{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T05:02:08Z","timestamp":1787029328558,"version":"build-2736575974"},"reference-count":43,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2019,12,6]],"date-time":"2019-12-06T00:00:00Z","timestamp":1575590400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"undefined  &lt;span style=&quot;color:gray;font-size:10px;&quot;&gt;undefined&lt;\/span&gt;","award":["201504603"],"award-info":[{"award-number":["201504603"]}]},{"name":"North Jiangsu Science and Technology Project","award":["SZ-SQ2018018"],"award-info":[{"award-number":["SZ-SQ2018018"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>As one of the main consumables of interior decoration and furniture, decorative paper can be seen everywhere in the indoor space. However, because of its high content of formaldehyde, it has a certain threat to people\u2019s health. Therefore, it is necessary to develop and study new formaldehyde-free decorative paper to meet the market demand. In this work, we have obtained formaldehyde-free decorative paper with high CO2 adsorption capacity. Here, cellulose nanocrystals (CNC) were prepared by hydrolyzing microcrystalline cellulose with sulfuric acid. The N-(2-aminoethyl) (3-amino-propyl) methyldimethoxysilane (AEAPMDS) was grafted onto the CNCs by liquid phase hydrothermal treatment, and the aqueous solution was substituted by tert-butanol to obtain aminated CNCs (AEAPMDS-CNCs). The as-prepared AEAPMDS-CNCs were applied to formaldehyde-free decorative paper by the spin-coating method. The effects of various parameters on the properties of synthetic materials were systematically studied, and the optimum reaction conditions were revealed. Moreover, the surface bond strength and abrasion resistance of modified formaldehyde-free decorative paper were investigated. The experimental results showed that AEAPMDS grafted successfully without destroying the basic morphology of the CNCs. The formaldehyde-free decorative paper coated with AEAPMDS-CNCs had high CO2 adsorption capacity and exhibited excellent performance of veneer to plywood. Therefore, laminating the prepared formaldehyde-free decorative paper onto indoor furniture can achieve the purpose of capturing indoor CO2 and have a highly potential use for the indoor decoration.<\/jats:p>","DOI":"10.3390\/polym11122021","type":"journal-article","created":{"date-parts":[[2019,12,6]],"date-time":"2019-12-06T10:41:44Z","timestamp":1575628904000},"page":"2021","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Synthesis and Characterization of Aminosilane Grafted Cellulose Nanocrystal Modified Formaldehyde-Free Decorative Paper and its CO2 Adsorption Capacity"],"prefix":"10.3390","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6897-677X","authenticated-orcid":false,"given":"Wenkai","family":"Zhu","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meixiu","family":"Ji","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhe","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanyuan","family":"Xue","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2019,12,6]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1016\/j.cej.2019.04.206","article-title":"5 ultramicropore-rich renewable porous carbon from biomass tar with excellent adsorption capacity and selectivity for CO2 capture","volume":"373","author":"Yuan","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"6291","DOI":"10.1166\/jnn.2019.17043","article-title":"Characteristics of CO2 capture by tetraethylenepentamine modified mesoporous silica morphology","volume":"19","author":"Bae","year":"2019","journal-title":"J. Nanosci. Nanotechnol."},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Liu, B., Lian, Y., Li, S., Deng, S., Zhao, L., Chen, B., and Wang, D. (2019). Experimental investigation on separation and energy-efficiency performance of temperature swing adsorption system for CO2 capture. Sep. Purif. Technol., 227.","DOI":"10.1016\/j.seppur.2019.06.008"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"811","DOI":"10.1016\/j.jngse.2016.07.042","article-title":"Influence of high-pressure CO2 exposure on adsorption kinetics of methane and CO2 on coals","volume":"34","author":"Wang","year":"2016","journal-title":"J. Nat. Gas. Sci. Eng."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.energy.2018.04.183","article-title":"Melamine-nitrogenated mesoporous activated carbon derived from rice husk for carbon dioxide adsorption in fixed-bed","volume":"155","author":"Yaumi","year":"2018","journal-title":"Energy"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"478","DOI":"10.1177\/0263617417704527","article-title":"Surface characteristics of koh-treated commercial carbons applied for CO2 adsorption","volume":"36","author":"Czekajlo","year":"2018","journal-title":"Adsorpt. Sci. Technol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"605","DOI":"10.1007\/s10311-017-0701-8","article-title":"High CO2 adsorption by amino-modified bio-spherical cellulose nanofibres aerogels","volume":"16","author":"Liu","year":"2018","journal-title":"Environ. Chem. Lett."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1016\/j.jcou.2017.12.016","article-title":"The effect of pore size dimensions in isoreticular zeolites on carbon dioxide adsorption heats","volume":"24","author":"Zukal","year":"2018","journal-title":"J. CO2 Util."