{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,4]],"date-time":"2026-07-04T11:27:13Z","timestamp":1783164433337,"version":"3.54.6"},"reference-count":63,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2021,7,6]],"date-time":"2021-07-06T00:00:00Z","timestamp":1625529600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100017445","name":"Natural Science Fund for Distinguished Young Scholars of Shandong Province","doi-asserted-by":"publisher","award":["ZR2019BEM025"],"award-info":[{"award-number":["ZR2019BEM025"]}],"id":[{"id":"10.13039\/100017445","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Young Doctor Cooperation Foundation of Qilu University of Technology","award":["2019BSHZ0016"],"award-info":[{"award-number":["2019BSHZ0016"]}]},{"name":"College Students Innovation and Entrepreneurship Training Program","award":["S20191043107"],"award-info":[{"award-number":["S20191043107"]}]},{"name":"Science-Education-Industry Integration Innovation Pilot Project of Qilu University of Technology","award":["2020KJC-GH13"],"award-info":[{"award-number":["2020KJC-GH13"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>Low-cost urea formaldehyde resin (UF)\/reactive halloysite nanotubes (HNTs) nanocomposite adhesive was prepared successfully via in situ polymerization. The HNTs were modified to improve its compatibility with polymer. The XRD and FTIR results showed that physical and chemical interaction between the HNTs and polymer resin influenced the structure of UF owing to the functional groups on the HNTs. It is found from SEM images that the modified HNTs could be dispersed uniformly in the resin and the nanocomposite particles were spherical. The performance experiment confirmed that thermal stability of nanocomposite increased largely, formaldehyde emission of UF wood adhesive reduced 62%, and water resistance of UF wood adhesive improved by 84%. Meanwhile, the content of HNTs on the nanocomposites could be up to 60 wt %. The mechanism of the nanocomposites based on the reactive HNTs was proposed. The approach of the preparation could supply an idea to prepare other polymer\/clay nanocomposites.<\/jats:p>","DOI":"10.3390\/polym13142224","type":"journal-article","created":{"date-parts":[[2021,7,6]],"date-time":"2021-07-06T11:36:44Z","timestamp":1625571404000},"page":"2224","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Preparation and Properties of the Urea-Formaldehyde Res-In\/Reactive Halloysite Nanocomposites Adhesive with Low-Formaldehyde Emission and Good Water Resistance"],"prefix":"10.3390","volume":"13","author":[{"given":"Jingbiao","family":"Song","sequence":"first","affiliation":[{"name":"Shandong Provincial Key Laboratory of Processing and Testing Technology of Glass and Functional Ceramics, School of Material Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9018-1981","authenticated-orcid":false,"given":"Shiwei","family":"Chen","sequence":"additional","affiliation":[{"name":"Shandong Provincial Key Laboratory of Processing and Testing Technology of Glass and Functional Ceramics, School of Material Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China"},{"name":"Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xibin","family":"Yi","sequence":"additional","affiliation":[{"name":"Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinfu","family":"Zhao","sequence":"additional","affiliation":[{"name":"Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaochan","family":"Liu","sequence":"additional","affiliation":[{"name":"Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Benxue","family":"Liu","sequence":"additional","affiliation":[{"name":"Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2021,7,6]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"110","DOI":"10.1016\/j.porgcoat.2018.08.015","article-title":"Self-healing and corrosion protection performance of organic polysulfide@urea-formaldehyde resin core-shell nanoparticles in epoxy\/PANI\/ZnO nanocomposite coatings on anodized aluminum alloy","volume":"124","author":"Najjar","year":"2018","journal-title":"Prog. 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