"110","year":"2010","journal-title":"Chem. Rev."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"590","DOI":"10.1016\/j.elecom.2011.03.017","article-title":"Conformal MnO2 Electrodeposition onto Defect-Free Graphitic Carbons","volume":"13","author":"Perez","year":"2011","journal-title":"Electrochem. Commun."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"7904","DOI":"10.1016\/j.jpowsour.2010.06.060","article-title":"A Review of Conduction Phenomena in Li-Ion Batteries","volume":"195","author":"Park","year":"2010","journal-title":"J. Power Sources"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"8646","DOI":"10.1021\/ja301586m","article-title":"Diffusion Mechanism of Lithium Ion through Basal Plane of Layered Graphene","volume":"134","author":"Yao","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1016\/S0378-7753(01)00777-7","article-title":"Effect of Bath Temperature on Electrochemical Properties of the Anodically Deposited Manganese Dioxide","volume":"102","author":"Ghaemi","year":"2001","journal-title":"J. Power Sources"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"6671","DOI":"10.1016\/j.apsusc.2008.04.044","article-title":"Microstructure and Properties of Manganese Dioxide Films Prepared by Electrodeposition","volume":"254","author":"Jacob","year":"2008","journal-title":"Appl. Surf. Sci."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"10153","DOI":"10.1039\/c0jm04357e","article-title":"Conformal Electrodeposition of Manganese Dioxide onto Reticulated Vitreous Carbon for 3D Microbattery Applications","volume":"21","author":"Johns","year":"2011","journal-title":"J. Mater. Chem."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"343","DOI":"10.1016\/j.electacta.2015.04.036","article-title":"Mesoscale Morphological Control of Electrodeposited Manganese Dioxide Films","volume":"170","author":"Gibson","year":"2015","journal-title":"Electrochim. Acta"},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"845","DOI":"10.1038\/nmat2297","article-title":"Materials for Electrochemical Capacitors","volume":"7","author":"Simon","year":"2008","journal-title":"Nat. Mater"},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"1130","DOI":"10.1021\/am900094e","article-title":"Microstructural Effects on Charge-Storage Properties in MnO2-Based Electrochemical Supercapacitors","volume":"1","author":"Ghodbane","year":"2009","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"1597","DOI":"10.1039\/c3ee44164d","article-title":"Pseudocapacitive Oxide Materials for High-Rate Electrochemical Energy Storage","volume":"7","author":"Augustyn","year":"2014","journal-title":"Energy Environ. Sci."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"656","DOI":"10.1016\/S0378-7753(99)00095-6","article-title":"\u03b3-MnO2 for Li Batteries: Part I. \u03b3-MnO2: Relationships between Synthesis Conditions, Material Characteristics and Performances in Lithium Batteries","volume":"81\u201382","author":"Sarciaux","year":"1999","journal-title":"J. Power Sources"},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"661","DOI":"10.1016\/S0378-7753(98)00230-4","article-title":"\u03b3-MnO2 for Li Batteries Part II. Some Aspects of the Lithium Insertion Process into \u03b3-MnO2 and Electrochemically Lithiated \u03b3-LixMnO2 Compounds","volume":"81\u201382","author":"Sarciaux","year":"1999","journal-title":"J. Power Sources"},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1016\/j.mseb.2014.11.014","article-title":"Fundamental Degradation Mechanisms of Layered Oxide Li-Ion Battery Cathode Materials: Methodology, Insights and Novel Approaches","volume":"192","author":"Hausbrand","year":"2015","journal-title":"Mater. Sci. Eng. B Solid-State Mater. Adv. Technol."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"32639","DOI":"10.1038\/srep32639","article-title":"Elucidating the Performance Limitations of Lithium-Ion Batteries due to Species and Charge Transport through Five Characteristic Parameters","volume":"6","author":"Jiang","year":"2016","journal-title":"Sci. Rep."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1016\/j.jpowsour.2012.08.043","article-title":"Optimizing Li\/MnO2 Batteries: Relating Manganese Dioxide Properties and Electrochemical Performance","volume":"221","author":"Dose","year":"2013","journal-title":"J. Power Sources"},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1149\/2.F07081IF","article-title":"Manganese Oxides: Battery Materials Make the Leap to Electrochemical Capacitors","volume":"17","author":"Brousse","year":"2008","journal-title":"Electrochem. Soc. Interface"},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1016\/j.ssi.2008.02.057","article-title":"Incorporation of TiB2 Additive into MnO2 Cathode and Its Influence on Rechargeability in an Aqueous Battery System","volume":"179","author":"Minakshi","year":"2008","journal-title":"Solid State Ionics"},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"852","DOI":"10.1016\/j.jpowsour.2013.08.142","article-title":"Optimising Heat Treatment Environment and Atmosphere of Electrolytic Manganese Dioxide for Primary Li\/MnO2 Batteries","volume":"247","author":"Dose","year":"2014","journal-title":"J. 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