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"1818","DOI":"10.1002\/ceat.201700402","article-title":"Separation of methane and carbon dioxide gas mixtures using activated carbon modified with 2-methylimidazole","volume":"41","author":"Zhang","year":"2018","journal-title":"Chem. Eng. Technol."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1441","DOI":"10.1177\/0263617418779459","article-title":"Comparative assessment between different sample preparation methodologies for ptga CO2 adsorption assays-pellet, powder, and fragment samples","volume":"36","author":"Ramos","year":"2018","journal-title":"Adsorpt. Sci. Technol."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1158","DOI":"10.1016\/j.energy.2018.08.090","article-title":"Adsorption artificial tree for atmospheric carbon dioxide capture, purification and compression","volume":"162","author":"Santori","year":"2018","journal-title":"Energy"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1120","DOI":"10.1134\/S1990793118070047","article-title":"Adsorption properties of aerosilicagels prepared by drying in a supercritical carbon dioxide medium","volume":"12","author":"Gordienko","year":"2018","journal-title":"Russ. J. Phys. Chem. B"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"225","DOI":"10.1016\/j.ijggc.2018.07.001","article-title":"Optimization of carbon dioxide capture using sorbent-loaded hollow-fiber modules","volume":"76","author":"Hoysall","year":"2018","journal-title":"Int. J. Greenh. Gas. Control."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"29003","DOI":"10.1021\/acsami.8b08636","article-title":"Polyethylenimine-modified membranes for CO2 capture and in situ hydrogenation","volume":"10","author":"Wang","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1949","DOI":"10.1039\/c0ee00136h","article-title":"Nanostructured silica as a support for regenerable high-capacity organoamine-based CO2 sorbents","volume":"3","author":"Goeppert","year":"2010","journal-title":"Energy Environ. Sci."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"16","DOI":"10.2174\/187221012798109255","article-title":"Review of cellulose nanocrystals patents: Preparation, composites and general applications","volume":"6","author":"Duran","year":"2012","journal-title":"Recent Pat. Nanotechnol."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"2807","DOI":"10.1021\/acssuschemeng.7b03437","article-title":"Importance of agricultural and industrial waste in the field of nanocellulose and recent industrial developments of wood based nanocellulose: A review","volume":"6","author":"Rajinipriya","year":"2018","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2479","DOI":"10.3762\/bjnano.9.232","article-title":"Nanocellulose: Recent advances and its prospects in environmental remediation","volume":"9","author":"Shak","year":"2018","journal-title":"Beilstein J. Nanotechnol."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"813","DOI":"10.1016\/j.porgcoat.2014.01.009","article-title":"Modification of cellulose nanocrystals as reinforcement derivatives for wood coatings","volume":"77","author":"Poaty","year":"2014","journal-title":"Prog. Org. Coat."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/j.indcrop.2013.04.022","article-title":"Cellulose based organogel as an adsorbent for dissolved organic compounds","volume":"49","author":"Maatar","year":"2013","journal-title":"Ind. Crop. Prod."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1016\/j.carbpol.2015.03.015","article-title":"Poly (methacylic acid-co-maleic acid) grafted nanofibrillated cellulose as a reusable novel heavy metal ions adsorbent","volume":"126","author":"Maatar","year":"2015","journal-title":"Carbohydr. Polym."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"16716","DOI":"10.1007\/s11356-019-05068-3","article-title":"Aminosilane-grafted spherical cellulose nanocrystal aerogel with high CO2 adsorption capacity","volume":"26","author":"Zhang","year":"2019","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"13304","DOI":"10.1007\/s10853-018-2595-7","article-title":"Synthesis and characterization of amine-modified spherical nanocellulose aerogels","volume":"53","author":"Wang","year":"2018","journal-title":"J. Mater. Sci."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"403","DOI":"10.32604\/jrm.2019.01846","article-title":"Water-based processing of fiberboard of acrylic resin composites reinforced with cellulose wood pulp and cellulose nanofibrils","volume":"7","author":"Trovatti","year":"2019","journal-title":"J. Renew. Mater."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"2435","DOI":"10.1007\/s10570-018-1739-x","article-title":"Dispersing and stabilizing cellulose nanoparticles in acrylic resin dispersions with unreduced transparency and changed rheological property","volume":"25","author":"Du","year":"2018","journal-title":"Cellulose"},{"key":"ref_26","first-page":"147","article-title":"Preparation and properties of impregnated paper with waterborne acrylic modified by nano Al(OH)3 and cellulose nanocrystalline","volume":"3","author":"Chen","year":"2018","journal-title":"J. For. Eng."