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Although the flame retardants such as halogen- and phosphorus-containing compounds can inhibit combustion, they cannot effectively reduce the release of toxic fumes. Zinc hydroxystannate (ZHS, ZnSn(OH)6) is an environmentally friendly flame retardant that has attracted extensive interest because of its high efficiency, safety, and smoke suppression properties. However, using ZHS itself may not contribute to the optimal flame retardant effect, which is commonly combined with other flame retardants to achieve more significant efficiency. Few articles systematically review the recent development of ZHS in the fire safety field. This review aims to deliver an insight towards further direction and advancement of ZHS in flame retardant and smoke suppression for multiple polymer blends. In addition, the fire retarded and smoke suppression mechanism of ZHS will be demonstrated and discussed in depth.<\/jats:p>","DOI":"10.3390\/polym14112175","type":"journal-article","created":{"date-parts":[[2022,5,31]],"date-time":"2022-05-31T00:25:12Z","timestamp":1653956712000},"page":"2175","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Recent Advances in Zinc Hydroxystannate-Based Flame Retardant Polymer Blends"],"prefix":"10.3390","volume":"14","author":[{"given":"Wei-Hao","family":"Pan","sequence":"first","affiliation":[{"name":"School of Energy, Materials and Chemical Engineering, Hefei University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen-Jie","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Architecture and Civil Engineering, City University of Hong Kong, 88 Tat Chee Avenue, Kowloon, Hong Kong, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3051-8877","authenticated-orcid":false,"given":"Chun-Xiang","family":"Wei","sequence":"additional","affiliation":[{"name":"School of Energy, Materials and Chemical Engineering, Hefei University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling-Yun","family":"Hao","sequence":"additional","affiliation":[{"name":"School of Materials Engineering, Jinling Institute of Technology, Nanjing 211169, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong-Dian","family":"Lu","sequence":"additional","affiliation":[{"name":"School of Energy, Materials and Chemical Engineering, Hefei University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4759-4996","authenticated-orcid":false,"given":"Wei","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Energy, Materials and Chemical Engineering, Hefei University, Hefei 230601, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,5,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1119","DOI":"10.1016\/j.chemosphere.2012.03.067","article-title":"Phosphorus flame retardants: Properties, production, environmental occurrence, toxicity and analysis","volume":"88","year":"2012","journal-title":"Chemosphere"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"132031","DOI":"10.1016\/j.cej.2021.132031","article-title":"Flame-Retardant multifunctional epoxy resin with high performances","volume":"427","author":"Liu","year":"2022","journal-title":"Chem. 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