{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,4]],"date-time":"2025-12-04T06:10:56Z","timestamp":1764828656996,"version":"build-2065373602"},"reference-count":44,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2019,1,8]],"date-time":"2019-01-08T00:00:00Z","timestamp":1546905600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51603096,  21663015"],"award-info":[{"award-number":["51603096,  21663015"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>A simple and versatile route for industrial scale synthesis of adipicdihydrazide (ADH)\/polymer hybrids with excellent performance of formaldehyde degradation is proposed in this paper. The ADH compound is uniformly dispersed in poly(methyl methacrylate-butyl acrylate-methacrylic acid) (P(MMA-BA-MAA)) latex, which is validated by UV and dispersibility tests. The results illustrate that ADH has excellent compatibility and dispersion stability without affecting the film formation of the polymer latex. Furthermore, scanning electron microscope (SEM) and mapping analysis of the hybrid films also demonstrate that ADH is homogenously dispersed in the polymer matrix. Compared with neat polymers, the thermal properties of hybrid films are improved, for example, T0.5 increases by 8.3 \u00b0C. According to qualitative tests of the 4-amino-3-hydrazino-5-mercapto-1,2,4-triazol-red\/green\/blue (AHMT-RGB) method, the hybrid films demonstrate high formaldehyde removal efficiency. On the basis of the semi-quantitative test of Fourier Transform infrared spectroscopy (FTIR) measurements, the rate of formaldehyde degradation can reach 1.034 \u00d7 102 mol\/(h\u00b7m3) for the hybrid film with 5 wt% ADH.<\/jats:p>","DOI":"10.3390\/polym11010086","type":"journal-article","created":{"date-parts":[[2019,1,9]],"date-time":"2019-01-09T03:06:06Z","timestamp":1547003166000},"page":"86","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["An Industrial Scale Synthesis of Adipicdihydrazide (ADH)\/Polyacrylate Hybrid with Excellent Formaldehyde Degradation Performance"],"prefix":"10.3390","volume":"11","author":[{"given":"Rui","family":"Zhu","sequence":"first","affiliation":[{"name":"Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China"},{"name":"The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Renjie","family":"Chen","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China"},{"name":"The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yunxia","family":"Duo","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China"},{"name":"The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Saigang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China"},{"name":"The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5766-8210","authenticated-orcid":false,"given":"Delong","family":"Xie","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China"},{"name":"The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7224-597X","authenticated-orcid":false,"given":"Yi","family":"Mei","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China"},{"name":"The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2019,1,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"4775","DOI":"10.15376\/biores.8.3.4775-4790","article-title":"Understanding of Formaldehyde Emissions from Solid Wood: An Overview","volume":"8","author":"Salem","year":"2013","journal-title":"Bioresource"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1186\/s40066-018-0166-4","article-title":"Concentration and Formation Behavior of Naturally Occurring Formaldehyde in Foods","volume":"7","author":"Nowshad","year":"2018","journal-title":"Agric. Food Secur."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1016\/j.foodchem.2016.01.136","article-title":"Determination of Formaldehyde in Food and Feed by an In-house Validated HPLC Method","volume":"202","author":"Wahed","year":"2016","journal-title":"Food Chem."},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Mei, Y.F., Duan, C.L., Li, X.X., Zhao, Y., Cao, F.H., Shang, S., Ding, S.M., Yue, X.P., Gao, G., and Yang, H. (2016). Reduction of Endogenous Melatonin Accelerates Cognitive Decline in Mice in a Simulated Occupational Formaldehyde Exposure Environment. Int. J. Environ. Res. Public Health, 13.","DOI":"10.3390\/ijerph13030258"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1111\/j.1432-1033.1978.tb20906.x","article-title":"The Disposition of Formaldehyde and Formate Arising from Drug N-Demethylations Dependent on Cytochrome P-450 in Hepatocytes and in Perfused Rat Liver","volume":"89","author":"Waydhas","year":"1978","journal-title":"Eur. J. Biochem."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"98","DOI":"10.3844\/ajptsp.2009.98.106","article-title":"The Health Risk of Formaldehyde to Human Beings","volume":"4","author":"Norliana","year":"2009","journal-title":"Am. J. Pharmacol. Toxicol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"2536","DOI":"10.1021\/cr800399g","article-title":"Formaldehyde in Indoor Environment","volume":"110","author":"Salthammer","year":"2010","journal-title":"Chem. Rev."