{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,1]],"date-time":"2026-04-01T14:10:45Z","timestamp":1775052645415,"version":"3.50.1"},"reference-count":50,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2021,8,13]],"date-time":"2021-08-13T00:00:00Z","timestamp":1628812800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["project \u2116 20-13-00161"],"award-info":[{"award-number":["project \u2116 20-13-00161"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>Polymethacrylic molecular brushes with oligo(ethylene glycol)-block-oligo(propylene glycol) side chains were investigated by static and dynamic light scattering and viscometry. The solvents used were acetonitrile, tetrahydrofuran, chloroform, and water. The grafted copolymers were molecularly dispersed and dissolved in tetrahydrofuran and acetonitrile. In these solvents, the molar masses of copolymers were determined. In thermodynamically good solvents, namely tetrahydrofuran and acetonitrile, investigated copolymers have a high intramolecular density and the shape of their molecules resembles a star-shaped macromolecule. In chloroform and water, the micelle-like aggregates were formed. Critical micelle concentrations decreased with the lengthening of the hydrophobic block. Molecular brushes demonstrated thermosensitive behavior in aqueous solutions. The phase separation temperatures reduced with an increase in the content of the oligo(propylene glycol) block.<\/jats:p>","DOI":"10.3390\/polym13162715","type":"journal-article","created":{"date-parts":[[2021,8,15]],"date-time":"2021-08-15T22:51:27Z","timestamp":1629067887000},"page":"2715","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Conformation, Self-Organization and Thermoresponsibility of Polymethacrylate Molecular Brushes with Oligo(ethylene glycol)-block-oligo(propylene glycol) Side Chains"],"prefix":"10.3390","volume":"13","author":[{"given":"Maria","family":"Simonova","sequence":"first","affiliation":[{"name":"Institute of Macromolecular Compounds of the Russian Academy of Sciences, Bolshoy Prospekt 31, 199004 Saint Petersburg, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Denis","family":"Kamorin","sequence":"additional","affiliation":[{"name":"Laboratory of Acrylic Monomers and Polymers, Department of Chemical Technology, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia"},{"name":"Chromatography Laboratory, Department of Production Control and Chromatography Methods, Lobachevsky State University of Nizhni Novgorod, Dzerzhinsk Branch, 23 Prospekt Gagarina, 603950 Nizhny Novgorod, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oleg","family":"Kazantsev","sequence":"additional","affiliation":[{"name":"Laboratory of Acrylic Monomers and Polymers, Department of Chemical Technology, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maria","family":"Nepomnyashaya","sequence":"additional","affiliation":[{"name":"Higher School of Technology and Energy, Ivana Chernykh 4, 198095 Saint Petersburg, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Filippov","sequence":"additional","affiliation":[{"name":"Institute of Macromolecular Compounds of the Russian Academy of Sciences, Bolshoy Prospekt 31, 199004 Saint Petersburg, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,8,13]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3461","DOI":"10.1002\/pola.20900","article-title":"Cylindrical Polymer Brushes","volume":"43","author":"Zhang","year":"2005","journal-title":"J. Polym. Sci. Part A Polym. 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