{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T02:52:07Z","timestamp":1760151127098,"version":"build-2065373602"},"reference-count":86,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2022,2,24]],"date-time":"2022-02-24T00:00:00Z","timestamp":1645660800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>Anionic homo- and copolymerization of p-diethynylbenzene in the presence of n-BuLi in polar solvents was carried out. The use of hexamethylphosphortriamide (HMPA) makes it possible to synthesize a completely linear soluble polymer that does not have branching and phenylene fragments. A copolymer of p-diethynylbenzene with diphenyldiacetylene was synthesized. Homo- and copolymers of p-diethynylbenzene have high thermo- and thermo-oxidative stability. By the interaction of side reactive ethynylphenylene groups with various reagents, it is proposed to synthesize clusters along the conducting chain of poly-p-diethynylbenzene. Due to presenting C\u2261CH side groups, boron, copper, and cobalt derivatives were synthesized. It is shown that not all theoretically possible stereoisomers can be formed as a result of the polymerization. The application of p-diethynylbenzene polymers for the modification of industrial samples of epoxy novolac resin, oligoester acrylates, and carbon fibers has been demonstrated.<\/jats:p>","DOI":"10.3390\/polym14050900","type":"journal-article","created":{"date-parts":[[2022,2,24]],"date-time":"2022-02-24T21:11:07Z","timestamp":1645737067000},"page":"900","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer"],"prefix":"10.3390","volume":"14","author":[{"given":"Vyacheslav M.","family":"Misin","sequence":"first","affiliation":[{"name":"N.M. Emanuel Institute of Biochemical Physics RAS, 4 Kosygina Street, 119334 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2905-3873","authenticated-orcid":false,"given":"Irina E.","family":"Maltseva","sequence":"additional","affiliation":[{"name":"N.M. Emanuel Institute of Biochemical Physics RAS, 4 Kosygina Street, 119334 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander A.","family":"Maltsev","sequence":"additional","affiliation":[{"name":"N.M. Emanuel Institute of Biochemical Physics RAS, 4 Kosygina Street, 119334 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5696-5723","authenticated-orcid":false,"given":"Alexander V.","family":"Naumkin","sequence":"additional","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds RAS, 28 Vavilova Street, 119991 Moscow, Russia"},{"name":"A.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 31 bld.4 Leninsky Prospect, 119071 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mark E.","family":"Kazakov","sequence":"additional","affiliation":[{"name":"SPC UVICOM Ltd., 5 Kolontsova St., 141009 Mytischi, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,2,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"348","DOI":"10.1070\/RC1976v045n04ABEH002642","article-title":"Polymerisation of Acetylenes. The Structure and Electrophysical Properties of Polyvinylenes","volume":"45","author":"Chauser","year":"1976","journal-title":"Russ. Chem. 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