},{"key":"ref_8","doi-asserted-by":"crossref","unstructured":"Kim, J., Kim, H., Lim, D., Lee, Y.K., and Kim, J.H. (2016). Effects of Indoor Air Pollutants on Atopic Dermatitis. Int. J. Environ. Res. Public Health, 13.","DOI":"10.3390\/ijerph13121220"},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Chen, X.Y., Li, F., Liu, C.Y., Yang, J., Zhang, J.D., and Peng, C.L. (2017). Monitoring, Human Health Risk Assessment and Optimized Management for Typical Pollutants in Indoor Air from Random Families of University Staff, Wuhan City, China. Sustainability, 9.","DOI":"10.3390\/su9071115"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1126\/science.6857273","article-title":"Indoor air pollution: A public health perspective","volume":"221","author":"Spengler","year":"1983","journal-title":"Science"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"942","DOI":"10.1016\/j.biortech.2010.09.042","article-title":"Study on Activated Carbon Derived from Sewage Sludge for Absorption of Gaseous Formaldehyde","volume":"102","author":"Wen","year":"2011","journal-title":"Bioresour. Technol."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"5543","DOI":"10.1016\/S1352-2310(02)00670-2","article-title":"Oxidative Decomposition of Dormaldehyde by Metal Oxides at Room Temperature","volume":"36","author":"Sekine","year":"2002","journal-title":"Atmos. Environ."},{"key":"ref_13","unstructured":"Liu, Y. (2009). Study on Properties and Application of Amine Formaldehyde Fixative, Chang\u2019an University."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1657","DOI":"10.1016\/j.jece.2017.02.033","article-title":"Silver Nano-particles Deposited on Bamboo-based Activated Carbon for Removal of Formaldehyde","volume":"5","author":"Rengga","year":"2017","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_15","unstructured":"He, B.J. (2016). Preparation and Properties Investigation of Formaldehyde-Eliminative Wood Coatings, South China University of Technology."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"3449","DOI":"10.1021\/ma00011a063","article-title":"New High Refractive Index Organic\/Inorganic Hybrid Materials from Sol-Gel Processing","volume":"24","author":"Wang","year":"1991","journal-title":"Macromolecules"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"262","DOI":"10.1016\/j.materresbull.2017.01.050","article-title":"Pt-TiO2, microspheres with exposed {001 facets for degradation of formaldehyde in air: Formation mechanism and enhanced visible light photocatalytic activity","volume":"96","author":"Wang","year":"2017","journal-title":"Mater. Res. Bull."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/j.jtice.2017.12.021","article-title":"Enhancement mechanism of hydroxyapatite for photocatalytic degradation of gaseous formaldehyde over TiO2\/hydroxyapatite","volume":"85","author":"Hu","year":"2018","journal-title":"J. Taiwan Inst. Chem. Eng."},{"key":"ref_19","unstructured":"McMurry, J. (2005). Fundamentals of Organic Chemistry, Mechanical Industry Press."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1021\/ed060pA283.1","article-title":"Introduction to Chemical Analysis","volume":"60","author":"Robert","year":"1983","journal-title":"J. Chem. Educ."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"2078","DOI":"10.1007\/BF02494259","article-title":"Pathways of Reactions of Nucleophilic Addition of H2O and HF Molecules to Formaldehyde in Gas Phase and in Complex with Formic Acid: Ab initio, Calculations","volume":"47","author":"Minyaev","year":"1998","journal-title":"Russ. Chem. Bull."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"775","DOI":"10.1021\/jacs.7b11749","article-title":"Entropy-Driven High Reactivity of Formaldehyde in Nucleophilic Attacked by Enolates on Oxide Surfaces","volume":"140","author":"Wang","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"14086","DOI":"10.1021\/ja304661g","article-title":"Radical Versus Nucleophilic Mechanism of Formaldehyde Polymerization Catalyzed by (WO3)3 Clusters on Reduced or Stoichiometric TiO2(110)","volume":"134","author":"Valentin","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"1741","DOI":"10.1016\/S1001-0742(08)62482-1","article-title":"Enhancement of Formaldehyde Degradation by Amine Functionalized Silica\/Titania films","volume":"21","author":"Photong","year":"2009","journal-title":"J. Environ. Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"9311","DOI":"10.1016\/j.apsusc.2009.07.021","article-title":"Preparation and Characterization of Amine-functionalized SiO2\/TiO2 Films for Formaldehyde Degradation","volume":"255","author":"Photong","year":"2009","journal-title":"Appl. Surf. Sci."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"379","DOI":"10.1016\/S1001-0742(08)60059-5","article-title":"Absorption of Formaldehyde Vapor by Amine-functionalized Mesoporous Silica Materials","volume":"20","author":"Saeung","year":"2008","journal-title":"J. Environ. Sci."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"297","DOI":"10.1021\/cr60085a001","article-title":"A Summary of the Reactions of Aldehydes with Amines","volume":"26","author":"Sprung","year":"1940","journal-title":"Chem. Rev."},{"key":"ref_28","first-page":"314","article-title":"Formaldehyde Removal by Potted Plant-soil Systems","volume":"192","author":"Xu","year":"2011","journal-title":"J. Hazard. Mater."