{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,28]],"date-time":"2026-10-28T03:00:50Z","timestamp":1793156450755,"version":"4.5.0"},"reference-count":58,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2023,3,2]],"date-time":"2023-03-02T00:00:00Z","timestamp":1677715200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Russian Science Foundation","award":["21-13-00437"],"award-info":[{"award-number":["21-13-00437"]}]},{"name":"Russian Science Foundation","award":["075-03-2023-642"],"award-info":[{"award-number":["075-03-2023-642"]}]},{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["21-13-00437"],"award-info":[{"award-number":["21-13-00437"]}]},{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["075-03-2023-642"],"award-info":[{"award-number":["075-03-2023-642"]}]},{"name":"Center for Molecular Composition Studies of INEOS RAS","award":["21-13-00437"],"award-info":[{"award-number":["21-13-00437"]}]},{"name":"Center for Molecular Composition Studies of INEOS RAS","award":["075-03-2023-642"],"award-info":[{"award-number":["075-03-2023-642"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Pharmaceutics"],"abstract":"<jats:p>New hybrid materials based on Ag nanoparticles stabilized by a polyaminopropylalkoxysiloxane hyperbranched polymer matrix were prepared. The Ag nanoparticles were synthesized in 2-propanol by metal vapor synthesis (MVS) and incorporated into the polymer matrix using metal-containing organosol. MVS is based on the interaction of extremely reactive atomic metals formed by evaporation in high vacuum (10\u22124\u201310\u22125 Torr) with organic substances during their co-condensation on the cooled walls of a reaction vessel. Polyaminopropylsiloxanes with hyperbranched molecular architectures were obtained in the process of heterofunctional polycondensation of the corresponding AB2-type monosodiumoxoorganodialkoxysilanes derived from the commercially available aminopropyltrialkoxysilanes. The nanocomposites were characterized using transmission (TEM) and scanning (SEM) electron microscopy, X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (PXRD) and Fourier-transform infrared spectroscopy (FTIR). TEM images show that Ag nanoparticles stabilized in the polymer matrix have an average size of 5.3 nm. In the Ag-containing composite, the metal nanoparticles have a \u201ccore-shell\u201d structure, in which the \u201ccore\u201d and \u201cshell\u201d represent the M0 and M\u03b4+ states, respectively. Nanocomposites based on silver nanoparticles stabilized with amine-containing polyorganosiloxane polymers showed antimicrobial activity against Bacillus subtilis and Escherichia coli.<\/jats:p>","DOI":"10.3390\/pharmaceutics15030809","type":"journal-article","created":{"date-parts":[[2023,3,2]],"date-time":"2023-03-02T03:54:56Z","timestamp":1677729296000},"page":"809","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Hybrid Materials with Antimicrobial Properties Based on Hyperbranched Polyaminopropylalkoxysiloxanes Embedded with Ag Nanoparticles"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8225-647X","authenticated-orcid":false,"given":"Alexander","family":"Vasil\u2019kov","sequence":"first","affiliation":[{"name":"A. N. Nesmeyanov Institute of Organoelement Compounds, RAS, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6063-8677","authenticated-orcid":false,"given":"Dmitry","family":"Migulin","sequence":"additional","affiliation":[{"name":"Enikolopov Institute of Synthetic Polymeric Materials, RAS, 117393 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5696-5723","authenticated-orcid":false,"given":"Alexander","family":"Naumkin","sequence":"additional","affiliation":[{"name":"A. N. Nesmeyanov Institute of Organoelement Compounds, RAS, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ilya","family":"Volkov","sequence":"additional","affiliation":[{"name":"A. N. 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Gause Institute of New Antibiotics, 119021 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3050-3253","authenticated-orcid":false,"given":"Aziz","family":"Muzafarov","sequence":"additional","affiliation":[{"name":"A. N. Nesmeyanov Institute of Organoelement Compounds, RAS, 119991 Moscow, Russia"},{"name":"Enikolopov Institute of Synthetic Polymeric Materials, RAS, 117393 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,3,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"220","DOI":"10.1007\/s11094-015-1260-6","article-title":"Prospects for using gold, silver, and iron oxide nanoparticles for increasing the efficacy of chemotherapy","volume":"49","author":"Fedotcheva","year":"2015","journal-title":"Pharm. Chem. 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