{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T12:37:58Z","timestamp":1785674278962,"version":"3.56.0"},"reference-count":55,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2020,12,10]],"date-time":"2020-12-10T00:00:00Z","timestamp":1607558400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"The work was completed as a part of the state assignment","award":["AAAA-A20-120013190076-0"],"award-info":[{"award-number":["AAAA-A20-120013190076-0"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>Microcrystalline cellulose (MCC) is a chemically pure product of cellulose mechano-chemical conversion. It is a white powder composed of the short fragments of the plant cells widely used in the modern food industry and pharmaceutics. The acid hydrolysis of the bleached lignin-free cellulose raw is the main and necessary stage of MCC production. For this reason, the acid hydrolysis is generally accepted to be the driving force of the fragmentation of the initial cellulose fibers into MCC particles. However, the low sensibility of the MCC properties to repeating the hydrolysis forces doubting this point of view. The sharp, cleave-looking edges of the MCC particles suggesting the initial cellulose fibers were fractured; hence the hydrolysis made them brittle. Zhurkov showed that mechanical stress decreases the activation energy of the polymer fracture, which correlates with the elevated enthalpy of the MCC thermal destruction compared to the initial cellulose.<\/jats:p>","DOI":"10.3390\/polym12122952","type":"journal-article","created":{"date-parts":[[2020,12,10]],"date-time":"2020-12-10T20:18:22Z","timestamp":1607631502000},"page":"2952","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Zhurkov\u2019s Stress-Driven Fracture as a Driving Force of the Microcrystalline Cellulose Formation"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8820-9615","authenticated-orcid":false,"given":"Sergey V.","family":"Stovbun","sequence":"first","affiliation":[{"name":"N.N. 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Semenov Institute of Chemical Physics, RAS, Kosygina 4, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vasily A.","family":"Kharitonov","sequence":"additional","affiliation":[{"name":"N.N. Semenov Institute of Chemical Physics, RAS, Kosygina 4, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kseniya I.","family":"Kovaleva","sequence":"additional","affiliation":[{"name":"N.N. Semenov Institute of Chemical Physics, RAS, Kosygina 4, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Galina G.","family":"Politenkova","sequence":"additional","affiliation":[{"name":"N.N. Semenov Institute of Chemical Physics, RAS, Kosygina 4, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9295-583X","authenticated-orcid":false,"given":"Alexander S.","family":"Vedenkin","sequence":"additional","affiliation":[{"name":"N.N. 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