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1146\/annurev.arplant.52.1.119","article-title":"One-carbon metabolism in higher plants","volume":"52","author":"Hanson","year":"2001","journal-title":"Annu. Rev. Plant Biol."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"281","DOI":"10.1016\/S0981-9428(02)01378-5","article-title":"Cloning and Characterisation of S-formylglutathione Hydrolase from Arabidopsisthaliana: A Pathway for Formaldehyde Detoxification","volume":"40","author":"Haslam","year":"2002","journal-title":"Plant Physiol. Biochem."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1501","DOI":"10.1007\/s10870-011-0130-7","article-title":"Synthesis and Crystal Structure Analysis of 3,5,5,7-Tetraacetylnonane-2,8-Dione","volume":"41","author":"Guo","year":"2011","journal-title":"J. Chem. Crystallogr."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"453","DOI":"10.1007\/s11270-009-0268-5","article-title":"Synthesis of APTMS-Functionalized SiO2\/TiO2, Transparent Film Using Peroxo Titanic Acid Refluxed Solution for Formaldehyde Removal","volume":"210","author":"Photong","year":"2010","journal-title":"Water Air Soil Pollut."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"2873","DOI":"10.1016\/j.carbon.2011.02.058","article-title":"Removal of Low-concentration Formaldehyde in Air by Absorption on Activated Carbon Modified by Hexamethylenediamine","volume":"49","author":"Ma","year":"2011","journal-title":"Carbon"},{"key":"ref_34","first-page":"52","article-title":"Study on the Reaction Characteristics of Tea Polyphenols and Formaldehyde","volume":"8","author":"Li","year":"2008","journal-title":"J. Chin. Inst. Food Sci. Technol."},{"key":"ref_35","first-page":"455","article-title":"Effects of Anti oxidation on Thermal-oxidation stability of Fuel NNJ-150","volume":"20","author":"Sun","year":"2006","journal-title":"J. Chem. Eng. Chin.Univ."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"170","DOI":"10.1016\/j.ejps.2005.05.008","article-title":"An Experimental Investigation of Stability of Ethylcellulose Latex Correlation between Zeta Potential and Sedimentation","volume":"26","author":"Gallardo","year":"2005","journal-title":"Eur. J. Pharm. Sci."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"13720","DOI":"10.1002\/chem.201101871","article-title":"Aldehyde cruciforms: Dosimeters for Primary and Secondary Amines","volume":"17","author":"Patze","year":"2011","journal-title":"Chemistry"},{"key":"ref_38","first-page":"1","article-title":"FeCl2-Catalyzed Oxidative Amidation of Aldehydes with Primary and Secondary Amines","volume":"73","author":"Li","year":"2015","journal-title":"Acta Chim. Sin."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1016\/j.snb.2004.07.010","article-title":"Development of a novel hand-held formaldehyde gas sensor for the rapid detection of sick building syndrome","volume":"105","author":"Kawamura","year":"2005","journal-title":"Sens. Actuators B Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1080\/00387019708002586","article-title":"Infrared Quantitative Study of Acetylation of Microspheres of Polystyrene","volume":"30","author":"Liu","year":"1997","journal-title":"Spectrosc. Lett."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.aca.2009.02.042","article-title":"Quantitative flash pyrolysis Fourier transform infrared spectroscopy of organic materials","volume":"639","author":"Court","year":"2009","journal-title":"Anal. Chim. Acta"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"269","DOI":"10.1023\/A:1011383408381","article-title":"Quantitative determination of apoptosis on leukemia cells by infrared spectroscopy","volume":"6","author":"Liu","year":"2001","journal-title":"Apoptosis"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/0146-6380(89)90021-1","article-title":"Quantitative determination of thermal maturity in sedimentary organic matter by diffuse reflectance infrared spectroscopy of asphaltenes","volume":"14","author":"Christy","year":"1989","journal-title":"Org. Geochem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1865","DOI":"10.1021\/ma980791d","article-title":"Study of Self-Diffusion of Molecules in a Polymer Gel by Pulsed-Gradient Spin-Echo 1H NMR. 2. Intermolecular Hydrogen-Bond Interaction between the Probe Polymer and Network Polymer in N,N-Dimethylacrylamide\u2212Acrylic Acid Copolymer Gel Systems","volume":"30","author":"Matsukawa","year":"1999","journal-title":"Macromolecules"}],"container-title":["Polymers"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4360\/11\/1\/86\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T12:24:10Z","timestamp":1760185450000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4360\/11\/1\/86"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,1,8]]},"references-count":44,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2019,1]]}},"alternative-id":["polym11010086"],"URL":"https:\/\/doi.org\/10.3390\/polym11010086","relation":{},"ISSN":["2073-4360"],"issn-type":[{"type":"electronic","value":"2073-4360"}],"subject":[],"published":{"date-parts":[[2019,1,8]]}}}