{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T08:25:47Z","timestamp":1773390347978,"version":"3.50.1"},"reference-count":47,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2018,5,14]],"date-time":"2018-05-14T00:00:00Z","timestamp":1526256000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21774029"],"award-info":[{"award-number":["21774029"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21774107"],"award-info":[{"award-number":["21774107"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"National Science Foundation of Hubei Province of China","award":["2016CFB104"],"award-info":[{"award-number":["2016CFB104"]}]},{"name":"High Level Master Degree Thesis Cultivation Project of Hubei Engineering University","award":["201705"],"award-info":[{"award-number":["201705"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>We describe here the preparation of copper nanoparticles stabilized on a chitosan\/poly (vinyl alcohol) composite film. This material could catalyze the borylation of \u03b1,\u03b2-unsaturated acceptors in aqueous media under mild conditions. The corresponding organoboron compounds as well as their converted \u03b2-hydroxyl products were all obtained in good to excellent yields. It is noteworthy that this catalyst of copper nanoparticles can be easily recycled eight times and remained catalytically reactive. This newly developed methodology provides an efficient and sustainable pathway for the synthesis of organoboron compounds and application of copper nanoparticles.<\/jats:p>","DOI":"10.3390\/nano8050326","type":"journal-article","created":{"date-parts":[[2018,5,14]],"date-time":"2018-05-14T07:04:51Z","timestamp":1526281491000},"page":"326","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Borylation of \u03b1,\u03b2-Unsaturated Acceptors by Chitosan Composite Film Supported Copper Nanoparticles"],"prefix":"10.3390","volume":"8","author":[{"given":"Wu","family":"Wen","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Hubei Collaborative Innovation Center of Conversion and Utilization for Biomass Resources, Xiaogan 432000, China"},{"name":"School of Materials Science and Engineering, Hubei University, Wuhan 430062, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Biao","family":"Han","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Hubei Collaborative Innovation Center of Conversion and Utilization for Biomass Resources, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Feng","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Hubei Collaborative Innovation Center of Conversion and Utilization for Biomass Resources, Xiaogan 432000, China"},{"name":"School of Materials Science and Engineering, Hubei University, Wuhan 430062, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liang","family":"Ding","sequence":"additional","affiliation":[{"name":"Department of Polymer and Composite Material, Yancheng Institute of Technology, School of Materials Engineering, Yancheng 224051, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bojie","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Hubei Collaborative Innovation Center of Conversion and Utilization for Biomass Resources, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liansheng","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Hubei Collaborative Innovation Center of Conversion and Utilization for Biomass Resources, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4399-1855","authenticated-orcid":false,"given":"Lei","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Hubei Collaborative Innovation Center of Conversion and Utilization for Biomass Resources, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2018,5,14]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2457","DOI":"10.1021\/cr00039a007","article-title":"Palladium-catalyzed cross-coupling reactions of organoboron compounds","volume":"95","author":"Miyaura","year":"1995","journal-title":"Chem. 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