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With this aim, three lignins, derived from the kraft pulping and bioethanol industries, were chemically modified via the Mannich reaction to be used as cationic emulsifiers. A comprehensive chemical characterization was conducted on raw lignin-rich products, showing that the kraft sample presents a higher lignin concentration and lower molecular weight. Instead, bioethanol-derived samples, with characteristics of non-woody lignins, present a high concentration of carbohydrate residues and ashes. Lignin amination was performed at pH = 10 and 13, using tetraethylene pentamine and formaldehyde as reagents at three different stoichiometric molar ratios. The emulsification ability of such cationic surfactants was firstly studied on prototype silicone oil-in-water emulsions, attending to their droplet size distribution and viscous behavior. Among the synthetized surfactants, cationic kraft lignin has shown the best emulsification performance, being used for the development of bitumen emulsions. In this regard, cationic kraft lignin has successfully stabilized oil-in-water emulsions containing 60% bitumen using small surfactant concentrations, between 0.25 and 0.75%, which was obtained at pH = 13 and reagent molar ratios between 1\/7\/7 and 1\/28\/28 (lignin\/tetraethylene pentamine\/formaldehyde).<\/jats:p>","DOI":"10.3390\/polym14142879","type":"journal-article","created":{"date-parts":[[2022,7,18]],"date-time":"2022-07-18T01:53:22Z","timestamp":1658109202000},"page":"2879","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes"],"prefix":"10.3390","volume":"14","author":[{"given":"Avido","family":"Yuliestyan","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering, Faculty of Industrial Technology, UPN Veteran Yogyakarta, Jalan SWK 104, Yogyakarta 55283, Indonesia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0141-0733","authenticated-orcid":false,"given":"Pedro","family":"Partal","sequence":"additional","affiliation":[{"name":"Pro2TecS-Chemical Process and Product Technology Research Centre, Department of Chemical Engineeing, ETSI, Campus de \u201cEl Carmen\u201d, University of Huelva, 21071 Huelva, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8277-1073","authenticated-orcid":false,"given":"Francisco J.","family":"Navarro","sequence":"additional","affiliation":[{"name":"Pro2TecS-Chemical Process and Product Technology Research Centre, Department of Chemical Engineeing, ETSI, Campus de \u201cEl Carmen\u201d, University of Huelva, 21071 Huelva, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2083-3723","authenticated-orcid":false,"given":"Raquel","family":"Mart\u00edn-Sampedro","sequence":"additional","affiliation":[{"name":"Forest Research Center (INIA, CSIC), Ctra. de la Coru\u00f1a km 7.5, 28040 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3001-7308","authenticated-orcid":false,"given":"David","family":"Ibarra","sequence":"additional","affiliation":[{"name":"Forest Research Center (INIA, CSIC), Ctra. de la Coru\u00f1a km 7.5, 28040 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mar\u00eda E.","family":"Eugenio","sequence":"additional","affiliation":[{"name":"Forest Research Center (INIA, CSIC), Ctra. de la Coru\u00f1a km 7.5, 28040 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,7,15]]},"reference":[{"key":"ref_1","unstructured":"Bolker, I.H. 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