},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Jia, C., Zhang, Y., and Cui, J. (2019). Gan, L. The Antibacterial Properties and Safety of a Nanoparticle-Coated Parquet Floor. Coatings, 9.","DOI":"10.3390\/coatings9060403"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1016\/j.polymer.2018.04.020","article-title":"Waterborne acrylic resin modified with glycidyl methacrylate (gma): Formula optimization and property analysis","volume":"143","author":"Guo","year":"2018","journal-title":"Polymer"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"252","DOI":"10.1016\/j.carbpol.2018.04.017","article-title":"Effects of amine loading on the properties of cellulose nanofibrils aerogel and its CO2 capturing performance","volume":"194","author":"Wu","year":"2018","journal-title":"Carbohydr. Polym."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"267","DOI":"10.1016\/j.clay.2017.11.023","article-title":"Polyethyleneimine (PEI) loaded MgO-SiO2 nanofibers from sepiolite minerals for reusable CO2 capture\/release applications","volume":"152","author":"Ouyang","year":"2018","journal-title":"Appl. Clay Sci."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"15163","DOI":"10.1021\/ie300180u","article-title":"Am-tepa impregnated disordered mesoporous silica as CO2 capture adsorbent for balanced adsorption-desorption properties","volume":"51","author":"Zhang","year":"2012","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_32","first-page":"207","article-title":"Preparation and characterization of 3-(2-aminoethylamino) propylmethyldimethoxysilane-nano cellulose aerogels","volume":"35","author":"Liu","year":"2018","journal-title":"Acta Mater. Compos. Sin."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"806","DOI":"10.1016\/j.compositesa.2010.03.005","article-title":"Silane coupling agents used for natural fiber\/polymer composites: A review","volume":"41","author":"Xie","year":"2010","journal-title":"Compos. Part. A Appl. Sci. Manuf."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1016\/j.watres.2016.01.008","article-title":"A review on modification methods to cellulose-based adsorbents to improve adsorption capacity","volume":"91","author":"Hokkanen","year":"2016","journal-title":"Water Res."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"9101","DOI":"10.1021\/es202223p","article-title":"Amine-based nanofibrillated cellulose as adsorbent for CO2 capture from air","volume":"45","author":"Gebald","year":"2011","journal-title":"Environ. Sci. Technol."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"63978","DOI":"10.1039\/C5RA04000K","article-title":"Improvement of chemical stability and durability of superhydrophobic wood surface via a film of TiO2 coated CaCO3 micro-\/nano-composite particles","volume":"5","author":"Gao","year":"2015","journal-title":"RSC Adv."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"621","DOI":"10.1515\/pac-2016-0503","article-title":"Dissolution, gelation, functionalization, and material preparation of chitin using ionic liquids","volume":"88","author":"Kadokawa","year":"2016","journal-title":"Pure Appl. Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"17312","DOI":"10.1021\/acsami.6b05044","article-title":"Amine-impregnated mesoporous silica nanotube as an emerging nanocomposite for CO2 capture","volume":"8","author":"Niu","year":"2016","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/j.carbpol.2016.03.048","article-title":"Facilitated fabrication of high strength silica aerogels using cellulose nanofibrils as scaffold","volume":"147","author":"Fu","year":"2016","journal-title":"Carbohydr. Polym."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"085303","DOI":"10.1088\/2053-1591\/aa8067","article-title":"Preparation and characterization of aminosilane-functionalized cellulose nanocrystal aerogel","volume":"4","author":"Wu","year":"2017","journal-title":"Mater. Res. Express"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"4371","DOI":"10.1021\/am500089g","article-title":"Amine-tethered adsorbents based on three-dimensional macroporous silica for CO2 capture from simulated flue gas and air","volume":"6","author":"Liu","year":"2014","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"865","DOI":"10.1111\/j.2042-7158.1951.tb13130.x","article-title":"Surface and colloid chemistry","volume":"3","author":"Saunders","year":"1951","journal-title":"J. Pharm. Pharmacol."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"342","DOI":"10.1016\/j.cej.2017.12.109","article-title":"Textural properties determined CO2 capture of tetraethylenepentamine loaded SiO2 nanowires from alpha-sepiolite","volume":"337","author":"Ouyang","year":"2018","journal-title":"Chem. Eng. J."}],"container-title":["Polymers"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4360\/11\/12\/2021\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T13:40:54Z","timestamp":1760190054000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4360\/11\/12\/2021"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,12,6]]},"references-count":43,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2019,12]]}},"alternative-id":["polym11122021"],"URL":"https:\/\/doi.org\/10.3390\/polym11122021","relation":{},"ISSN":["2073-4360"],"issn-type":[{"value":"2073-4360","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,12,6]]}}}