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However, commercial liquid rechargeable lithium batteries have safety hazards such as leakage or explosion, all-solid-state lithium rechargeable lithium batteries will become the best alternatives. But the biggest challenge we face at present is the large solid-solid interface contact resistance between the solid electrolyte and the electrode as well as the low ionic conductivity of the solid electrolyte. Due to the large relative molecular mass, polymers usually exhibit solid or gel state with good mechanical strength. The intermolecules are connected by covalent bonds, so that the chemical and physical stability, corrosion resistance, high temperature resistance and fire resistance are good. Many researchers have found that polymers play an important role in improving the performance of all-solid-state lithium rechargeable batteries. This review mainly describes the application of polymers in the fields of electrodes, electrolytes, electrolyte-electrode contact interfaces, and electrode binders in all-solid-state lithium rechargeable batteries, and how to improve battery performance. This review mainly introduces the recent applications of polymers in solid-state lithium battery electrodes, electrolytes, electrode binders, etc., and describes the performance of emerging porous polymer materials and materials based on traditional polymers in solid-state lithium batteries. The comparative analysis shows the application advantages and disadvantages of the emerging porous polymer materials in this field which provides valuable reference information for further development.<\/jats:p>","DOI":"10.3390\/polym14224804","type":"journal-article","created":{"date-parts":[[2022,11,9]],"date-time":"2022-11-09T02:44:32Z","timestamp":1667961872000},"page":"4804","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Recent Advances in Porous Polymers for Solid-State Rechargeable Lithium Batteries"],"prefix":"10.3390","volume":"14","author":[{"given":"Junyan","family":"Zou","sequence":"first","affiliation":[{"name":"Zhejiang Engineering Laboratory for Green Syntheses and Applications of Fluorine-Containing Specialty Chemicals, Institute of Advanced Fluorine-Containing Materials, Zhejiang Normal University, Jinhua 321004, China"},{"name":"Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China"},{"name":"Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy Materials, Department of Physics, Jinan University, Guangzhou 510632, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Teng","family":"Ben","sequence":"additional","affiliation":[{"name":"Zhejiang Engineering Laboratory for Green Syntheses and Applications of Fluorine-Containing Specialty Chemicals, Institute of Advanced Fluorine-Containing Materials, Zhejiang Normal University, Jinhua 321004, China"},{"name":"Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"5014","DOI":"10.1039\/D2CE00663D","article-title":"Metal-organic framework-based solid-state electrolytes for all solid-state lithium metal batteries: A review","volume":"24","author":"Wei","year":"2022","journal-title":"Crystengcomm"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"3243","DOI":"10.1039\/c1ee01598b","article-title":"Challenges in the development of advanced Li-ion batteries: A review","volume":"4","author":"Etacheri","year":"2011","journal-title":"Energy Environ. 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